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PVDC HOMO

Grade

ISO 1043 PVDC · also Saran

HOMO = pVDC homopolymer

Pick only when maximum crystallinity/barrier is needed and processing is by solution or sintering — melt processing is impractical.

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Values for the HOMO condition

Other PVDC grades and fills

PVDC is listed in 7 conditions; see the grade overview at PVDC.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Plasticized cling/wrap film grade
Use for soft, self-clinging household and food-wrap film; lowest stiffness and lowest service temperature.122525045 Shore D
Aqueous PVDC dispersion
Pick for water-based coating of paper, board, PET, BOPP or PVC blister film without solvent handling.153060—
VDC-MADefault
VDC/methyl-acrylate copolymer
Default barrier resin: choose for monolayer or coextruded high-barrier films and casings where melt processing is required.18348065 Shore D
Heat- and light-stabilized grade
Pick when processing residence time or outdoor exposure would otherwise cause HCl release and yellowing.19347066 Shore D
VDC/vinyl-chloride copolymer
Use where higher Tg and solvent-solubility for lacquer coating or blister-film coating are wanted.25405070 Shore D
VDC/acrylonitrile copolymer
Choose for solvent-borne barrier lacquers on paper, cellophane and PET where good film clarity and adhesion are needed.28403072 Shore D
HOMOThis page
PVDC homopolymer
Pick only when maximum crystallinity/barrier is needed and processing is by solution or sintering — melt processing is impractical.40451575 Shore D

What is PVDC HOMO?

PVDC HOMO is PVDC in the HOMO grade — pick only when maximum crystallinity/barrier is needed and processing is by solution or sintering — melt processing is impractical. PVDC HOMO has a yield strength of 40 MPa (5.8 ksi) and a tensile strength of 45 MPa (6.53 ksi) — weaker than 63% of polymer grades. Elongation at break is 15% and the elastic modulus is 1 GPa (0.145 Msi). PVDC HOMO has a density of 1.88 g/cm³ (0.0677 lb/in³), heavier than 97% of polymer grades. Its glass-transition temperature is -17°C (1 °F). VDC-MA is the default condition FabDigit quotes; HOMO is available on request or by drawing note.

Advantages

  • Low moisture uptake — 0.05%, better than 84% of polymer grades
  • Good corrosion resistance — 90/100, better than 82% of polymer grades

Limitations

  • Heavy — 1.88 g/cm³ (0.0677 lb/in³), worse than 97% of polymer grades
  • Difficult to machine — 35/100, worse than 84% of polymer grades
  • Poor heat conductor — 0.13 W/m·K (0.0751 BTU/hr·ft·°F), worse than 82% of polymer grades

PVDC HOMO properties

Typical room-temperature values for PVDC HOMO; 25 are specific to this condition. Other listed values are PVDC reference data and may not represent this condition. Bars are the position among polymer grades.

Physical7

PVDC HOMO has a density of 1.88 g/cm³ (0.0677 lb/in³), heavier than 97% of polymer grades. Its glass-transition temperature is -17°C (1 °F).

Density1.88 g/cm³0.07 lb/in³
Melting Temperature (Tm)202°C396 °F
Glass Transition (Tg)-17°C1 °F
Water Absorption (24 h)0.05%
Water Absorption (Saturation)0.1%
Refractive Index1.61
Light Transmission88%

Mechanical15

PVDC HOMO has a yield strength of 40 MPa (5.8 ksi) and a tensile strength of 45 MPa (6.53 ksi) — weaker than 63% of polymer grades. Elongation at break is 15% and the elastic modulus is 1 GPa (0.145 Msi).

Elastic (Young's) Modulus1 GPa0.15 Msi
Shear Modulus0.18 GPa0.03 Msi
Bulk Modulus0.9 GPa0.13 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)45 MPa6.5 ksi
Yield Strength (0.2% offset)40 MPa5.8 ksi
Elongation at Break15%
Compressive Strength70 MPa10.2 ksi
Flexural Strength60 MPa8.7 ksi
Flexural Modulus1.1 GPa0.16 Msi
Shear Strength30 MPa4.4 ksi
Izod Impact, Notched25 J/m0.47 ft·lbf/in
Hardness, Shore D75 Shore D
Hardness, Rockwell R110 HRR
Tear Strength12 kN/m68.5 lbf/in

Thermal10

PVDC HOMO is rated for continuous service to 85°C (185 °F). It conducts heat at 0.13 W/m·K (0.0751 BTU/hr·ft·°F), worse than 82% of polymer grades. Thermal expansion is 158 µm/m·K (87.8 µin/in·°F).

Thermal Conductivity0.13 W/m·K0.08 BTU/hr·ft·°F
Specific Heat Capacity1,150 J/kg·K0.27 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)158 µm/m·K87.8 µin/in·°F
Max Service Temperature (continuous)85°C185 °F
Min Service Temperature-20°C-4 °F
Heat Deflection Temp. @ 0.45 MPa90°C194 °F
Vicat Softening Point (B50)95°C203 °F
Flammability (UL 94)V-0 (self-extinguishing; high chlorine content, but evolves HCl)
Limiting Oxygen Index62%
Max Service Temperature (short-term)100°C212 °F

Electrical5

PVDC HOMO is an electrical insulator with a dielectric strength of 18 kV/mm (457.2 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength18 kV/mm457 V/mil
Dielectric Constant (1 MHz)3.5
Dissipation Factor (1 MHz)0.03
Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental3

Corrosion resistance is excellent (90/100), better than 82% of polymer grades. UV resistance is fair.

