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Stainless Steel 431 · temper

Stainless Steel 431 Annealed

Properties of the Annealed condition, compared with the other 431 tempers.

Stock condition for machining and subsequent heat treatment; note 431 is still quite strong when annealed because it air-hardens.

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What is 431 Annealed?

431 Annealed is 431 in the Annealed temper — stock condition for machining and subsequent heat treatment; note 431 is still quite strong when annealed because it air-hardens. 431 Annealed has a yield strength of 655 MPa (95 ksi) and a tensile strength of 830 MPa (120 ksi) — stronger than 90% of stainless steel grades. Elongation at break is 22% and the elastic modulus is 200 GPa (29 Msi). 431 Annealed has a density of 7.75 g/cm³ (0.28 lb/in³), lighter than 66% of stainless steel grades. It melts at 1,425°C (2,597 °F). Hardened & Tempered is the default condition FabDigit quotes; Annealed is available on request or by drawing note.

Advantages

  • High strength — 655 MPa (95 ksi), better than 90% of stainless steel grades
  • Conducts heat well — 20.2 W/m·K (11.7 BTU/hr·ft·°F), better than 75% of stainless steel grades

Limitations

  • Difficult to weld — 25/100, worse than 92% of stainless steel grades
  • Low fracture toughness — 80 MPa·√m (72.8 ksi·√in), worse than 83% of stainless steel grades
  • Needs corrosion protection — 46/100, worse than 82% of stainless steel grades
  • Limited ductility — 22%, worse than 76% of stainless steel grades

431 Annealed properties

Typical room-temperature values for 431 Annealed — 15 properties are specific to this condition; the rest are grade-level values shared by every 431 temper. Each bar shows where the value sits among the stainless steel grades in FabDigit's library — further right is higher.

Physical3

431 Annealed has a density of 7.75 g/cm³ (0.28 lb/in³), lighter than 66% of stainless steel grades. It melts at 1,425°C (2,597 °F).

Density7.75 g/cm³0.28 lb/in³
Melting Point (Solidus)1,425°C2,597 °F
Liquidus Temperature1,510°C2,750 °F

Mechanical16

431 Annealed has a yield strength of 655 MPa (95 ksi) and a tensile strength of 830 MPa (120 ksi) — stronger than 90% of stainless steel grades. Elongation at break is 22% and the elastic modulus is 200 GPa (29 Msi).

Elastic (Young's) Modulus200 GPa29 Msi
Shear Modulus77 GPa11.2 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.29
Tensile Strength (Ultimate)830 MPa120 ksi
Yield Strength (0.2% offset)655 MPa95 ksi
Elongation at Break22%
Reduction in Area50%
Compressive Strength790 MPa115 ksi
Shear Strength520 MPa75.4 ksi
Fatigue Strength (Endurance Limit)390 MPa56.6 ksi
Fracture Toughness (K_IC)80 MPa·√m72.8 ksi·√in
Charpy V-Notch Impact (RT)55 J40.6 ft·lbf
Hardness, Brinell262 HB
Hardness, Rockwell C26 HRC
Hardness, Vickers275 HV

Thermal6

431 Annealed is rated for continuous service to 550°C (1,022 °F). It conducts heat at 20.2 W/m·K (11.7 BTU/hr·ft·°F), better than 75% of stainless steel grades. Thermal expansion is 11.7 µm/m·K (6.5 µin/in·°F).

Thermal Conductivity20.2 W/m·K11.7 BTU/hr·ft·°F
Specific Heat Capacity460 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)11.7 µm/m·K6.5 µin/in·°F
Latent Heat of Fusion260 J/g112 BTU/lb
Max Service Temperature (continuous)550°C1,022 °F
Min Service Temperature-30°C-22 °F

Electrical3

431 Annealed conducts electricity at 2.4 % IACS, better than 67% of stainless steel grades.

Electrical Conductivity2.4 % IACS
Electrical Resistivity7.2×10⁻⁷ Ω·m28.3 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is fair (46/100), worse than 82% of stainless steel grades.

Galvanic Potential (seawater, vs SCE)-0.3 V
Corrosion ResistanceFair46/100
Chemical Resistance SummaryGood in rural/urban atmospheres, fresh water, steam, weak organic acids and mild alkalis when hardened and tempered below 370 °C or above 570 °C; pits in chlorides/seawater with stagnation, and is attacked by hot dilute mineral acids, ferric chloride and strong reducing acids.

Sustainability4

Producing a kilogram of 431 Annealed takes about 53 MJ of energy and emits 4.2 kg of CO₂ — less than 67% of stainless steel grades. Typical recycled content is 50%.

