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Steel C12A-AC (Spheroidize annealed)

Heat-treated state

ASTM A217 Grade C12A

Reference only: the raw casting is hard, brittle and crack-prone and must never be shipped or welded in this state.

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Values for the AC condition

Other C12A tempers and conditions

C12A is listed in 6 conditions; see the grade overview at C12A.

Compare all 6 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Annealed
Intermediate softening condition only — castings must be re-normalized and tempered before service.360560269 HRC3 % IACS
N+T high temper
Choose when weld-repair ductility, toughness or a ≤210 HB hardness cap is more important than peak strength.4356102413 HRC—
N+T plus post-weld heat treatment 750–770 °C
Condition of production/repair-welded castings after mandatory PWHT; slightly softer HAZ than the base N+T state.4506302117 HRC2.9 % IACS
N+TDefault
Normalized and tempered
Standard mandatory ASTM A217 delivery condition for all C12A castings in creep service.4706502119 HRC—
Quenched and tempered
Used on very heavy valve bodies where air cooling would not fully transform the core to martensite.5207001922 HRC—
ACThis page
Spheroidize annealed
Reference only: the raw casting is hard, brittle and crack-prone and must never be shipped or welded in this state.8001,150543 HRC2.6 % IACS

What is C12A-AC?

C12A-AC is C12A heat treated to AC — reference only: the raw casting is hard, brittle and crack-prone and must never be shipped or welded in this state. C12A-AC has a yield strength of 800 MPa (116 ksi) and a tensile strength of 1,150 MPa (167 ksi) — stronger than 86% of steel grades. Elongation at break is 5% and the elastic modulus is 216 GPa (31.3 Msi). C12A-AC has a density of 7.77 g/cm³ (0.281 lb/in³), lighter than 92% of steel grades. It melts at 1,420°C (2,588 °F). N+T is the default condition FabDigit quotes; AC is available on request or by drawing note.

Advantages

  • Good corrosion resistance — 30/100, better than 95% of steel grades
  • High strength — 800 MPa (116 ksi), better than 86% of steel grades

Limitations

  • Limited formability — 2/100, worse than 100% of steel grades
  • Limited ductility — 5%, worse than 98% of steel grades
  • Difficult to machine — 15/100, worse than 98% of steel grades
  • Low electrical conductivity — 2.6 % IACS, worse than 97% of steel grades
  • Difficult to weld — 12/100, worse than 96% of steel grades

C12A-AC properties

Typical room-temperature values for C12A-AC; 22 are specific to this condition. Other listed values are C12A reference data and may not represent this condition. Bars are the position among steel grades.

Physical3

C12A-AC has a density of 7.77 g/cm³ (0.281 lb/in³), lighter than 92% of steel grades. It melts at 1,420°C (2,588 °F).

Density7.77 g/cm³0.28 lb/in³
Melting Point (Solidus)1,420°C2,588 °F
Liquidus Temperature1,490°C2,714 °F

Mechanical16

C12A-AC has a yield strength of 800 MPa (116 ksi) and a tensile strength of 1,150 MPa (167 ksi) — stronger than 86% of steel grades. Elongation at break is 5% and the elastic modulus is 216 GPa (31.3 Msi).

Elastic (Young's) Modulus216 GPa31.3 Msi
Shear Modulus84 GPa12.2 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)1,150 MPa167 ksi
Yield Strength (0.2% offset)800 MPa116 ksi
Elongation at Break5%
Reduction in Area12%
Compressive Strength850 MPa123 ksi
Shear Strength690 MPa100 ksi
Fatigue Strength (Endurance Limit)430 MPa62.4 ksi
Fracture Toughness (K_IC)40 MPa·√m36.4 ksi·√in
Charpy V-Notch Impact (RT)8 J5.9 ft·lbf
Hardness, Brinell400 HB
Hardness, Rockwell C43 HRC
Hardness, Vickers425 HV

Thermal6

C12A-AC is rated for continuous service to 200°C (392 °F). It conducts heat at 24 W/m·K (13.9 BTU/hr·ft·°F), worse than 90% of steel grades. Thermal expansion is 10.8 µm/m·K (6 µin/in·°F).

Thermal Conductivity24 W/m·K13.9 BTU/hr·ft·°F
Specific Heat Capacity460 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)10.8 µm/m·K6 µin/in·°F
Latent Heat of Fusion270 J/g116 BTU/lb
Max Service Temperature (continuous)200°C392 °F
Min Service Temperature-30°C-22 °F

Electrical3

C12A-AC conducts electricity at 2.6 % IACS, worse than 97% of steel grades.

Electrical Conductivity2.6 % IACS
Electrical Resistivity6.6×10⁻⁷ Ω·m26 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is poor (30/100), better than 95% of steel grades.

Galvanic Potential (seawater, vs SCE)-0.52 V
Corrosion ResistancePoor30/100
Chemical Resistance SummaryDesigned for dry high-pressure steam and hot flue-gas service; 9 % Cr gives useful steam-oxidation and sulfidation resistance to ~600 °C but it rusts freely in humid air, water and chlorides and is attacked by acids — external painting/insulation and dry lay-up are required.