Corrosion ResistanceExcellent90/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryExcellent against water, dilute acids and alkalis, salts, alcohols, oils, fats and aliphatic hydrocarbons; outstanding gas/aroma barrier. Attacked or swollen by ketones, esters, THF, DMF, cyclohexanone and hot chlorinated solvents; degrades (HCl release, browning) above ~150 °C and under strong UV or amine contact.

Sustainability3

Producing a kilogram of PVDC HOMO takes about 80 MJ of energy and emits 3.6 kg of CO₂ — less than 85% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)80 MJ/kg34,394 BTU/lb
Embodied Carbon (primary production)3.6 kg CO₂/kg
Typical Recycled Content0%

Manufacturability7

PVDC HOMO's machinability is fair (35/100, worse than 84% of polymer grades); weldability fair (40/100); formability poor (25/100).

MachinabilityFair35/100
WeldabilityFair40/100
Formability (cold)Poor25/100
PolishabilityFair40/100
Mold Shrinkage1.5%
Processing Melt Temperature (typ.)172°C342 °F
Mold Temperature (typ.)30°C86 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PVDC HOMO

Is PVDC easy to machine?

Rarely machined; if solid stock exists use sharp tools, light cuts and air cooling — frictional heat quickly liberates HCl and discolors the part.

Can PVDC be welded?

Excellent heat sealing and impulse/RF sealing of films at 130–160 °C; solvent bonding possible with THF/MEK blends for lacquer grades.

Can PVDC be formed, bent or molded?

Very narrow melt window (160–185 °C) with short residence time; requires Hastelloy/nickel-alloy screws and dies, purge on shutdown, and low-shear coextrusion with tie layers.

What surface finishes work on PVDC?

Normally used as the barrier ply of a laminate; surface can be corona-treated for printing, but avoid amine-cured inks/adhesives and prolonged UV that dehydrochlorinate the coating.

PVDC chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
vinylidene chloride (VDC) monomer unitsmain chain; homopolymer = 100%80 – 9690
methyl acrylate / vinyl chloride / acrylcomonomer type defines commercial grade family4 – 2010
chlorine (elemental content)source of barrier and self-extinguishing behaviour63 – 7368
plasticizer (e.g. dibutyl sebacate, ATBCfilm/wrap grades only0 – 83
heat/light stabilizer + acid scavenger +epoxidized oils, phosphites, waxes0.2 – 31.5

PVDC HOMO — frequently asked

What is PVDC HOMO used for?

PVDC HOMO is typically used for food packaging film, barrier coatings on PET/PP film, sausage casings, moisture/oxygen barrier layers and industrial coatings. In short: highest-barrier vinyl polymer; coating and film, not structural; very narrow melt window.

What is the yield strength of PVDC HOMO?

PVDC HOMO has a typical yield strength of 40 MPa (5.8 ksi) and a tensile strength of 45 MPa (6.53 ksi) — weaker than 63% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is PVDC HOMO easy to machine?

Not especially — machinability is rated fair (35/100, worse than 84% of polymer grades). Rarely machined; if solid stock exists use sharp tools, light cuts and air cooling — frictional heat quickly liberates HCl and discolors the part.

Can PVDC HOMO be welded?

With care — weldability is rated fair (40/100). Excellent heat sealing and impulse/RF sealing of films at 130–160 °C; solvent bonding possible with THF/MEK blends for lacquer grades.

What surface finishes work on PVDC HOMO?

Normally used as the barrier ply of a laminate; surface can be corona-treated for printing, but avoid amine-cured inks/adhesives and prolonged UV that dehydrochlorinate the coating.

Can PVDC HOMO be formed, bent or molded?

Very narrow melt window (160–185 °C) with short residence time; requires Hastelloy/nickel-alloy screws and dies, purge on shutdown, and low-shear coextrusion with tie layers.

What is the maximum service temperature of PVDC HOMO?

PVDC HOMO is rated for continuous use to about 85°C (185 °F), and briefly to 100°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PVDC VDC-MA and PVDC HOMO?

VDC-MA is the default condition — default barrier resin: choose for monolayer or coextruded high-barrier films and casings where melt processing is required. HOMO: pick only when maximum crystallinity/barrier is needed and processing is by solution or sintering — melt processing is impractical. Yield strength is 18 MPa in VDC-MA versus 40 MPa in HOMO.

Sources

  1. ISO 1043-1 Plastics — Symbols and abbreviated terms — ISO (2011)
  2. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)
  3. Polymer Handbook, 4th ed. — Wiley (1999)
  4. SARAN barrier resins — product and processing data — Dow / SK Functional Polymer (2020)
  5. IXAN / DIOFAN PVDC resins and latices technical data — Solvay / Solvin (2019)
  6. Krehalon PVDC barrier and shrink films — Kureha (2021)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.