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Stainless Steel E2594-SA (Solution annealed weld metal)

Heat-treated state

UNS W39594 · ASTM A5.4

Only for castings/overlays that are re-solution treated with the component; restores phase balance and toughness but lowers strength slightly.

High cost $$$$

Values for the SA condition

What is E2594-SA?

E2594-SA is E2594 heat treated to SA — only for castings/overlays that are re-solution treated with the component; restores phase balance and toughness but lowers strength slightly. E2594-SA has a yield strength of 600 MPa (87 ksi) and a tensile strength of 820 MPa (119 ksi) — stronger than 86% of stainless steel grades. Elongation at break is 30% and the elastic modulus is 200 GPa (29 Msi). E2594-SA has a density of 7.8 g/cm³ (0.282 lb/in³), heavier than 50% of stainless steel grades. It melts at 1,350°C (2,462 °F).

Advantages

  • Good corrosion resistance — 88/100, better than 97% of stainless steel grades
  • High strength — 600 MPa (87 ksi), better than 86% of stainless steel grades
  • Readily welded — 80/100, better than 80% of stainless steel grades

Limitations

  • Limited service temperature — 250°C (482 °F), worse than 99% of stainless steel grades
  • Difficult to machine — 25/100, worse than 88% of stainless steel grades
  • Hard to polish — 60/100, worse than 80% of stainless steel grades
  • Limited formability — 25/100, worse than 78% of stainless steel grades
  • Low fracture toughness — 90 MPa·√m (81.9 ksi·√in), worse than 75% of stainless steel grades

E2594-SA properties

Typical room-temperature values for E2594-SA; 7 are specific to this condition. Other listed values are E2594 reference data and may not represent this condition. Bars are the position among stainless steel grades.

Physical3

E2594-SA has a density of 7.8 g/cm³ (0.282 lb/in³), heavier than 50% of stainless steel grades. It melts at 1,350°C (2,462 °F).

Density7.8 g/cm³0.28 lb/in³
Melting Point (Solidus)1,350°C2,462 °F
Liquidus Temperature1,440°C2,624 °F

Mechanical15

E2594-SA has a yield strength of 600 MPa (87 ksi) and a tensile strength of 820 MPa (119 ksi) — stronger than 86% of stainless steel grades. Elongation at break is 30% and the elastic modulus is 200 GPa (29 Msi).

Elastic (Young's) Modulus200 GPa29 Msi
Shear Modulus77 GPa11.2 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)820 MPa119 ksi
Yield Strength (0.2% offset)600 MPa87 ksi
Elongation at Break30%
Reduction in Area45%
Shear Strength520 MPa75.4 ksi
Fatigue Strength (Endurance Limit)380 MPa55.1 ksi
Fracture Toughness (K_IC)90 MPa·√m81.9 ksi·√in
Charpy V-Notch Impact (RT)110 J81.1 ft·lbf
Hardness, Brinell270 HB
Hardness, Rockwell C24 HRC
Hardness, Vickers260 HV

Thermal6

E2594-SA is rated for continuous service to 250°C (482 °F). It conducts heat at 15 W/m·K (8.67 BTU/hr·ft·°F), worse than 59% of stainless steel grades. Thermal expansion is 13 µm/m·K (7.22 µin/in·°F).

Thermal Conductivity15 W/m·K8.7 BTU/hr·ft·°F
Specific Heat Capacity480 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)13 µm/m·K7.2 µin/in·°F
Latent Heat of Fusion270 J/g116 BTU/lb
Max Service Temperature (continuous)250°C482 °F
Min Service Temperature-50°C-58 °F

Electrical3

E2594-SA conducts electricity at 2.2 % IACS, worse than 61% of stainless steel grades.

Electrical Conductivity2.2 % IACS
Electrical Resistivity8×10⁻⁷ Ω·m31.5 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is excellent (88/100), better than 97% of stainless steel grades.

Galvanic Potential (seawater, vs SCE)-0.12 V
Corrosion ResistanceExcellent88/100
Chemical Resistance SummaryExcellent in chloride-bearing seawater, brines and sour service (NACE MR0175 qualified); very good in dilute sulphuric/organic acids and caustic; not for hot concentrated hydrochloric or strongly reducing acids, and avoid 300–1000 °C exposure (σ-phase / 475 °C embrittlement).