Sustainability4

Producing a kilogram of C12A-AC takes about 33 MJ of energy and emits 2.4 kg of CO₂ — more than 76% of steel grades. Typical recycled content is 80%.

Embodied Energy (primary production)33 MJ/kg14,187 BTU/lb
Embodied Carbon (primary production)2.4 kg CO₂/kg
Embodied Water45 L/kg5.4 gal/lb
Typical Recycled Content80%

Manufacturability7

C12A-AC's machinability is poor (15/100, worse than 98% of steel grades); weldability not recommended (12/100); formability not recommended (2/100).

MachinabilityPoor15/100
Machinability Rating (AISI 1212 = 100 %)15%
WeldabilityNot recommended12/100
Formability (cold)Not recommended2/100
CastabilityGood55/100
Brazeability / SolderabilityPoor25/100
PolishabilityGood60/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with C12A-AC

Is C12A easy to machine?

Machine in the tempered condition with rigid setups, carbide inserts and moderate speed (≈60–100 m/min); the martensitic matrix work-hardens and scale from heat treatment is very abrasive, so take the first cut under the scale.

Can C12A be welded?

Weld with matching 9Cr-1Mo-V filler (AWS E9015-B9 / ER90S-B9), 200–250 °C preheat, ≤300 °C interpass, cool to 80–120 °C to complete martensite transformation, then PWHT 750–770 °C — never leave the joint untempered.

Can C12A be formed, bent or molded?

Cast to shape only; use generous risers and chills for the long freezing range, control nitrogen and avoid hot tearing in section changes, and always re-normalize + temper after any upgrading weld.

What surface finishes work on C12A?

Shot blast to remove heat-treat scale; parts are painted or aluminized for external protection, and no anodizing applies — internal steam surfaces rely on the Cr oxide formed in service.

C12A chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
C0.08 – 0.120.1
MnMn+Ni often limited to ≤1.0 % to keep Ac1 high0.3 – 0.60.45
Si0.2 – 0.50.35
P≤ 0.020.01
S≤ 0.010.01
Cr8 – 9.58.8
Mo0.85 – 1.050.95
VMX carbonitride former0.18 – 0.250.21
Nblisted as Cb in ASTM A2170.06 – 0.10.08
Nessential for VN precipitation strengthening0.03 – 0.070.05
Ni≤ 0.40.2
Almax; low Al preserves free N≤ 0.020.01
Ti≤ 0.010
Zr≤ 0.010
Febalance—

C12A-AC — frequently asked

What is C12A-AC used for?

C12A-AC is typically used for ultra-supercritical steam valve bodies, turbine casings and high-temperature power plant castings. In short: cast P91 equivalent; highest creep strength here; ultra-supercritical steam grade.

What is the yield strength of C12A-AC?

C12A-AC has a typical yield strength of 800 MPa (116 ksi) and a tensile strength of 1,150 MPa (167 ksi) — stronger than 86% of steel grades. Strength varies by condition: see the 6 listed tempers.

Is C12A-AC easy to machine?

Not especially — machinability is rated poor (15/100, worse than 98% of steel grades). Machine in the tempered condition with rigid setups, carbide inserts and moderate speed (≈60–100 m/min); the martensitic matrix work-hardens and scale from heat treatment is very abrasive, so take the first cut under the scale.

Can C12A-AC be welded?

Not readily — weldability is rated not recommended (12/100). Weld with matching 9Cr-1Mo-V filler (AWS E9015-B9 / ER90S-B9), 200–250 °C preheat, ≤300 °C interpass, cool to 80–120 °C to complete martensite transformation, then PWHT 750–770 °C — never leave the joint untempered.

What surface finishes work on C12A-AC?

Shot blast to remove heat-treat scale; parts are painted or aluminized for external protection, and no anodizing applies — internal steam surfaces rely on the Cr oxide formed in service.

Can C12A-AC be formed, bent or molded?

Cast to shape only; use generous risers and chills for the long freezing range, control nitrogen and avoid hot tearing in section changes, and always re-normalize + temper after any upgrading weld.

What is the maximum service temperature of C12A-AC?

C12A-AC is rated for continuous use to about 200°C (392 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between C12A N+T and C12A-AC?

N+T is the default condition — standard mandatory ASTM A217 delivery condition for all C12A castings in creep service. AC: reference only: the raw casting is hard, brittle and crack-prone and must never be shipped or welded in this state. Yield strength is 470 MPa in N+T versus 800 MPa in AC.

Sources

  1. ASTM A217/A217M — Steel Castings, Martensitic Stainless and Alloy, for Pressure-Containing Parts at High Temperature — ASTM International (2021)
  2. ASME BPVC Section II Part D — Properties (Materials) — ASME (2023)
  3. ASM Handbook Vol. 1: Properties and Selection — Irons, Steels, and High-Performance Alloys — ASM International (1990)
  4. The Grade 91 Steel Handbook / EPRI Guidelines for Grade 91 Fabrication and Service — EPRI (2015)
  5. GB/T 16253 / DL/T (ZG1Cr9Mo1VNbN) (2019)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.