FabDigit

PMMA HH

Grade

also Acrylite, Perspex

HH = heat-resistant / high-Tg acrylic copolymer

Pick when clarity must survive lamp housings, headlight lenses or autoclave-adjacent temperatures above 100 °C.

Values for the HH condition

Other PMMA grades and fills

PMMA is listed in 8 conditions; see the grade overview at PMMA.

Compare all 8 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
rubber-toughened acrylic (HI-PMMA / acrylic-impact blends)
Use where clarity is still needed but breakage or notch sensitivity is the failure mode — machine guards, signage, POP displays.47503560 HRM
FR V-0
For lighting diffusers, transit glazing and electrical enclosures needing UL 94 V-0 or low smoke; expect some loss of clarity and toughness.5658387 Shore D
UV-absorber stabilised outdoor grade
For long-life outdoor glazing, signage faces and automotive lenses, or to shield UV-sensitive contents behind the sheet.68704.589 Shore D
ExtrudedDefault
standard extruded sheet / general purpose grade
Lowest-cost transparent acrylic sheet with tight thickness tolerance; best for thermoforming, laser cutting and signage.704.592 HRM
General-purpose injection-molding pellet grade
Free-flowing pellet grade for thin-wall transparent moldings; dry 4 h at 80 °C before molding.7072490 Shore D
low-birefringence, high-purity molding/sheet grade
Pick for lenses, light guides, LED optics and display covers where transmission, low haze and low birefringence matter.724
As cast
Choose for machined and polished parts, thick sheet, chemical exposure and laser-engraved work — higher MW gives better crazing and thermal resistance.764100 HRM
HHThis page
Heat-resistant / high-Tg acrylic copolymer
Pick when clarity must survive lamp housings, headlight lenses or autoclave-adjacent temperatures above 100 °C.763.5

What is PMMA HH?

PMMA HH is PMMA in the HH grade — pick when clarity must survive lamp housings, headlight lenses or autoclave-adjacent temperatures above 100 °C. PMMA HH has a yield strength of 68 MPa (9.86 ksi) and a tensile strength of 76 MPa (11 ksi) — stronger than 77% of polymer grades. Elongation at break is 3.5% and the elastic modulus is 3.2 GPa (0.464 Msi). PMMA HH has a density of 1.19 g/cm³ (0.043 lb/in³), heavier than 53% of polymer grades. Its glass-transition temperature is 125°C (257 °F). Extruded is the default condition FabDigit quotes; HH is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 96/100, better than 99% of polymer grades
  • Good UV / weathering resistance — 92/100, better than 93% of polymer grades
  • High strength — 68 MPa (9.86 ksi), better than 77% of polymer grades
  • Stiff — 3.2 GPa (0.464 Msi), better than 77% of polymer grades

Limitations

  • Limited ductility — 3.5%, worse than 79% of polymer grades
  • Low fracture toughness — 1.2 MPa·√m (1.09 ksi·√in), worse than 77% of polymer grades

PMMA HH properties

Typical room-temperature values for PMMA HH; 10 are specific to this condition. Other listed values are PMMA reference data and may not represent this condition. Bars are the position among polymer grades.

Physical6

PMMA HH has a density of 1.19 g/cm³ (0.043 lb/in³), heavier than 53% of polymer grades. Its glass-transition temperature is 125°C (257 °F).

Density1.19 g/cm³0.04 lb/in³
Glass Transition (Tg)125°C257 °F
Water Absorption (24 h)0.3%
Water Absorption (Saturation)2%
Refractive Index1.491
Light Transmission92%

Mechanical16

PMMA HH has a yield strength of 68 MPa (9.86 ksi) and a tensile strength of 76 MPa (11 ksi) — stronger than 77% of polymer grades. Elongation at break is 3.5% and the elastic modulus is 3.2 GPa (0.464 Msi).

