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Aluminum 222.0-O (Annealed)

Temper

AA 222.0 · UNS A02220

Pick when maximum dimensional stability and lowest residual stress matter more than strength.

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Values for the O condition

Other 222.0 tempers and conditions

222.0 is listed in 4 conditions; see the grade overview at 222.0.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
OThis page
Annealed
Pick when maximum dimensional stability and lowest residual stress matter more than strength.138186180 HB38 % IACS
Permanent mold cast, stabilized
Permanent-mold condition without solution treatment — good hardness with better dimensional stability and lower distortion risk.2412550.5115 HB35 % IACS
T61Default
T6 variant, underaged
Standard sand-cast condition: highest strength/hardness combination normally supplied for 222.0.2752830.5115 HB33 % IACS
Permanent mold cast, solution heat treated and fully artificially aged
Highest strength and hardness available in 222.0 — choose for wear/bearing surfaces where near-zero ductility is acceptable.3313310.5140 HB31 % IACS

What is 222.0-O?

222.0-O is 222.0 in the O temper — pick when maximum dimensional stability and lowest residual stress matter more than strength. 222.0-O has a yield strength of 138 MPa (20 ksi) and a tensile strength of 186 MPa (27 ksi) — weaker than 71% of aluminum grades. Elongation at break is 1% and the elastic modulus is 74 GPa (10.7 Msi). 222.0-O has a density of 2.95 g/cm³ (0.107 lb/in³), heavier than 99% of aluminum grades. It melts at 521°C (970 °F). T61 is the default condition FabDigit quotes; O is available on request or by drawing note.

Advantages

  • High service temperature — 230°C (446 °F), better than 95% of aluminum grades

Limitations

  • Needs corrosion protection — 25/100, worse than 100% of aluminum grades
  • Limited ductility — 1%, worse than 95% of aluminum grades
  • Difficult to weld — 20/100, worse than 89% of aluminum grades
  • Hard to polish — 45/100, worse than 76% of aluminum grades

222.0-O properties

Typical room-temperature values for 222.0-O; 10 are specific to this condition. Other listed values are 222.0 reference data and may not represent this condition. Bars are the position among aluminum grades.

Physical3

222.0-O has a density of 2.95 g/cm³ (0.107 lb/in³), heavier than 99% of aluminum grades. It melts at 521°C (970 °F).

Density2.95 g/cm³0.11 lb/in³
Melting Point (Solidus)521°C970 °F
Liquidus Temperature627°C1,161 °F

Mechanical10

222.0-O has a yield strength of 138 MPa (20 ksi) and a tensile strength of 186 MPa (27 ksi) — weaker than 71% of aluminum grades. Elongation at break is 1% and the elastic modulus is 74 GPa (10.7 Msi).

Elastic (Young's) Modulus74 GPa10.7 Msi
Shear Modulus28 GPa4.1 Msi
Bulk Modulus74 GPa10.7 Msi
Poisson's Ratio0.33
Tensile Strength (Ultimate)186 MPa27 ksi
Yield Strength (0.2% offset)138 MPa20 ksi
Elongation at Break1%
Shear Strength145 MPa21 ksi
Fatigue Strength (Endurance Limit)55 MPa8 ksi
Hardness, Brinell80 HB

Thermal6

222.0-O is rated for continuous service to 230°C (446 °F). It conducts heat at 138 W/m·K (79.7 BTU/hr·ft·°F), worse than 55% of aluminum grades. Thermal expansion is 22.6 µm/m·K (12.6 µin/in·°F).

Thermal Conductivity138 W/m·K79.7 BTU/hr·ft·°F
Specific Heat Capacity963 J/kg·K0.23 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)22.6 µm/m·K12.6 µin/in·°F
Latent Heat of Fusion389 J/g167 BTU/lb
Max Service Temperature (continuous)230°C446 °F
Min Service Temperature-195°C-319 °F

Electrical3

222.0-O conducts electricity at 38 % IACS, better than 61% of aluminum grades.

Electrical Conductivity38 % IACS
Electrical Resistivity5.2×10⁻⁸ Ω·m2.05 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is poor (25/100), worse than 100% of aluminum grades.

Galvanic Potential (seawater, vs SCE)-0.72 V
Corrosion ResistancePoor25/100
Chemical Resistance SummaryPoor in chloride and marine environments; high Cu promotes pitting and intergranular attack. Acceptable in dry air, oils and fuels. Requires paint, chromate or organic coating for outdoor use; avoid direct contact with steel/copper in wet service.

