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Solder & Low-Melting Alloy Lead-Calcium-Tin-AA (Artificially aged)

Precip hard

Pick when grids must reach handling/pasting strength within hours instead of weeks.

Standard cost $$

Values for the AA condition

Other Lead-Calcium-Tin tempers and conditions

Lead-Calcium-Tin is listed in 5 conditions; see the grade overview at Lead-Calcium-Tin.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
As fabricated
Condition of gravity/book-mould cast grids immediately after casting; soft and easily distorted until aged.1528357 HB7.2 % IACS
CAST-AGEDDefault
book-mould cast grid after room-temperature age hardening (≈30 days)
Standard condition of cast battery grids in service; peak precipitation hardening at ambient temperature.30452516 HB7.5 % IACS
AAThis page
Artificially aged
Pick when grids must reach handling/pasting strength within hours instead of weeks.33482018 HB7.6 % IACS
Cold rolled
Rolled strip for expanded-metal and punched grids; worked structure gives the highest as-produced strength.40552218 HB7.3 % IACS
cold-rolled strip after full age hardening
Highest-strength, most creep-resistant condition; used for thin expanded grids in maintenance-free batteries.50651821 HB7.3 % IACS

What is Lead-Calcium-Tin-AA?

Lead-Calcium-Tin-AA is Lead-Calcium-Tin in the AA condition — pick when grids must reach handling/pasting strength within hours instead of weeks. Lead-Calcium-Tin-AA has a yield strength of 33 MPa (4.79 ksi) and a tensile strength of 48 MPa (6.96 ksi) — stronger than 77% of solder & low-melting alloy grades. Elongation at break is 20% and the elastic modulus is 15 GPa (2.18 Msi). Lead-Calcium-Tin-AA has a density of 11.3 g/cm³ (0.408 lb/in³), heavier than 96% of solder & low-melting alloy grades. It melts at 320°C (608 °F). CAST-AGED is the default condition FabDigit quotes; AA is available on request or by drawing note.

Advantages

  • Low embodied carbon — 1.8 kg CO₂/kg, better than 98% of solder & low-melting alloy grades
  • Readily welded — 60/100, better than 92% of solder & low-melting alloy grades
  • Good corrosion resistance — 55/100, better than 78% of solder & low-melting alloy grades
  • High strength — 33 MPa (4.79 ksi), better than 77% of solder & low-melting alloy grades

Limitations

  • Heavy — 11.3 g/cm³ (0.408 lb/in³), worse than 96% of solder & low-melting alloy grades
  • Low stiffness — 15 GPa (2.18 Msi), worse than 91% of solder & low-melting alloy grades
  • Hard to polish — 20/100, worse than 88% of solder & low-melting alloy grades
  • Limited ductility — 20%, worse than 82% of solder & low-melting alloy grades
  • Low electrical conductivity — 7.6 % IACS, worse than 77% of solder & low-melting alloy grades

Lead-Calcium-Tin-AA properties

Typical room-temperature values for Lead-Calcium-Tin-AA; 17 are specific to this condition. Other listed values are Lead-Calcium-Tin reference data and may not represent this condition. Bars are the position among solder & low-melting alloy grades.

Physical3

Lead-Calcium-Tin-AA has a density of 11.3 g/cm³ (0.408 lb/in³), heavier than 96% of solder & low-melting alloy grades. It melts at 320°C (608 °F).

Density11.3 g/cm³0.41 lb/in³
Melting Point (Solidus)320°C608 °F
Liquidus Temperature327°C621 °F

Mechanical12

Lead-Calcium-Tin-AA has a yield strength of 33 MPa (4.79 ksi) and a tensile strength of 48 MPa (6.96 ksi) — stronger than 77% of solder & low-melting alloy grades. Elongation at break is 20% and the elastic modulus is 15 GPa (2.18 Msi).

Elastic (Young's) Modulus15 GPa2.2 Msi
Shear Modulus5.6 GPa0.81 Msi
Bulk Modulus45 GPa6.5 Msi
Poisson's Ratio0.44
Tensile Strength (Ultimate)48 MPa7 ksi
Yield Strength (0.2% offset)33 MPa4.8 ksi
Elongation at Break20%
Reduction in Area28%
Shear Strength27 MPa3.9 ksi
Fatigue Strength (Endurance Limit)13 MPa1.9 ksi
Hardness, Brinell18 HB
Hardness, Vickers19 HV

Thermal6

Lead-Calcium-Tin-AA is rated for continuous service to 100°C (212 °F). It conducts heat at 33 W/m·K (19.1 BTU/hr·ft·°F), worse than 76% of solder & low-melting alloy grades. Thermal expansion is 29 µm/m·K (16.1 µin/in·°F).

Thermal Conductivity33 W/m·K19.1 BTU/hr·ft·°F
Specific Heat Capacity130 J/kg·K0.03 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)29 µm/m·K16.1 µin/in·°F
Latent Heat of Fusion23 J/g9.9 BTU/lb
Max Service Temperature (continuous)100°C212 °F
Min Service Temperature-60°C-76 °F

Electrical3

Lead-Calcium-Tin-AA conducts electricity at 7.6 % IACS, worse than 77% of solder & low-melting alloy grades.

Electrical Conductivity7.6 % IACS
Electrical Resistivity2.28×10⁻⁷ Ω·m8.98 µΩ·in
Magnetic Responsenon-magnetic (diamagnetic)

Chemical & Environmental3

Corrosion resistance is good (55/100), better than 78% of solder & low-melting alloy grades.