Elastic (Young's) Modulus3.2 GPa0.46 Msi
Shear Modulus1.2 GPa0.17 Msi
Bulk Modulus6 GPa0.81 Msi
Poisson's Ratio0.37
Tensile Strength (Ultimate)76 MPa11 ksi
Yield Strength (0.2% offset)68 MPa9.9 ksi
Elongation at Break3.5%
Compressive Strength110 MPa16 ksi
Compressive Modulus3.1 GPa0.45 Msi
Flexural Strength115 MPa16.7 ksi
Flexural Modulus3.1 GPa0.45 Msi
Shear Strength60 MPa8.7 ksi
Fracture Toughness (K_IC)1.2 MPa·√m1.1 ksi·√in
Izod Impact, Notched18 J/m0.34 ft·lbf/in
Hardness, Shore D89 Shore D
Hardness, Rockwell M92 HRM

Thermal11

PMMA HH is rated for continuous service to 95°C (203 °F). It conducts heat at 0.19 W/m·K (0.11 BTU/hr·ft·°F), worse than 68% of polymer grades. Thermal expansion is 70 µm/m·K (38.9 µin/in·°F).

Thermal Conductivity0.19 W/m·K0.11 BTU/hr·ft·°F
Specific Heat Capacity1,470 J/kg·K0.35 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)70 µm/m·K38.9 µin/in·°F
Max Service Temperature (continuous)95°C203 °F
Min Service Temperature-40°C-40 °F
Heat Deflection Temp. @ 0.45 MPa115°C239 °F
Heat Deflection Temp. @ 1.8 MPa105°C221 °F
Vicat Softening Point (B50)122°C252 °F
Flammability (UL 94)HB (typical unfilled grades; V-0 only with flame-retardant formulations)
Limiting Oxygen Index18%
Max Service Temperature (short-term)95°C203 °F

Electrical7

PMMA HH is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)2.7
Dissipation Factor (1 MHz)0.02
Volume Resistivity1×10¹⁵ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is very good (80/100), worse than 52% of polymer grades. UV resistance is excellent.

Corrosion ResistanceVery good80/100
UV / Weathering ResistanceExcellent92/100
Chemical Resistance SummaryGood against water, dilute acids/alkalis, aliphatic hydrocarbons, mineral oils and most detergents. Attacked or stress-crazed by ketones (acetone/MEK), esters, chlorinated and aromatic solvents, concentrated acids, and by alcohols/ammonia cleaners under stress; anneal parts before solvent contact.

Sustainability4

Producing a kilogram of PMMA HH takes about 101 MJ of energy and emits 6.4 kg of CO₂ — less than 56% of polymer grades. Typical recycled content is 2%.

Embodied Energy (primary production)101 MJ/kg43,422 BTU/lb
Embodied Carbon (primary production)6.4 kg CO₂/kg
Embodied Water280 L/kg33.6 gal/lb
Typical Recycled Content2%

Manufacturability8

PMMA HH's machinability is very good (70/100, better than 74% of polymer grades); weldability good (55/100); formability fair (45/100).

MachinabilityVery good70/100
WeldabilityGood55/100
Formability (cold)Fair45/100
PolishabilityExcellent96/100
Mold Shrinkage0.5%
Melt Flow Rate1.5 g/10 min
Processing Melt Temperature (typ.)265°C509 °F
Mold Temperature (typ.)70°C158 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PMMA HH

Is PMMA easy to machine?

Machines cleanly with sharp, polished, high-rake carbide tools and high spindle speed / low feed; use 0° rake or step drills to avoid chipping, and anneal (80 °C, 1 h per 3 mm) before and after cutting to prevent crazing.

Can PMMA be welded?

Not conventionally weldable — join with methylene-chloride or MMA cement (solvent/polymerisable), UV-cure acrylic adhesive, or ultrasonic welding for molded parts; hot-gas/hot-plate welding is possible but leaves visible seams.

Can PMMA be formed, bent or molded?

