FabDigit

PVDC

ISO 1043 PVDC · also Saran

A highly crystalline chlorinated vinyl polymer distinct from PVC, prized for exceptional barrier properties against oxygen, moisture and aroma; used mainly as a coating or thin film rather than a structural plastic.

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Reference datasheet — PVDC is not in the instant-quote catalog. Upload your part and an engineer will quote it in this grade or suggest the closest stocked equivalent.

Values for the VDC-MA condition

PVDC grades and fills

PVDC is supplied in 7 conditions, soft to hard. VDC-MA is the default FabDigit quotes; the values on this page are for it.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Plasticized cling/wrap film grade
Use for soft, self-clinging household and food-wrap film; lowest stiffness and lowest service temperature.122525045 Shore D
Aqueous PVDC dispersion
Pick for water-based coating of paper, board, PET, BOPP or PVC blister film without solvent handling.153060
VDC-MADefault
VDC/methyl-acrylate copolymer
Default barrier resin: choose for monolayer or coextruded high-barrier films and casings where melt processing is required.18348065 Shore D
Heat- and light-stabilized grade
Pick when processing residence time or outdoor exposure would otherwise cause HCl release and yellowing.19347066 Shore D
VDC/vinyl-chloride copolymer
Use where higher Tg and solvent-solubility for lacquer coating or blister-film coating are wanted.25405070 Shore D
VDC/acrylonitrile copolymer
Choose for solvent-borne barrier lacquers on paper, cellophane and PET where good film clarity and adhesion are needed.28403072 Shore D
PVDC homopolymer
Pick only when maximum crystallinity/barrier is needed and processing is by solution or sintering — melt processing is impractical.40451575 Shore D

Supply forms, finishes and certifications

Ways PVDC is supplied — form, process route, surface or paperwork — without a datasheet of their own. The property values above apply.

OptionWhat it isType
FIBER
Monofilament / fiber gradeSupply form
BO
Biaxially oriented / heat-shrink barrier filmSurface finish
FOOD
Food-contact / pharmaceutical gradeCertification

What is PVDC?

A highly crystalline chlorinated vinyl polymer distinct from PVC, prized for exceptional barrier properties against oxygen, moisture and aroma; used mainly as a coating or thin film rather than a structural plastic. PVDC has a density of 1.68 g/cm³ (0.0607 lb/in³), heavier than 94% of polymer grades. Its glass-transition temperature is -15°C (5 °F). PVDC has a yield strength of 18 MPa (2.61 ksi) and a tensile strength of 34 MPa (4.93 ksi) — weaker than 82% of polymer grades. Elongation at break is 80% and the elastic modulus is 0.5 GPa (0.0725 Msi).

What is PVDC used for?

  • food packaging film
  • barrier coatings on PET/PP film
  • sausage casings
  • moisture/oxygen barrier layers
  • industrial coatings

Advantages

  • Readily welded — 85/100, better than 89% of polymer grades
  • Low moisture uptake — 0.05%, better than 84% of polymer grades

Limitations

  • Heavy — 1.68 g/cm³ (0.0607 lb/in³), worse than 94% of polymer grades
  • Difficult to machine — 30/100, worse than 87% of polymer grades
  • Low strength — 18 MPa (2.61 ksi), worse than 82% of polymer grades
  • Poor heat conductor — 0.13 W/m·K (0.0751 BTU/hr·ft·°F), worse than 82% of polymer grades

PVDC properties

Typical room-temperature values for PVDC-VDC-MA; bars are the position among polymer grades.

Physical7

PVDC has a density of 1.68 g/cm³ (0.0607 lb/in³), heavier than 94% of polymer grades. Its glass-transition temperature is -15°C (5 °F).

Density1.68 g/cm³0.06 lb/in³
Melting Temperature (Tm)165°C329 °F
Glass Transition (Tg)-15°C5 °F
Water Absorption (24 h)0.05%
Water Absorption (Saturation)0.1%
Refractive Index1.61
Light Transmission88%

Mechanical15

PVDC has a yield strength of 18 MPa (2.61 ksi) and a tensile strength of 34 MPa (4.93 ksi) — weaker than 82% of polymer grades. Elongation at break is 80% and the elastic modulus is 0.5 GPa (0.0725 Msi).