Embodied Energy (primary production)53 MJ/kg22,786 BTU/lb
Embodied Carbon (primary production)4.2 kg CO₂/kg
Embodied Water140 L/kg16.8 gal/lb
Typical Recycled Content50%

Manufacturability7

431 Annealed's machinability is fair (42/100, better than 79% of stainless steel grades); weldability poor (25/100); formability fair (35/100).

MachinabilityFair42/100
Machinability Rating (AISI 1212 = 100 %)45%
WeldabilityPoor25/100
Formability (cold)Fair35/100
Brazeability / SolderabilityFair45/100
PolishabilityVery good70/100
Anodizing Responsen/a — ferrous alloy; use passivation (ASTM A967) or hard chrome/electroless nickel instead

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Other 431 tempers and conditions

431 is also supplied in 7 other conditions. The full side-by-side table is on the 431 overview.

Working with 431 Annealed

Is 431 easy to machine?

Machine in the annealed or ≤32 HRC condition with rigid setups, sharp carbide, positive rake, heavy flood coolant and constant feed to avoid work hardening; expect ~40 % of 1212 and use ground/turned bar for finish-critical diameters.

Can 431 be welded?

Best avoided — air-hardening HAZ cracks readily; if required, preheat 200–300 °C, use 309/310 or matching 431 filler, weld hot and immediately post-weld temper at 620–650 °C, then slow cool.

Can 431 be formed, bent or molded?

Hot work 1150–900 °C then slow cool/anneal; cold forming is limited to gentle bends in the annealed state, and all forming should be done before hardening.

What surface finishes work on 431?

Passivate per ASTM A967 after machining/grinding; polishes to a bright finish and takes hard chrome, electroless nickel or nitriding — do not bake or plate-relieve in the 370–570 °C embrittlement window.

431 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
CASTM A276 S43100: 0.20 max; EN 1.4057: 0.12–0.220.12 – 0.20.17
Si≤ 10.5
Mn≤ 10.6
P≤ 0.040.03
SEN 1.4057 S ≤ 0.015; free-machining sulphurised versions (BS 431S29 type) run higher≤ 0.030.02
Cr15 – 1716
NiEN 1.4057: 1.5–2.51.25 – 2.52
Monot specified in ASTM; EN permits residual Mo ≤ 0.8≤ 0.8
Febalance

431 Annealed — frequently asked

What is 431 Annealed used for?

431 Annealed is typically used for marine propeller and rudder shafts, pump and mixer shafts, high-strength bolts and studs, valve stems and spindles, steam and gas turbine blades and aerospace fittings and linkages. In short: high-strength martensitic shafting.

What is the yield strength of 431 Annealed?

431 Annealed has a typical yield strength of 655 MPa (95 ksi) and a tensile strength of 830 MPa (120 ksi) — stronger than 90% of stainless steel grades. Strength varies by condition: see the 8 listed tempers.

Is 431 Annealed easy to machine?

Not especially — machinability is rated fair (42/100, better than 79% of stainless steel grades). Machine in the annealed or ≤32 HRC condition with rigid setups, sharp carbide, positive rake, heavy flood coolant and constant feed to avoid work hardening; expect ~40 % of 1212 and use ground/turned bar for finish-critical diameters.

Can 431 Annealed be welded?

Not readily — weldability is rated poor (25/100). Best avoided — air-hardening HAZ cracks readily; if required, preheat 200–300 °C, use 309/310 or matching 431 filler, weld hot and immediately post-weld temper at 620–650 °C, then slow cool.

What surface finishes work on 431 Annealed?

Passivate per ASTM A967 after machining/grinding; polishes to a bright finish and takes hard chrome, electroless nickel or nitriding — do not bake or plate-relieve in the 370–570 °C embrittlement window.

Can 431 Annealed be formed, bent or molded?

Hot work 1150–900 °C then slow cool/anneal; cold forming is limited to gentle bends in the annealed state, and all forming should be done before hardening.

What is the maximum service temperature of 431 Annealed?

431 Annealed is rated for continuous use to about 550°C (1,022 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in 431 Annealed?

Yes — 431 Annealed is available for CNC machining and sheet metal with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. ASTM A276/A276M — Stainless Steel Bars and ShapesASTM International (2023)
  2. ASTM A582/A582M — Free-Machining Stainless Steel BarsASTM International (2021)
  3. EN 10088-3 — Stainless steels: semi-finished products, bars, rods (X17CrNi16-2, 1.4057)CEN (2014)
  4. AMS 5628 — Steel Bars, Forgings, 16Cr–2.0NiSAE International (2018)
  5. GB/T 1220 — (14Cr17Ni2)SAC (2007)
  6. ASM Handbook Vol. 1: Properties and Selection — Irons, Steels and High-Performance AlloysASM International (1990)
  7. Martensitic stainless steel 1.4057/431 bar datasheetEuropean long-product mill (typical values) (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.