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Titanium Grade 4-AW (As-welded deposit)

Heat-treated state

ASTM Grade 4 · UNS R50700 · EN 3.7065 · GB TA4

Properties of Grade 4 used as GTAW/GMAW filler metal deposit for joining CP-Ti Grade 3/4 components.

CNC machiningSheet metalSpecialty cost $$$$$

Values for the AW condition

Other Grade 4 tempers and conditions

Grade 4 is listed in 5 conditions; see the grade overview at Grade 4.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
AWThis page
As-welded deposit
Properties of Grade 4 used as GTAW/GMAW filler metal deposit for joining CP-Ti Grade 3/4 components.52062015258 HB2.9 % IACS
Hot rolled
Economical condition for thick plate, billet and forgings that will be machined and, if needed, annealed later.54063018255 HB2.9 % IACS
ODefault
Annealed
Default stocked condition for sheet, plate, bar and tube — best balance of strength, ductility and weldability.55062020253 HB—
Stress relieved
Pick for straightness/dimensional stability after cold work or welding while keeping most of the cold-worked yield strength.5906601826 HRC2.9 % IACS
Cold worked
Use where maximum strength from unalloyed titanium is needed — dental implants, bone screws, high-pressure small-bore tube.7007801331 HRC—

What is Grade 4-AW?

Grade 4-AW is Grade 4 heat treated to AW — properties of Grade 4 used as GTAW/GMAW filler metal deposit for joining CP-Ti Grade 3/4 components. Grade 4-AW has a yield strength of 520 MPa (75.4 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 60% of titanium grades. Elongation at break is 15% and the elastic modulus is 105 GPa (15.2 Msi). Grade 4-AW has a density of 4.51 g/cm³ (0.163 lb/in³), heavier than 57% of titanium grades. It melts at 1,660°C (3,020 °F). O is the default condition FabDigit quotes; AW is available on request or by drawing note.

Advantages

  • Conducts heat well — 17.2 W/m·K (9.94 BTU/hr·ft·°F), better than 88% of titanium grades

Limitations

  • Low fracture toughness — 58 MPa·√m (52.8 ksi·√in), worse than 87% of titanium grades

Grade 4-AW properties

Typical room-temperature values for Grade 4-AW; 22 are specific to this condition. Other listed values are Grade 4 reference data and may not represent this condition. Bars are the position among titanium grades.

Physical3

Grade 4-AW has a density of 4.51 g/cm³ (0.163 lb/in³), heavier than 57% of titanium grades. It melts at 1,660°C (3,020 °F).

Density4.51 g/cm³0.16 lb/in³
Melting Point (Solidus)1,660°C3,020 °F
Liquidus Temperature1,665°C3,029 °F

Mechanical16

Grade 4-AW has a yield strength of 520 MPa (75.4 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 60% of titanium grades. Elongation at break is 15% and the elastic modulus is 105 GPa (15.2 Msi).

Elastic (Young's) Modulus105 GPa15.2 Msi
Shear Modulus45 GPa6.5 Msi
Bulk Modulus110 GPa16 Msi
Poisson's Ratio0.34
Tensile Strength (Ultimate)620 MPa89.9 ksi
Yield Strength (0.2% offset)520 MPa75.4 ksi
Elongation at Break15%
Reduction in Area30%
Compressive Strength560 MPa81.2 ksi
Shear Strength415 MPa60.2 ksi
Fatigue Strength (Endurance Limit)300 MPa43.5 ksi
Fracture Toughness (K_IC)58 MPa·√m52.8 ksi·√in
Charpy V-Notch Impact (RT)16 J11.8 ft·lbf
Hardness, Brinell258 HB
Hardness, Rockwell B101 HRB
Hardness, Vickers270 HV

Thermal6

Grade 4-AW is rated for continuous service to 300°C (572 °F). It conducts heat at 17.2 W/m·K (9.94 BTU/hr·ft·°F), better than 88% of titanium grades. Thermal expansion is 9 µm/m·K (5 µin/in·°F).

Thermal Conductivity17.2 W/m·K9.9 BTU/hr·ft·°F
Specific Heat Capacity540 J/kg·K0.13 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)9 µm/m·K5 µin/in·°F
Latent Heat of Fusion365 J/g157 BTU/lb
Max Service Temperature (continuous)300°C572 °F
Min Service Temperature-196°C-321 °F

Electrical3

Grade 4-AW conducts electricity at 2.9 % IACS, better than 58% of titanium grades.

Electrical Conductivity2.9 % IACS
Electrical Resistivity6×10⁻⁷ Ω·m23.6 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (90/100), worse than 63% of titanium grades.

Galvanic Potential (seawater, vs SCE)-0.1 V
Corrosion ResistanceExcellent90/100
Chemical Resistance SummaryOutstanding in seawater, chlorides, wet chlorine, hypochlorite, nitric acid and most oxidising media thanks to a stable TiO₂ film; attacked by hydrofluoric acid, hot concentrated HCl/H₂SO₄/phosphoric acid and dry chlorine; risk of stress-corrosion cracking in anhydrous methanol and in red fuming nitric acid.

Sustainability4

Producing a kilogram of Grade 4-AW takes about 700 MJ of energy and emits 45 kg of CO₂ — more than 74% of titanium grades. Typical recycled content is 25%.