Sustainability4

Producing a kilogram of E2594-SA takes about 62 MJ of energy and emits 5.2 kg of CO₂ — more than 75% of stainless steel grades. Typical recycled content is 45%.

Embodied Energy (primary production)62 MJ/kg26,655 BTU/lb
Embodied Carbon (primary production)5.2 kg CO₂/kg
Embodied Water130 L/kg15.6 gal/lb
Typical Recycled Content45%

Manufacturability6

E2594-SA's machinability is poor (25/100, worse than 88% of stainless steel grades); weldability very good (80/100); formability poor (25/100).

MachinabilityPoor25/100
Machinability Rating (AISI 1212 = 100 %)20%
WeldabilityVery good80/100
Formability (cold)Poor25/100
PolishabilityGood60/100
Anodizing Responsen/a — stainless steel; use pickling/passivation (ASTM A380) or electropolishing instead

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with E2594-SA

Is E2594 easy to machine?

Deposited super duplex work-hardens fast — use rigid setups, sharp carbide, heavy positive feed and flood coolant; grind rather than mill where possible.

Can E2594 be welded?

Redry electrodes (≈250–300 °C/2 h), DCEP (or AC for -16/-17), stringer beads, heat input 0.5–2.0 kJ/mm and interpass ≤150 °C to keep ferrite 30–60 FN and avoid σ-phase.

Can E2594 be formed, bent or molded?

Not a wrought product; consumable is used as-deposited, no post-weld cold forming of the weld metal is recommended.

What surface finishes work on E2594?

Remove slag and heat tint fully — pickle (HNO₃/HF paste) or blast plus passivate per ASTM A380 to restore the full pitting resistance of the weld and HAZ.

E2594 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
CAWS A5.4 max≤ 0.040.03
Cr24 – 2725.3
Ni8 – 10.59.4
Mo2.5 – 4.53.8
Nkey austenite stabiliser / PREN contributor0.1 – 0.250.2
Mn0.5 – 21
Si≤ 10.5
Cu≤ 1.50.3
Woptional; higher in S32760-matching variants≤ 10.3
P≤ 0.040.02
S≤ 0.030.01
Febalance

E2594-SA — frequently asked

What is E2594-SA used for?

E2594-SA is typically used for subsea and offshore equipment, desalination, high chloride process piping and heat exchangers. In short: matched to 2507 base metal; highest strength duplex electrode; superior crevice corrosion resistance.

What is the yield strength of E2594-SA?

E2594-SA has a typical yield strength of 600 MPa (87 ksi) and a tensile strength of 820 MPa (119 ksi) — stronger than 86% of stainless steel grades.

Is E2594-SA easy to machine?

Not especially — machinability is rated poor (25/100, worse than 88% of stainless steel grades). Deposited super duplex work-hardens fast — use rigid setups, sharp carbide, heavy positive feed and flood coolant; grind rather than mill where possible.

Can E2594-SA be welded?

Yes — weldability is rated very good (80/100). Redry electrodes (≈250–300 °C/2 h), DCEP (or AC for -16/-17), stringer beads, heat input 0.5–2.0 kJ/mm and interpass ≤150 °C to keep ferrite 30–60 FN and avoid σ-phase.

What surface finishes work on E2594-SA?

Remove slag and heat tint fully — pickle (HNO₃/HF paste) or blast plus passivate per ASTM A380 to restore the full pitting resistance of the weld and HAZ.

Can E2594-SA be formed, bent or molded?

Not a wrought product; consumable is used as-deposited, no post-weld cold forming of the weld metal is recommended.

What is the maximum service temperature of E2594-SA?

E2594-SA is rated for continuous use to about 250°C (482 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. AWS A5.4/A5.4M — Specification for Stainless Steel Electrodes for Shielded Metal Arc Welding — American Welding Society (2012)
  2. ASTM A240 / UNS S32750 (2507) base-metal properties — ASTM International (2022)
  3. Super duplex SMAW electrode all-weld-metal data (2594-type) — ESAB / Böhler Welding / Metrode (2023)
  4. ASM Handbook Vol. 6 — Welding, Brazing and Soldering (duplex stainless welding) — ASM International (1993)
  5. Duplex stainless steel physical property data (2507) — Outokumpu (2020)
  6. NACE MR0175 / ISO 15156-3 hardness limits for duplex weld metal — NACE/ISO (2020)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.