Sustainability4

Producing a kilogram of 222.0-O takes about 200 MJ of energy and emits 12.5 kg of CO₂ — less than 60% of aluminum grades. Typical recycled content is 50%.

Embodied Energy (primary production)200 MJ/kg85,985 BTU/lb
Embodied Carbon (primary production)12.5 kg CO₂/kg
Embodied Water1,100 L/kg132 gal/lb
Typical Recycled Content50%

Manufacturability6

222.0-O's machinability is very good (70/100, better than 72% of aluminum grades); weldability poor (20/100).

MachinabilityVery good70/100
WeldabilityPoor20/100
CastabilityFair35/100
Brazeability / SolderabilityPoor15/100
PolishabilityFair45/100
Anodizing Responsepoor — high copper gives dark, non-uniform, low-protection films; chromic/hard anodize not recommended, use paint or chemical conversion instead

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with 222.0-O

Is 222.0 easy to machine?

Machines very well with sharp carbide tools and light lubrication; hard CuAl2 phase gives short, easily broken chips and good surface finish.

Can 222.0 be welded?

Poor fusion weldability — high Cu promotes hot cracking and loss of aged strength; repair by brazing/adhesive or mechanical fastening where possible.

Can 222.0 be formed, bent or molded?

Casting only, no cold forming; low fluidity and high hot-tear sensitivity demand generous fillets, chills and well-fed risers, plus careful post-cast heat treatment to avoid distortion.

What surface finishes work on 222.0?

Do not rely on anodizing (dark, non-protective); use chromate/phosphate conversion, primer + paint or plating, and avoid galvanic couples with steel or copper in humid service.

222.0 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Siimpurity limit≤ 21
Feimpurity limit≤ 1.50.8
Cuprincipal strengthening element9.2 – 10.710
Mn≤ 0.5—
Mgaids age hardening0.15 – 0.350.25
Ni≤ 0.5—
Zn≤ 0.8—
Tigrain refiner≤ 0.25—
Others (each)≤ 0.05—
Others (total)≤ 0.35—
Albalance—

222.0-O — frequently asked

What is 222.0-O used for?

222.0-O is typically used for cylinder heads (legacy), engine brackets and high-hardness machinery parts. In short: highest-hardness Al-Cu casting; very low ductility; legacy permanent-mold alloy.

What is the yield strength of 222.0-O?

222.0-O has a typical yield strength of 138 MPa (20 ksi) and a tensile strength of 186 MPa (27 ksi) — weaker than 71% of aluminum grades. Strength varies by condition: see the 4 listed tempers.

Is 222.0-O easy to machine?

Yes — machinability is rated very good (70/100, better than 72% of aluminum grades). Machines very well with sharp carbide tools and light lubrication; hard CuAl2 phase gives short, easily broken chips and good surface finish.

Can 222.0-O be welded?

Not readily — weldability is rated poor (20/100). Poor fusion weldability — high Cu promotes hot cracking and loss of aged strength; repair by brazing/adhesive or mechanical fastening where possible.

What surface finishes work on 222.0-O?

Do not rely on anodizing (dark, non-protective); use chromate/phosphate conversion, primer + paint or plating, and avoid galvanic couples with steel or copper in humid service.

Can 222.0-O be formed, bent or molded?

Casting only, no cold forming; low fluidity and high hot-tear sensitivity demand generous fillets, chills and well-fed risers, plus careful post-cast heat treatment to avoid distortion.

What is the maximum service temperature of 222.0-O?

222.0-O is rated for continuous use to about 230°C (446 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between 222.0-T61 and 222.0-O?

T61 is the default condition — standard sand-cast condition: highest strength/hardness combination normally supplied for 222.0. O: pick when maximum dimensional stability and lowest residual stress matter more than strength. Yield strength is 275 MPa in T61 versus 138 MPa in O.

Sources

  1. Aluminum Association Designations and Chemical Composition Limits for Aluminum Alloys in the Form of Castings and Ingot (Pink Sheets) — The Aluminum Association (2018)
  2. ASTM B26/B26M — Aluminum-Alloy Sand Castings — ASTM International (2018)
  3. ASTM B108/B108M — Aluminum-Alloy Permanent Mold Castings — ASTM International (2019)
  4. ASM Handbook Vol.2 — Properties and Selection: Nonferrous Alloys — ASM International (1990)
  5. ASM Specialty Handbook: Aluminum and Aluminum Alloys — ASM International (1993)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.