Elastic (Young's) Modulus0.5 GPa0.07 Msi
Shear Modulus0.18 GPa0.03 Msi
Bulk Modulus0.9 GPa0.13 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)34 MPa4.9 ksi
Yield Strength (0.2% offset)18 MPa2.6 ksi
Elongation at Break80%
Compressive Strength45 MPa6.5 ksi
Flexural Strength30 MPa4.4 ksi
Flexural Modulus0.5 GPa0.07 Msi
Shear Strength22 MPa3.2 ksi
Izod Impact, Notched55 J/m1 ft·lbf/in
Hardness, Shore D65 Shore D
Hardness, Rockwell R100 HRR
Tear Strength12 kN/m68.5 lbf/in

Thermal10

PVDC is rated for continuous service to 75°C (167 °F). It conducts heat at 0.13 W/m·K (0.0751 BTU/hr·ft·°F), worse than 82% of polymer grades. Thermal expansion is 158 µm/m·K (87.8 µin/in·°F).

Thermal Conductivity0.13 W/m·K0.08 BTU/hr·ft·°F
Specific Heat Capacity1,150 J/kg·K0.27 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)158 µm/m·K87.8 µin/in·°F
Max Service Temperature (continuous)75°C167 °F
Min Service Temperature-20°C-4 °F
Heat Deflection Temp. @ 0.45 MPa60°C140 °F
Vicat Softening Point (B50)70°C158 °F
Flammability (UL 94)V-0 (self-extinguishing; high chlorine content, but evolves HCl)
Limiting Oxygen Index60%
Max Service Temperature (short-term)100°C212 °F

Electrical5

PVDC is an electrical insulator with a dielectric strength of 18 kV/mm (457.2 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength18 kV/mm457 V/mil
Dielectric Constant (1 MHz)3.5
Dissipation Factor (1 MHz)0.03
Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental3

Corrosion resistance is excellent (88/100), better than 74% of polymer grades. UV resistance is fair.

Corrosion ResistanceExcellent88/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryExcellent against water, dilute acids and alkalis, salts, alcohols, oils, fats and aliphatic hydrocarbons; outstanding gas/aroma barrier. Attacked or swollen by ketones, esters, THF, DMF, cyclohexanone and hot chlorinated solvents; degrades (HCl release, browning) above ~150 °C and under strong UV or amine contact.

Sustainability3

Producing a kilogram of PVDC takes about 80 MJ of energy and emits 3.6 kg of CO₂ — less than 85% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)80 MJ/kg34,394 BTU/lb
Embodied Carbon (primary production)3.6 kg CO₂/kg
Typical Recycled Content0%

Manufacturability7

PVDC's machinability is poor (30/100, worse than 87% of polymer grades); weldability excellent (85/100); formability very good (75/100).

MachinabilityPoor30/100
WeldabilityExcellent85/100
Formability (cold)Very good75/100
PolishabilityFair40/100
Mold Shrinkage1.5%
Processing Melt Temperature (typ.)172°C342 °F
Mold Temperature (typ.)30°C86 °F

Common Calculations5

Specific Strength (UTS / density)calculated20 kN·m/kg
Specific Stiffness (E / density)calculated0.3 MN·m/kg
Modulus of Resiliencecalculated324 kJ/m³
Thermal Diffusivitycalculated0.1 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Strength versus weight in the polymer family

Yield strength against density for every polymer grade FabDigit runs. PVDC is highlighted; hover a dot for its name, or open the interactive family chart.

0.1110100123Density (g/cm³)Yield strength (MPa) — log scalePVDC

Working with PVDC

Is PVDC easy to machine?

Rarely machined; if solid stock exists use sharp tools, light cuts and air cooling — frictional heat quickly liberates HCl and discolors the part.

Can PVDC be welded?

