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Titanium C-4-F (As fabricated)

Temper · default condition

ASTM B367 Grade C-4

Standard supply condition for general corrosion-service castings where B367 minimums are sufficient.

High cost $$$$

Values for the F condition

Other C-4 tempers and conditions

C-4 is listed in 5 conditions; see the grade overview at C-4.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Annealed
Choose for maximum ductility, dimensional stability and lowest hardness before heavy machining or forming of thin sections.5005901524 HRC—
hot isostatically pressed then vacuum annealed
Highest-integrity condition for critical aerospace/medical or high-cycle-fatigue castings needing both pore closure and full stress relief.51060017250 HB—
Stress relieved
Pick when casting/weld-repair residual stresses must be removed before final machining, with no strength loss.5206151325 HRC2.9 % IACS
Hot isostatic pressed
Specify for pressure-containing or fatigue-loaded castings: closes internal gas/shrinkage porosity and lifts ductility and fatigue life.52562016260 HB—
FDefaultThis page
As fabricated
Standard supply condition for general corrosion-service castings where B367 minimums are sufficient.5306201226 HRC—

What is C-4-F?

C-4-F is C-4 in the F temper — standard supply condition for general corrosion-service castings where B367 minimums are sufficient. C-4-F has a yield strength of 530 MPa (76.9 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 59% of titanium grades. Elongation at break is 12% and the elastic modulus is 104 GPa (15.1 Msi). C-4-F has a density of 4.51 g/cm³ (0.163 lb/in³), heavier than 57% of titanium grades. It melts at 1,660°C (3,020 °F).

Advantages

  • Conducts heat well — 17.2 W/m·K (9.94 BTU/hr·ft·°F), better than 88% of titanium grades

Limitations

  • Low fracture toughness — 60 MPa·√m (54.6 ksi·√in), worse than 83% of titanium grades
  • Limited formability — 20/100, worse than 83% of titanium grades
  • Limited ductility — 12%, worse than 78% of titanium grades

C-4-F properties

Typical room-temperature values for C-4-F; 12 are specific to this condition. Other listed values are C-4 reference data and may not represent this condition. Bars are the position among titanium grades.

Physical3

C-4-F has a density of 4.51 g/cm³ (0.163 lb/in³), heavier than 57% of titanium grades. It melts at 1,660°C (3,020 °F).

Density4.51 g/cm³0.16 lb/in³
Melting Point (Solidus)1,660°C3,020 °F
Liquidus Temperature1,670°C3,038 °F

Mechanical16

C-4-F has a yield strength of 530 MPa (76.9 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 59% of titanium grades. Elongation at break is 12% and the elastic modulus is 104 GPa (15.1 Msi).

Elastic (Young's) Modulus104 GPa15.1 Msi
Shear Modulus45 GPa6.5 Msi
Bulk Modulus110 GPa16 Msi
Poisson's Ratio0.34
Tensile Strength (Ultimate)620 MPa89.9 ksi
Yield Strength (0.2% offset)530 MPa76.9 ksi
Elongation at Break12%
Reduction in Area20%
Compressive Strength560 MPa81.2 ksi
Shear Strength430 MPa62.4 ksi
Fatigue Strength (Endurance Limit)240 MPa34.8 ksi
Fracture Toughness (K_IC)60 MPa·√m54.6 ksi·√in
Charpy V-Notch Impact (RT)14 J10.3 ft·lbf
Hardness, Brinell265 HB
Hardness, Rockwell C26 HRC
Hardness, Vickers280 HV

Thermal6

C-4-F is rated for continuous service to 300°C (572 °F). It conducts heat at 17.2 W/m·K (9.94 BTU/hr·ft·°F), better than 88% of titanium grades. Thermal expansion is 8.6 µm/m·K (4.78 µin/in·°F).

Thermal Conductivity17.2 W/m·K9.9 BTU/hr·ft·°F
Specific Heat Capacity544 J/kg·K0.13 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)8.6 µm/m·K4.8 µin/in·°F
Latent Heat of Fusion320 J/g138 BTU/lb
Max Service Temperature (continuous)300°C572 °F
Min Service Temperature-196°C-321 °F

Electrical3

C-4-F conducts electricity at 2.9 % IACS, better than 58% of titanium grades.

Electrical Conductivity2.9 % IACS
Electrical Resistivity6×10⁻⁷ Ω·m23.6 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 53% of titanium grades.

Galvanic Potential (seawater, vs SCE)-0.1 V
Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryExcellent in seawater, wet chlorine, hypochlorite, nitric acid and most oxidizing media thanks to the TiO₂ film; attacked by HF, hot concentrated HCl/H₂SO₄/phosphoric acid, and dry chlorine; risk of hydriding in reducing acids and of ignition in pure oxygen at pressure.

Sustainability4

Producing a kilogram of C-4-F takes about 650 MJ of energy and emits 39 kg of CO₂ — less than 75% of titanium grades. Typical recycled content is 25%.

