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Stainless Steel 1.4466-SA (Solution Annealed)

Heat-treated state · default condition

EN 1.4466

Standard supply condition for plate, sheet, seamless tube and forgings in urea and hot-acid service; maximum corrosion resistance and ductility.

High cost $$$$

Values for the SA condition

Other 1.4466 tempers and conditions

1.4466 is listed in 4 conditions; see the grade overview at 1.4466.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
SADefaultThis page
Solution Annealed
Standard supply condition for plate, sheet, seamless tube and forgings in urea and hot-acid service; maximum corrosion resistance and ductility.31062045165 HB—
As-welded deposit
Property set for matching-consumable weldments and overlays in urea service; strength close to annealed base metal, ferrite kept very low.35061032180 HB1.9 % IACS
Cold drawn
Choose for bar stock, fasteners and machined valve parts where higher yield strength and tighter tolerances are needed.5507502521 HRC1.9 % IACS
Cold Rolled 1/4 Hard
Rarely stocked; used where a spring-back/stiffness gain is needed in thin strip, accepting reduced ductility and slight magnetic permeability rise.6008001822 HRC1.9 % IACS

What is 1.4466-SA?

1.4466-SA is 1.4466 heat treated to SA — standard supply condition for plate, sheet, seamless tube and forgings in urea and hot-acid service; maximum corrosion resistance and ductility. 1.4466-SA has a yield strength of 310 MPa (45 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 63% of stainless steel grades. Elongation at break is 45% and the elastic modulus is 195 GPa (28.3 Msi). 1.4466-SA has a density of 8 g/cm³ (0.289 lb/in³), heavier than 92% of stainless steel grades. It melts at 1,370°C (2,498 °F).

Advantages

  • Good corrosion resistance — 80/100, better than 88% of stainless steel grades
  • Tough — resists crack growth — 200 MPa·√m (182 ksi·√in), better than 86% of stainless steel grades
  • Ductile — tolerates forming and impact — 45%, better than 76% of stainless steel grades
  • Forms and bends easily — 68/100, better than 75% of stainless steel grades

Limitations

  • Poor heat conductor — 12 W/m·K (6.93 BTU/hr·ft·°F), worse than 93% of stainless steel grades
  • High embodied carbon — 6.2 kg CO₂/kg, worse than 90% of stainless steel grades
  • Low electrical conductivity — 1.9 % IACS, worse than 84% of stainless steel grades
  • Limited service temperature — 400°C (752 °F), worse than 78% of stainless steel grades

1.4466-SA properties

Typical room-temperature values for 1.4466-SA; 10 are specific to this condition. Other listed values are 1.4466 reference data and may not represent this condition. Bars are the position among stainless steel grades.

Physical3

1.4466-SA has a density of 8 g/cm³ (0.289 lb/in³), heavier than 92% of stainless steel grades. It melts at 1,370°C (2,498 °F).

Density8 g/cm³0.29 lb/in³
Melting Point (Solidus)1,370°C2,498 °F
Liquidus Temperature1,410°C2,570 °F

Mechanical16

1.4466-SA has a yield strength of 310 MPa (45 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 63% of stainless steel grades. Elongation at break is 45% and the elastic modulus is 195 GPa (28.3 Msi).

Elastic (Young's) Modulus195 GPa28.3 Msi
Shear Modulus75 GPa10.9 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.29
Tensile Strength (Ultimate)620 MPa89.9 ksi
Yield Strength (0.2% offset)310 MPa45 ksi
Elongation at Break45%
Reduction in Area65%
Compressive Strength310 MPa45 ksi
Shear Strength400 MPa58 ksi
Fatigue Strength (Endurance Limit)250 MPa36.3 ksi
Fracture Toughness (K_IC)200 MPa·√m182 ksi·√in
Charpy V-Notch Impact (RT)200 J148 ft·lbf
Hardness, Brinell165 HB
Hardness, Rockwell B85 HRB
Hardness, Vickers175 HV

Thermal6

1.4466-SA is rated for continuous service to 400°C (752 °F). It conducts heat at 12 W/m·K (6.93 BTU/hr·ft·°F), worse than 93% of stainless steel grades. Thermal expansion is 15 µm/m·K (8.33 µin/in·°F).

Thermal Conductivity12 W/m·K6.9 BTU/hr·ft·°F
Specific Heat Capacity490 J/kg·K0.12 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)15 µm/m·K8.3 µin/in·°F
Latent Heat of Fusion280 J/g120 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-196°C-321 °F

Electrical3

1.4466-SA conducts electricity at 1.9 % IACS, worse than 84% of stainless steel grades.

Electrical Conductivity1.9 % IACS
Electrical Resistivity9×10⁻⁷ Ω·m35.4 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is very good (80/100), better than 88% of stainless steel grades.

Galvanic Potential (seawater, vs SCE)-0.05 V
Corrosion ResistanceVery good80/100
Chemical Resistance SummaryExcellent in hot concentrated nitric acid, ammonium carbamate (urea synthesis), hot phosphoric and dilute sulfuric acid; high resistance to chloride SCC and intergranular attack thanks to <0.02 %C and N alloying; not intended for hot high-chloride pitting service where 6Mo/duplex grades or halide-containing reducing acids (HCl, HF) are involved.

