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Stainless Steel E33-31-AW (As-welded deposit)

Heat-treated state · default condition

UNS W33310

Standard stocked condition: covered-electrode deposit used in the as-welded state for acid-service fabrication and repair.

High cost $$$$

Values for the AW condition

Other E33-31 tempers and conditions

E33-31 is listed in 3 conditions; see the grade overview at E33-31.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Weldment solution annealed ~1120–1180 °C and quenched
Choose when the fabricated component can be re-solution-annealed to dissolve interdendritic precipitates and restore maximum ductility and acid resistance.41079045210 HB1.9 % IACS
AWDefaultThis page
As-welded deposit
Standard stocked condition: covered-electrode deposit used in the as-welded state for acid-service fabrication and repair.4807603321 HRC1.9 % IACS
AW-GTAW/GMAW
Pick for root passes, thin-wall and high-purity acid-service welds where the cleaner, slightly tougher bare-wire deposit is required.50078038225 HB1.9 % IACS

What is E33-31-AW?

E33-31-AW is E33-31 heat treated to AW — standard stocked condition: covered-electrode deposit used in the as-welded state for acid-service fabrication and repair. E33-31-AW has a yield strength of 480 MPa (69.6 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 75% of stainless steel grades. Elongation at break is 33% and the elastic modulus is 196 GPa (28.4 Msi). E33-31-AW has a density of 7.9 g/cm³ (0.285 lb/in³), heavier than 68% of stainless steel grades. It melts at 1,350°C (2,462 °F).

Advantages

  • Good corrosion resistance — 88/100, better than 97% of stainless steel grades
  • High strength — 480 MPa (69.6 ksi), better than 75% of stainless steel grades

Limitations

  • Difficult to machine — 20/100, worse than 98% of stainless steel grades
  • Poor heat conductor — 12 W/m·K (6.93 BTU/hr·ft·°F), worse than 93% of stainless steel grades
  • High embodied carbon — 6.5 kg CO₂/kg, worse than 93% of stainless steel grades
  • Low electrical conductivity — 1.9 % IACS, worse than 84% of stainless steel grades

E33-31-AW properties

Typical room-temperature values for E33-31-AW; 23 are specific to this condition. Other listed values are E33-31 reference data and may not represent this condition. Bars are the position among stainless steel grades.

Physical3

E33-31-AW has a density of 7.9 g/cm³ (0.285 lb/in³), heavier than 68% of stainless steel grades. It melts at 1,350°C (2,462 °F).

Density7.9 g/cm³0.29 lb/in³
Melting Point (Solidus)1,350°C2,462 °F
Liquidus Temperature1,400°C2,552 °F

Mechanical16

E33-31-AW has a yield strength of 480 MPa (69.6 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 75% of stainless steel grades. Elongation at break is 33% and the elastic modulus is 196 GPa (28.4 Msi).

Elastic (Young's) Modulus196 GPa28.4 Msi
Shear Modulus75 GPa10.9 Msi
Bulk Modulus165 GPa23.9 Msi
Poisson's Ratio0.29
Tensile Strength (Ultimate)760 MPa110 ksi
Yield Strength (0.2% offset)480 MPa69.6 ksi
Elongation at Break33%
Reduction in Area45%
Compressive Strength490 MPa71.1 ksi
Shear Strength455 MPa66 ksi
Fatigue Strength (Endurance Limit)290 MPa42.1 ksi
Charpy V-Notch Impact (RT)65 J47.9 ft·lbf
Hardness, Brinell235 HB
Hardness, Rockwell B98 HRB
Hardness, Rockwell C21 HRC
Hardness, Vickers245 HV

Thermal6

E33-31-AW is rated for continuous service to 550°C (1,022 °F). It conducts heat at 12 W/m·K (6.93 BTU/hr·ft·°F), worse than 93% of stainless steel grades. Thermal expansion is 14.5 µm/m·K (8.06 µin/in·°F).

Thermal Conductivity12 W/m·K6.9 BTU/hr·ft·°F
Specific Heat Capacity435 J/kg·K0.1 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)14.5 µm/m·K8.1 µin/in·°F
Latent Heat of Fusion270 J/g116 BTU/lb
Max Service Temperature (continuous)550°C1,022 °F
Min Service Temperature-100°C-148 °F

Electrical3

E33-31-AW conducts electricity at 1.9 % IACS, worse than 84% of stainless steel grades.

Electrical Conductivity1.9 % IACS
Electrical Resistivity9×10⁻⁷ Ω·m35.4 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (88/100), better than 97% of stainless steel grades.

Galvanic Potential (seawater, vs SCE)-0.08 V
Corrosion ResistanceExcellent88/100
Chemical Resistance SummaryOutstanding in concentrated and hot sulfuric acid (all concentrations at moderate temperature), phosphoric and nitric acid, and chloride-bearing oxidising media; PREN ≈ 50 gives high pitting/crevice and chloride SCC resistance. Weaker in hot reducing hydrochloric acid and in HF; unsuitable for prolonged high-temperature (>600 °C) exposure.