Excellent heat sealing and impulse/RF sealing of films at 130–160 °C; solvent bonding possible with THF/MEK blends for lacquer grades.

Can PVDC be formed, bent or molded?

Very narrow melt window (160–185 °C) with short residence time; requires Hastelloy/nickel-alloy screws and dies, purge on shutdown, and low-shear coextrusion with tie layers.

PVDC chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
vinylidene chloride (VDC) monomer unitsmain chain; homopolymer = 100%80 – 9690
methyl acrylate / vinyl chloride / acrylcomonomer type defines commercial grade family4 – 2010
chlorine (elemental content)source of barrier and self-extinguishing behaviour63 – 7368
plasticizer (e.g. dibutyl sebacate, ATBCfilm/wrap grades only0 – 83
heat/light stabilizer + acid scavenger +epoxidized oils, phosphites, waxes0.2 – 31.5

What surface finishes work on PVDC?

Normally used as the barrier ply of a laminate; surface can be corona-treated for printing, but avoid amine-cured inks/adhesives and prolonged UV that dehydrochlorinate the coating.

Equivalent designations

Standards and trade names that resolve to PVDC in FabDigit's catalog. Equivalence is nominal — check the exact specification when certification matters.

ISO
1043 PVDC
Trade names
Saran

How much does PVDC cost?

PVDC is a premium-cost polymer ($$$), cheaper than about 51% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

PVDC — frequently asked

What is PVDC used for?

PVDC is typically used for food packaging film, barrier coatings on PET/PP film, sausage casings, moisture/oxygen barrier layers and industrial coatings. In short: highest-barrier vinyl polymer; coating and film, not structural; very narrow melt window.

What is the yield strength of PVDC?

PVDC has a typical yield strength of 18 MPa (2.61 ksi) and a tensile strength of 34 MPa (4.93 ksi) — weaker than 82% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is PVDC easy to machine?

Not especially — machinability is rated poor (30/100, worse than 87% of polymer grades). Rarely machined; if solid stock exists use sharp tools, light cuts and air cooling — frictional heat quickly liberates HCl and discolors the part.

Can PVDC be welded?

Yes — weldability is rated excellent (85/100). Excellent heat sealing and impulse/RF sealing of films at 130–160 °C; solvent bonding possible with THF/MEK blends for lacquer grades.

What surface finishes work on PVDC?

Normally used as the barrier ply of a laminate; surface can be corona-treated for printing, but avoid amine-cured inks/adhesives and prolonged UV that dehydrochlorinate the coating.

Can PVDC be formed, bent or molded?

Very narrow melt window (160–185 °C) with short residence time; requires Hastelloy/nickel-alloy screws and dies, purge on shutdown, and low-shear coextrusion with tie layers.

What is the maximum service temperature of PVDC?

PVDC is rated for continuous use to about 75°C (167 °F), and briefly to 100°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PVDC VDC-MA and PVDC HOMO?

VDC-MA is the default condition — default barrier resin: choose for monolayer or coextruded high-barrier films and casings where melt processing is required. HOMO: pick only when maximum crystallinity/barrier is needed and processing is by solution or sintering — melt processing is impractical. Yield strength is 18 MPa in VDC-MA versus 40 MPa in HOMO.

How much does PVDC cost?

PVDC is a premium-cost polymer ($$$), cheaper than about 51% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Sources

  1. ISO 1043-1 Plastics — Symbols and abbreviated terms — ISO (2011)
  2. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)
  3. Polymer Handbook, 4th ed. — Wiley (1999)
  4. SARAN barrier resins — product and processing data — Dow / SK Functional Polymer (2020)
  5. IXAN / DIOFAN PVDC resins and latices technical data — Solvay / Solvin (2019)
  6. Krehalon PVDC barrier and shrink films — Kureha (2021)

Property data is compiled from published supplier and standards handbooks and normalised for comparison; hardness values on non-Brinell scales are converted approximately for charting only. Manufacturability limits are FabDigit quote-engine defaults and may be relaxed by engineering review. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.