Sustainability4

Producing a kilogram of 1.4466-SA takes about 85 MJ of energy and emits 6.2 kg of CO₂ — more than 92% of stainless steel grades. Typical recycled content is 55%.

Embodied Energy (primary production)85 MJ/kg36,543 BTU/lb
Embodied Carbon (primary production)6.2 kg CO₂/kg
Embodied Water200 L/kg24 gal/lb
Typical Recycled Content55%

Manufacturability7

1.4466-SA's machinability is poor (28/100, worse than 79% of stainless steel grades); weldability very good (70/100); formability good (68/100).

MachinabilityPoor28/100
Machinability Rating (AISI 1212 = 100 %)35%
WeldabilityVery good70/100
Formability (cold)Good68/100
Brazeability / SolderabilityGood55/100
PolishabilityVery good75/100
Anodizing Responsen/a — stainless steel is not anodized; use pickling/passivation or electropolishing instead

Common Calculations5

Specific Strength (UTS / density)calculated78 kN·m/kg
Specific Stiffness (E / density)calculated24.4 MN·m/kg
Modulus of Resiliencecalculated246 kJ/m³
Thermal Diffusivitycalculated3.1 mm²/s
Thermal Shock Resistance Indexcalculated3

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with 1.4466-SA

Is 1.4466 easy to machine?

Machine like a super-austenitic: rigid setups, sharp positive-rake carbide, low speed/high feed, heavy flood coolant and no dwelling — it work-hardens and galls rapidly.

Can 1.4466 be welded?

Weld with GTAW/GMAW/SMAW using matching low-C low-Si 25-22-2 consumables, low heat input, interpass <150 °C, no PWHT; back-purge tube welds and pickle/passivate to keep urea-grade corrosion performance.

Can 1.4466 be formed, bent or molded?

Cold forms well but needs ~50 % more press force than 304 and generous springback allowance; hot work at 1150–900 °C followed by full solution anneal and water quench.

What surface finishes work on 1.4466?

Not anodizable; pickle and passivate (HNO₃/HF) or electropolish after fabrication — a clean, oxide-free surface is essential for urea and hot-acid duty; can be mirror polished.

1.4466 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
CEN 1.4466; ASTM S31050 allows 0.025 max≤ 0.020.01
SiASTM S31050: 0.40 max; kept low for urea service≤ 0.70.35
Mn≤ 21.2
P≤ 0.030.02
Svery low S for corrosion and weldability≤ 0.010
Cr24 – 2625
NiASTM S31050: 20.5–23.521 – 2322
MoASTM S31050: 1.6–2.62 – 2.52.2
NASTM S31050: 0.09–0.150.1 – 0.160.13
Febalance—

1.4466-SA — frequently asked

What is 1.4466-SA used for?

1.4466-SA is typically used for phosphoric acid plants, sulfuric acid handling, fertilizer industry and chemical reactors. In short: urea-grade super austenitic; top hot-acid resistance; strong SCC resistance.

What is the yield strength of 1.4466-SA?

1.4466-SA has a typical yield strength of 310 MPa (45 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 63% of stainless steel grades. Strength varies by condition: see the 4 listed tempers.

Is 1.4466-SA easy to machine?

Not especially — machinability is rated poor (28/100, worse than 79% of stainless steel grades). Machine like a super-austenitic: rigid setups, sharp positive-rake carbide, low speed/high feed, heavy flood coolant and no dwelling — it work-hardens and galls rapidly.

Can 1.4466-SA be welded?

Yes — weldability is rated very good (70/100). Weld with GTAW/GMAW/SMAW using matching low-C low-Si 25-22-2 consumables, low heat input, interpass <150 °C, no PWHT; back-purge tube welds and pickle/passivate to keep urea-grade corrosion performance.

What surface finishes work on 1.4466-SA?

Not anodizable; pickle and passivate (HNO₃/HF) or electropolish after fabrication — a clean, oxide-free surface is essential for urea and hot-acid duty; can be mirror polished.

Can 1.4466-SA be formed, bent or molded?

Cold forms well but needs ~50 % more press force than 304 and generous springback allowance; hot work at 1150–900 °C followed by full solution anneal and water quench.

What is the maximum service temperature of 1.4466-SA?

1.4466-SA is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between 1.4466-SA and 1.4466-CD?

SA is the default condition — standard supply condition for plate, sheet, seamless tube and forgings in urea and hot-acid service; maximum corrosion resistance and ductility. CD: choose for bar stock, fasteners and machined valve parts where higher yield strength and tighter tolerances are needed. Yield strength is 310 MPa in SA versus 550 MPa in CD.

Sources

  1. EN 10088-1/-2/-3 Stainless steels — X1CrNiMoN25-22-2 (1.4466) — CEN (2014)
  2. ASTM A240/A480 and A213/A249 — UNS S31050 — ASTM International (2022)
  3. EN 10216-5 Seamless steel tubes for pressure purposes — stainless — CEN (2021)
  4. Urea-grade austenitic stainless (25Cr-22Ni-2Mo-N) tube and plate datasheet — Sandvik / Alleima (2023)
  5. ASM Handbook Vol. 1 & Vol. 13B — stainless steels — ASM International (2005)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.