Thermoform at 150–175 °C from dried sheet; injection mold at 220–265 °C melt / 50–90 °C mold after drying 3–4 h at 80 °C, and hold back pressure to avoid silver streaking.

What surface finishes work on PMMA?

Flame, diamond or buff polish gives optical edges; hard-coat lacquers improve scratch and chemical resistance; paints and inks must be acrylic/urethane-based — solvent-rich systems craze the surface.

PMMA chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
methyl acrylate / ethyl acrylate comonomadded in extrusion/injection grades for thermal-processing stability0 – 82
acrylic impact modifier (core-shell rubbonly in impact-modified grades0 – 250
UV absorber (benzotriazole/benzophenone)UV-resistant grades0 – 10
processing aids / release agent / antiox0 – 10.3
methyl methacrylate (MMA)polymerised MMA backbone; homopolymer for cast sheet≥ 92 (balance)

PMMA HH — frequently asked

What is PMMA HH used for?

PMMA HH is typically used for automotive taillight lenses, illuminated signage and lettering, machine guards and viewing windows, light pipes and optical lenses, display cases and retail fixtures and skylights and architectural glazing. In short: crystal clear; weatherproof.

What is the yield strength of PMMA HH?

PMMA HH has a typical yield strength of 68 MPa (9.86 ksi) and a tensile strength of 76 MPa (11 ksi) — stronger than 77% of polymer grades. Strength varies by condition: see the 8 listed tempers.

Is PMMA HH easy to machine?

Yes — machinability is rated very good (70/100, better than 74% of polymer grades). Machines cleanly with sharp, polished, high-rake carbide tools and high spindle speed / low feed; use 0° rake or step drills to avoid chipping, and anneal (80 °C, 1 h per 3 mm) before and after cutting to prevent crazing.

Can PMMA HH be welded?

Yes — weldability is rated good (55/100). Not conventionally weldable — join with methylene-chloride or MMA cement (solvent/polymerisable), UV-cure acrylic adhesive, or ultrasonic welding for molded parts; hot-gas/hot-plate welding is possible but leaves visible seams.

What surface finishes work on PMMA HH?

Flame, diamond or buff polish gives optical edges; hard-coat lacquers improve scratch and chemical resistance; paints and inks must be acrylic/urethane-based — solvent-rich systems craze the surface.

Can PMMA HH be formed, bent or molded?

Thermoform at 150–175 °C from dried sheet; injection mold at 220–265 °C melt / 50–90 °C mold after drying 3–4 h at 80 °C, and hold back pressure to avoid silver streaking.

What is the maximum service temperature of PMMA HH?

PMMA HH is rated for continuous use to about 95°C (203 °F), and briefly to 95°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PMMA Extruded and PMMA FR?

Extruded is the default condition — lowest-cost transparent acrylic sheet with tight thickness tolerance; best for thermoforming, laser cutting and signage. FR: for lighting diffusers, transit glazing and electrical enclosures needing UL 94 V-0 or low smoke; expect some loss of clarity and toughness. Yield strength is 68 MPa in Extruded versus 56 MPa in FR.

Can FabDigit make parts in PMMA HH?

Yes — PMMA HH is available for CNC machining, sheet metal and injection molding with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. ISO 7823-1/-2 (Poly(methyl methacrylate) sheets — cast and extruded) — ISO (2003)
  2. ASTM D788 Standard Classification for Poly(Methyl Methacrylate) Molding and Extrusion Compounds — ASTM (2018)
  3. PLEXIGLAS GS/XT and molding compound datasheets — Röhm GmbH (2023)
  4. ACRYLITE cast and extruded sheet technical data — Röhm America / Trinseo (2022)
  5. ACRYPET molding grade technical brochure — Mitsubishi Chemical (2021)
  6. CAMPUS plastics database — PMMA property profiles (ISO 10350) — CWFG (2024)
  7. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.