Galvanic Potential (seawater, vs SCE)-0.55 V
Corrosion ResistanceGood55/100
Chemical Resistance SummaryExcellent in sulfuric and phosphoric acid (protective sulfate film) and in most soils; attacked by nitric, acetic and other organic acids, by strong alkalis and by soft/aerated waters.

Sustainability4

Producing a kilogram of Lead-Calcium-Tin-AA takes about 22 MJ of energy and emits 1.8 kg of CO₂ — less than 98% of solder & low-melting alloy grades. Typical recycled content is 75%.

Embodied Energy (primary production)22 MJ/kg9,458 BTU/lb
Embodied Carbon (primary production)1.8 kg CO₂/kg
Embodied Water80 L/kg9.6 gal/lb
Typical Recycled Content75%

Manufacturability7

Lead-Calcium-Tin-AA's machinability is fair (45/100, better than 69% of solder & low-melting alloy grades); weldability good (60/100); formability very good (78/100).

MachinabilityFair45/100
WeldabilityGood60/100
Formability (cold)Very good78/100
CastabilityExcellent85/100
Brazeability / SolderabilityExcellent90/100
PolishabilityPoor20/100
Anodizing Responsen/a — lead alloys are not anodized; surfaces are used bare or converted to PbSO₄/PbO₂ in service.

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Lead-Calcium-Tin-AA

Is Lead-Calcium-Tin easy to machine?

Cuts very easily but smears and loads tools — use sharp positive-rake tooling, high rake, low speed, and wet/HEPA controls for lead dust and swarf.

Can Lead-Calcium-Tin be welded?

Joined by lead burning (oxy-fuel or torch fusion) with matching Pb-Sn filler; keep heat low to avoid Ca burn-off and over-aging of the heat-affected zone.

Can Lead-Calcium-Tin be formed, bent or molded?

Cast at 440–480 °C in book moulds with Al-protected melt to keep Ca in solution; rolls and expands readily, but allow the age-hardening period before handling thin grids.

What surface finishes work on Lead-Calcium-Tin?

Normally left bare — the service PbSO₄/PbO₂ film is the protection; no anodizing or plating, and soldered lugs/straps are made with Pb-Sn alloys.

Lead-Calcium-Tin chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Caprimary hardener, forms Pb₃Ca / (Pb,Sn)₃Ca precipitates0.03 – 0.10.07
Snpositive grids typically ≥0.8 %, negative grids 0.2–0.4 %0.2 – 1.20.6
Almelt-surface protection against Ca oxidation loss0.01 – 0.030.02
Agoptional in Pb-Ca-Sn-Ag creep-resistant variants0 – 0.030
Sbimpurity limit — Sb poisons maintenance-free behaviour≤ 0.01—
Biimpurity limit≤ 0.02—
Cuimpurity limit≤ 0—
Feimpurity limit≤ 0—
Asimpurity limit≤ 0—
Znimpurity limit≤ 0—
Pb≥99 % balance, refined lead base per ASTM B29balance—

Lead-Calcium-Tin-AA — frequently asked

What is Lead-Calcium-Tin-AA used for?

Lead-Calcium-Tin-AA is typically used for lead-acid battery grids and straps, sealed/maintenance-free automotive batteries and stationary standby battery plates. In short: maintenance-free battery grid alloy; age-hardening, antimony-free lead; low gassing and self-discharge.

What is the yield strength of Lead-Calcium-Tin-AA?

Lead-Calcium-Tin-AA has a typical yield strength of 33 MPa (4.79 ksi) and a tensile strength of 48 MPa (6.96 ksi) — stronger than 77% of solder & low-melting alloy grades. Strength varies by condition: see the 5 listed tempers.

Is Lead-Calcium-Tin-AA easy to machine?

Reasonably — machinability is rated fair (45/100, better than 69% of solder & low-melting alloy grades). Cuts very easily but smears and loads tools — use sharp positive-rake tooling, high rake, low speed, and wet/HEPA controls for lead dust and swarf.

Can Lead-Calcium-Tin-AA be welded?

Yes — weldability is rated good (60/100). Joined by lead burning (oxy-fuel or torch fusion) with matching Pb-Sn filler; keep heat low to avoid Ca burn-off and over-aging of the heat-affected zone.

What surface finishes work on Lead-Calcium-Tin-AA?

Normally left bare — the service PbSO₄/PbO₂ film is the protection; no anodizing or plating, and soldered lugs/straps are made with Pb-Sn alloys.

Can Lead-Calcium-Tin-AA be formed, bent or molded?

Cast at 440–480 °C in book moulds with Al-protected melt to keep Ca in solution; rolls and expands readily, but allow the age-hardening period before handling thin grids.

What is the maximum service temperature of Lead-Calcium-Tin-AA?

Lead-Calcium-Tin-AA is rated for continuous use to about 100°C (212 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Lead-Calcium-Tin CAST-AGED and Lead-Calcium-Tin CR-AGED?

CAST-AGED is the default condition — standard condition of cast battery grids in service; peak precipitation hardening at ambient temperature. CR-AGED: highest-strength, most creep-resistant condition; used for thin expanded grids in maintenance-free batteries. Yield strength is 30 MPa in CAST-AGED versus 50 MPa in CR-AGED.

Sources

  1. ASTM B989 — Lead-Calcium-Tin alloy for battery grid applications — ASTM International (2020)
  2. ASTM B29 — Refined Lead — ASTM International (2020)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys (Lead and Lead Alloys) — ASM International (1990)
  4. ASM Handbook Vol. 13B — Corrosion of Lead and Lead Alloys — ASM International (2005)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.