Embodied Energy (primary production)650 MJ/kg279,450 BTU/lb
Embodied Carbon (primary production)39 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content25%

Manufacturability8

C-4-F's machinability is poor (30/100, better than 64% of titanium grades); weldability excellent (85/100); formability poor (20/100).

MachinabilityPoor30/100
Machinability Rating (AISI 1212 = 100 %)35%
WeldabilityExcellent85/100
Formability (cold)Poor20/100
CastabilityGood60/100
Brazeability / SolderabilityFair40/100
PolishabilityVery good75/100
Anodizing Responseexcellent — Type II colour anodizing (interference oxide) and Type III hard anodize/AMS 2488 conversion are routinely applied to CP-Ti castings

Common Calculations5

Specific Strength (UTS / density)calculated137 kN·m/kg
Specific Stiffness (E / density)calculated23.1 MN·m/kg
Modulus of Resiliencecalculated1,350 kJ/m³
Thermal Diffusivitycalculated7 mm²/s
Thermal Shock Resistance Indexcalculated12

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with C-4-F

Is C-4 easy to machine?

Machine at low surface speed (20–40 m/min) with sharp, positive-rake uncoated carbide, heavy rigid setup and flood coolant; remove the oxygen-rich α-case by chemical milling before finish cuts and never let the tool dwell (galling/fire risk in fine chips).

Can C-4 be welded?

Very good GTAW/EBW/plasma weldability with matching CP-Ti filler (ERTi-4) — but requires full argon/helium shielding of pool, root and hot metal below 425 °C; a bright silver bead colour is the acceptance criterion.

Can C-4 be formed, bent or molded?

Vacuum-arc or induction skull melted and poured into rammed graphite or yttria/zirconia face-coated investment shells; allow ~1 % shrink, generous fillets and thick risers, then chem-mill 0.2–0.5 mm α-case and HIP for pressure duty.

What surface finishes work on C-4?

Pickle in HNO₃/HF to remove scale and α-case, then anodize (AMS 2488 Type II colour or Type III wear-resistant oxide); grit blasting must use clean alumina, and iron contamination from steel tooling must be avoided to preserve corrosion resistance.

C-4 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
N≤ 0.050.02
C≤ 0.10.03
Hmax, on cast product≤ 0.020.01
Fe≤ 0.50.3
Omax — controls the strength level of C-4≤ 0.40.33
Residuals (each)per ASTM B367≤ 0.1—
Residuals (total)per ASTM B367≤ 0.4—
Tibalance—

C-4-F — frequently asked

What is C-4-F used for?

C-4-F is typically used for high-strength valve trim, structural brackets, marine/offshore fittings and medical instrument castings. In short: strongest unalloyed cast titanium; cast CP Grade 4 equivalent; strength without alloying additions.

What is the yield strength of C-4-F?

C-4-F has a typical yield strength of 530 MPa (76.9 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 59% of titanium grades. Strength varies by condition: see the 5 listed tempers.

Is C-4-F easy to machine?

Not especially — machinability is rated poor (30/100, better than 64% of titanium grades). Machine at low surface speed (20–40 m/min) with sharp, positive-rake uncoated carbide, heavy rigid setup and flood coolant; remove the oxygen-rich α-case by chemical milling before finish cuts and never let the tool dwell (galling/fire risk in fine chips).

Can C-4-F be welded?

Yes — weldability is rated excellent (85/100). Very good GTAW/EBW/plasma weldability with matching CP-Ti filler (ERTi-4) — but requires full argon/helium shielding of pool, root and hot metal below 425 °C; a bright silver bead colour is the acceptance criterion.

What surface finishes work on C-4-F?

Pickle in HNO₃/HF to remove scale and α-case, then anodize (AMS 2488 Type II colour or Type III wear-resistant oxide); grit blasting must use clean alumina, and iron contamination from steel tooling must be avoided to preserve corrosion resistance.

Can C-4-F be formed, bent or molded?

Vacuum-arc or induction skull melted and poured into rammed graphite or yttria/zirconia face-coated investment shells; allow ~1 % shrink, generous fillets and thick risers, then chem-mill 0.2–0.5 mm α-case and HIP for pressure duty.

What is the maximum service temperature of C-4-F?

C-4-F is rated for continuous use to about 300°C (572 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between C-4-F and C-4-ANN?

F is the default condition — standard supply condition for general corrosion-service castings where B367 minimums are sufficient. ANN: choose for maximum ductility, dimensional stability and lowest hardness before heavy machining or forming of thin sections. Yield strength is 530 MPa in F versus 500 MPa in ANN.

Sources

  1. ASTM B367 Standard Specification for Titanium and Titanium Alloy Castings — ASTM International (2022)
  2. ASTM B265 / ASTM F67 (wrought CP-Ti Grade 4 reference properties) — ASTM International (2020)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials — ASM International (1990)
  4. Materials Properties Handbook: Titanium Alloys — ASM International (1994)
  5. ASM Handbook Vol. 13B — Corrosion: Materials (Titanium) — ASM International (2005)
  6. GB/T 15073 / GB/T 6614 — SAC (2014)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.