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Commercially Pure Titanium

Commercially pure titanium is unalloyed metal in which the oxygen content — 0.18 % in Grade 1 rising to 0.40 % in Grade 4 — sets the strength: yield climbs from about 170 MPa to 480 MPa across the four grades while formability and weldability fall. Grades 7, 11, 16 and 17 add 0.05–0.25 % palladium to the same base for reducing acids and hot brines. All of them are single-phase alpha, cannot be hardened by heat treatment, and carry the best corrosion resistance of any titanium — the reason they fill chemical plants, desalination trains and heat exchangers rather than airframes.

Popular CP titanium grades

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Choose CP titanium for

Heat-exchanger tubing and plates, reactor and column linings, chlor-alkali and bleach plant, desalination and seawater piping, anode baskets and plating racks, medical device housings and CP-grade implants — wherever the part must survive chlorides or oxidizing chemistry indefinitely and does not need more than about 480 MPa yield.

Look elsewhere when

The part carries real structural load or fatigue (Grade 5 has three times the yield of Grade 2, Grade 9 twice), it runs above about 300 °C under stress (Ti-6242 or Grade 6), it must resist hot reducing acid without palladium (Grade 12 with molybdenum and nickel), or the service is only mild atmosphere or fresh water — 316L stainless or 6061 aluminum do that for a fraction of the material and machining cost.

Yield strength against elongation at break, Commercially pure (Grades 1–4, 7, 11, 12) among every titanium grade

No materials in view have both of these properties.

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CP titanium by application

Heat exchangers and process piping
Grade 2 tube (ASTM B338) and plate for seawater, brackish and oxidizing chemistry; Grade 1 for plate-and-frame exchangers that are pressed into deep corrugations.
Reducing acids and hot chlorides
Grade 7 or the leaner Grade 16 where hydrochloric or sulphuric acid, or brine above about 80 °C, would attack Grade 2 in crevices; Grade 12 is the palladium-free alternative for the same brine duty.
Implants, dental and instruments
Grade 4 under ASTM F67 for bone screws, dental implants and plates; Grade 2 for housings, trays and instrument bodies that only need biocompatibility. Grade 23 takes over when the implant is load-bearing.
Anodes, racks and electrochemical hardware
Grade 1 and Grade 2 for plating racks, anode baskets and cathodic-protection hardware — the oxide film is stable across the anodic range where stainless dissolves.

Working with CP titanium

Machining
The easiest titanium to cut, at roughly half the speed of mild steel: Grade 2 and Grade 1 are gummy rather than hard, so use sharp positive tooling, high feed at modest surface speed, flood coolant and never let the tool rub — the surface work-hardens and galls. Grade 4 behaves closer to Grade 5. Hold thin walls with support; the low modulus (about 105 GPa) lets the part push away from the cutter.
Welding
TIG with ERTi-2 filler for Grade 2 (ERTi-1 for Grade 1, ERTi-7 for Grade 7) under full argon shielding of the face, root and trailing zone; a straw or light-blue tint is acceptable, dark blue or gray is contaminated and must be cut out. Welds match base-metal strength with no post-weld heat treatment. Grade 2 also resistance- and laser-welds well.
Forming
Grade 1 bends cold to about 1.5 t inside radius and Grade 2 to about 2 t, with springback allowance; Grade 3 and Grade 4 need 2.5–3.5 t or warm forming at 200–300 °C. Deep drawing and spinning are done in Grade 1. Strip and tube take press bends and roll forming as freely as annealed stainless.
Finishing
None needed for corrosion: the bare oxide film is the protection, and pickling in nitric-hydrofluoric acid restores it after welding or heat tint. Anodizing gives interference colours (gold, blue, violet) for identification, a thicker Type III film for anti-galling on sliding joints. Bead blast or brushed finishes are standard for housings; passivate per ASTM F86 for medical parts.

Other titanium series

Commercially Pure Titanium — frequently asked

What is CP titanium?

Commercially pure titanium is unalloyed metal in which the oxygen content — 0.18 % in Grade 1 rising to 0.40 % in Grade 4 — sets the strength: yield climbs from about 170 MPa to 480 MPa across the four grades while formability and weldability fall. Grades 7, 11, 16 and 17 add 0.05–0.25 % palladium to the same base for reducing acids and hot brines. All of them are single-phase alpha, cannot be hardened by heat treatment, and carry the best corrosion resistance of any titanium — the reason they fill chemical plants, desalination trains and heat exchangers rather than airframes.

Which grade of CP titanium should I use?

Grade 2 unless there is a reason not to: about 275 MPa yield, the widest choice of sheet, plate, bar and tube, the ASTM B265 / B338 standard for process equipment and the easiest grade to weld. Grade 1 when the part must be deep-drawn, spun or bent tight (plate heat-exchanger plates, expansion bellows) and 170 MPa yield is enough. Grade 3 and Grade 4 carry more oxygen for about 380 and 480 MPa yield — Grade 4 is the CP grade for bone screws, dental implants and surgical instrument bodies under ASTM F67 where Grade 5 would be more than the design needs. Grade 7 is Grade 2 with palladium for hydrochloric, sulphuric and phosphoric acid and crevice-prone brine above 80 °C; Grade 16 does most of the same job with a quarter of the palladium, and Grade 11 is the palladium version of Grade 1 for the formable equivalent.

Which grade of CP titanium is the strongest?

Ti Grade 35 has the highest yield strength in the series at 920 MPa; VT14 follows at 850 MPa. Values are for each grade's default condition.

Which grade of CP titanium is easiest to machine?

Grade 11 (machinability fair, 45/100), then C-1 (42/100).

Is CP titanium heat-treatable?

No. These grades are strengthened by cold work and softened by annealing, not by heat treatment; the conditions are listed on each grade page.

Grade 2 or Grade 7 for acid service?

Grade 7 is Grade 2 with 0.12–0.25 % palladium, which shifts the corrosion potential so the oxide film repairs itself in reducing acids and in hot chloride crevices — hydrochloric acid, wet chlorine, brine above about 80 °C — where Grade 2 pits under deposits and gaskets. Mechanical properties, welding and forming are identical. Grade 7 costs several times as much per kilogram because of the palladium; Grade 16 with 0.04–0.08 % Pd or Grade 12 with Mo and Ni covers most of the same crevice-corrosion duty for less.

Can I weld Grade 2 to Grade 5?

Yes — CP titanium and Ti-6Al-4V weld together by TIG with either ERTi-2 or ERTi-5 filler under full inert shielding; the joint strength is set by the Grade 2 side (about 345 MPa tensile), so design the weld on that basis. Stress-relieve the assembly at 480–595 °C if the Grade 5 part is machined afterwards. What you cannot do is buy the Grade 2 strength back by heat treatment — CP grades gain strength only from oxygen content and cold work.