Sustainability4

Producing a kilogram of E33-31-AW takes about 90 MJ of energy and emits 6.5 kg of CO₂ — more than 94% of stainless steel grades. Typical recycled content is 30%.

Embodied Energy (primary production)90 MJ/kg38,693 BTU/lb
Embodied Carbon (primary production)6.5 kg CO₂/kg
Embodied Water240 L/kg28.8 gal/lb
Typical Recycled Content30%

Manufacturability7

E33-31-AW's machinability is poor (20/100, worse than 98% of stainless steel grades); weldability very good (70/100); formability fair (40/100).

MachinabilityPoor20/100
Machinability Rating (AISI 1212 = 100 %)18%
WeldabilityVery good70/100
Formability (cold)Fair40/100
Brazeability / SolderabilityFair45/100
PolishabilityVery good75/100
Anodizing Responsen/a — ferrous alloy; use pickling and passivation instead of anodising

Common Calculations5

Specific Strength (UTS / density)calculated96 kN·m/kg
Specific Stiffness (E / density)calculated24.8 MN·m/kg
Modulus of Resiliencecalculated588 kJ/m³
Thermal Diffusivitycalculated3.5 mm²/s
Thermal Shock Resistance Indexcalculated3

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with E33-31-AW

Is E33-31 easy to machine?

Very poor machinability — high N content gives severe work hardening; use rigid setups, sharp positive-rake carbide, low speed with heavy positive feed and flood coolant.

Can E33-31 be welded?

Weld with low heat input, stringer beads and interpass temperature below ~120 °C; keep electrodes dry (re-bake per producer instruction) and use Ar or Ar+He shielding — avoid N-free backing gas losses and never use oxidising/CO₂-rich mixtures.

Can E33-31 be formed, bent or molded?

Deposit is strong and heavily work hardening; cold straightening of wire/weldment is limited — prefer solution annealing before any significant cold work.

What surface finishes work on E33-31?

Grind off all weld oxide/tint, then pickle and passivate (HNO₃-HF type) to restore the Cr-rich passive film before acid service; can be polished to a bright finish.

E33-31 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Clow carbon for acid service≤ 0.020.01
Cr31 – 3533
Ni30 – 3331
Mo0.5 – 21.6
Cuaids sulfuric acid resistance0.3 – 1.20.6
Naustenite stabiliser and strengthener0.3 – 0.60.4
Mn≤ 20.6
Si≤ 0.80.4
P≤ 0.02—
S≤ 0.01—
Febalance, approx. 30 %balance—

E33-31-AW — frequently asked

What is E33-31-AW used for?

E33-31-AW is typically used for phosphoric acid production, sulfuric acid dew-point equipment and super-austenitic pressure vessels. In short: strongest deposit in family; super-austenitic acid resistance; poor machinability.

What is the yield strength of E33-31-AW?

E33-31-AW has a typical yield strength of 480 MPa (69.6 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 75% of stainless steel grades. Strength varies by condition: see the 3 listed tempers.

Is E33-31-AW easy to machine?

Not especially — machinability is rated poor (20/100, worse than 98% of stainless steel grades). Very poor machinability — high N content gives severe work hardening; use rigid setups, sharp positive-rake carbide, low speed with heavy positive feed and flood coolant.

Can E33-31-AW be welded?

Yes — weldability is rated very good (70/100). Weld with low heat input, stringer beads and interpass temperature below ~120 °C; keep electrodes dry (re-bake per producer instruction) and use Ar or Ar+He shielding — avoid N-free backing gas losses and never use oxidising/CO₂-rich mixtures.

What surface finishes work on E33-31-AW?

Grind off all weld oxide/tint, then pickle and passivate (HNO₃-HF type) to restore the Cr-rich passive film before acid service; can be polished to a bright finish.

Can E33-31-AW be formed, bent or molded?

Deposit is strong and heavily work hardening; cold straightening of wire/weldment is limited — prefer solution annealing before any significant cold work.

What is the maximum service temperature of E33-31-AW?

E33-31-AW is rated for continuous use to about 550°C (1,022 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between E33-31-AW and E33-31-SA?

AW is the default condition — standard stocked condition: covered-electrode deposit used in the as-welded state for acid-service fabrication and repair. SA: choose when the fabricated component can be re-solution-annealed to dissolve interdendritic precipitates and restore maximum ductility and acid resistance. Yield strength is 480 MPa in AW versus 410 MPa in SA.

Sources

  1. AWS A5.4/A5.4M — Specification for Stainless Steel Electrodes for Shielded Metal Arc Welding — American Welding Society (2012)
  2. AWS A5.9/A5.9M — Bare Stainless Steel Welding Electrodes and Rods — American Welding Society (2017)
  3. ASTM B625 / A240 (UNS R20033 requirements) — ASTM International (2021)
  4. VDM Alloy 33 (Nicrofer 3033) material data sheet — VDM Metals (2018)
  5. ASM Handbook Vol. 6 — Welding, Brazing and Soldering (stainless filler metals) — ASM International (1993)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.