Embodied Energy (primary production)700 MJ/kg300,946 BTU/lb
Embodied Carbon (primary production)45 kg CO₂/kg
Embodied Water800 L/kg95.9 gal/lb
Typical Recycled Content25%

Manufacturability8

Grade 4-AW's machinability is poor (28/100, better than 59% of titanium grades); weldability very good (80/100); formability fair (35/100).

MachinabilityPoor28/100
Machinability Rating (AISI 1212 = 100 %)22%
WeldabilityVery good80/100
Formability (cold)Fair35/100
CastabilityPoor30/100
Brazeability / SolderabilityFair40/100
PolishabilityVery good70/100
Anodizing Responsegood — not a hard/protective coating like on aluminium, but Type II colour anodizing (interference oxide) and Type III (hard/wear pretreatment for implants) are routine on CP Ti Gr4

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Grade 4-AW

Is Grade 4 easy to machine?

Machine with rigid setups, sharp uncoated-carbide or coated inserts, low surface speed (25–45 m/min), heavy feed and flood coolant; never dwell — the low thermal conductivity and chip galling cause work hardening and fire risk from fine chips.

Can Grade 4 be welded?

Readily GTAW/GMAW/EB/laser welded with matching ERTi-4 filler under full argon/helium shielding plus trailing shield and backing gas; keep the weld and HAZ below straw colour, and avoid hydrogen/oxygen/nitrogen pickup which embrittles the joint.

Can Grade 4 be formed, bent or molded?

Cold form with generous bend radii (≈3–4 t) and allow for high springback; warm forming at 200–400 °C markedly improves formability, and hot working/forging is done at 815–955 °C.

What surface finishes work on Grade 4?

Pickle in HNO₃/HF to remove alpha case and scale after hot work, then bead blast, passivate, colour anodize (Type II) or hard anodize/nitride for wear; avoid iron-contaminated abrasives which spoil corrosion resistance.

Grade 4 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nnitrogen, max≤ 0.050.02
Ccarbon, max≤ 0.080.02
Hhydrogen, max (0.0125 for some product forms)≤ 0.020.01
Feiron, max≤ 0.50.3
Ooxygen, max — main strengthener≤ 0.40.34
Residual eachother elements, each≤ 0.1—
Residual totalother elements, total≤ 0.4—
Tibalance, ≈99.0 % minbalance—

Grade 4-AW — frequently asked

What is Grade 4-AW used for?

Grade 4-AW is typically used for aircraft tubing and airframe fittings, surgical instruments and hand tools, orthopaedic and dental components, high-strength fasteners, cryogenic and pressure-vessel parts and chemical plant hardware. In short: high-strength CP titanium.

What is the yield strength of Grade 4-AW?

Grade 4-AW has a typical yield strength of 520 MPa (75.4 ksi) and a tensile strength of 620 MPa (89.9 ksi) — weaker than 60% of titanium grades. Strength varies by condition: see the 5 listed tempers.

Is Grade 4-AW easy to machine?

Not especially — machinability is rated poor (28/100, better than 59% of titanium grades). Machine with rigid setups, sharp uncoated-carbide or coated inserts, low surface speed (25–45 m/min), heavy feed and flood coolant; never dwell — the low thermal conductivity and chip galling cause work hardening and fire risk from fine chips.

Can Grade 4-AW be welded?

Yes — weldability is rated very good (80/100). Readily GTAW/GMAW/EB/laser welded with matching ERTi-4 filler under full argon/helium shielding plus trailing shield and backing gas; keep the weld and HAZ below straw colour, and avoid hydrogen/oxygen/nitrogen pickup which embrittles the joint.

What surface finishes work on Grade 4-AW?

Pickle in HNO₃/HF to remove alpha case and scale after hot work, then bead blast, passivate, colour anodize (Type II) or hard anodize/nitride for wear; avoid iron-contaminated abrasives which spoil corrosion resistance.

Can Grade 4-AW be formed, bent or molded?

Cold form with generous bend radii (≈3–4 t) and allow for high springback; warm forming at 200–400 °C markedly improves formability, and hot working/forging is done at 815–955 °C.

What is the maximum service temperature of Grade 4-AW?

Grade 4-AW is rated for continuous use to about 300°C (572 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Grade 4-O and Grade 4-CW?

O is the default condition — default stocked condition for sheet, plate, bar and tube — best balance of strength, ductility and weldability. CW: use where maximum strength from unalloyed titanium is needed — dental implants, bone screws, high-pressure small-bore tube. Yield strength is 550 MPa in O versus 700 MPa in CW.

Can FabDigit make parts in Grade 4-AW?

Yes — Grade 4-AW is available for CNC machining and sheet metal with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. ASTM B265 — Titanium and Titanium Alloy Strip, Sheet, and Plate — ASTM International (2020)
  2. ASTM B348 — Titanium and Titanium Alloy Bars and Billets — ASTM International (2021)
  3. ASTM F67 — Unalloyed Titanium for Surgical Implant Applications — ASTM International (2017)
  4. AWS A5.16 — Titanium and Titanium-Alloy Welding Electrodes and Rods — AWS (2013)
  5. GB/T 3621 — (TA4) — SAC (2022)
  6. ASM Handbook Vol.2 — Properties and Selection: Nonferrous Alloys — ASM International (1990)
  7. ASM Handbook Vol.13B / Vol.16 — Corrosion and Machining — ASM International (2005)
  8. CP Titanium Grade 4 mill product data — TIMET / Baoji Titanium (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.