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ECTFE HP

Other

ASTM D3275 · also Halar

HP = high-purity / semiconductor grade

Low-extractable, low-metal-ion resin for UPW and wet-bench fluid handling, filter housings and membrane supports.

High cost $$$$

Values for the HP condition

Other ECTFE grades and fills

ECTFE is listed in 5 conditions; see the grade overview at ECTFE.

Compare all 5 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Powder coating / rotolining grade
Pick for 0.5–2 mm thick pinhole-free linings on steel tanks, scrubbers, ducts and pumps in acid/chlorine service.284020073 Shore D
Wire & cable / plenum insulation grade
High-speed extrusion grade for plenum-rated data cable jacketing where low smoke and flame spread are required.294228074 Shore D
Conductive / antistatic (carbon-filled) grade
Carbon-black/carbon-fibre filled compound for static-dissipative tank linings and flammable-solvent handling.30358078 Shore D
HPThis page
High-purity / semiconductor grade
Low-extractable, low-metal-ion resin for UPW and wet-bench fluid handling, filter housings and membrane supports.314525075 Shore D
25% glass-fibre reinforced compound
Use where stiffness, creep resistance and dimensional stability of a fluoropolymer part matter more than ductility.—606—

What is ECTFE HP?

ECTFE HP is ECTFE in the HP condition — low-extractable, low-metal-ion resin for UPW and wet-bench fluid handling, filter housings and membrane supports. ECTFE HP has a yield strength of 31 MPa (4.5 ksi) and a tensile strength of 45 MPa (6.53 ksi) — weaker than 70% of polymer grades. Elongation at break is 250% and the elastic modulus is 1.7 GPa (0.247 Msi). ECTFE HP has a density of 1.68 g/cm³ (0.0607 lb/in³), heavier than 94% of polymer grades. Its glass-transition temperature is 65°C (149 °F).

Advantages

  • Good corrosion resistance — 97/100, better than 98% of polymer grades
  • Low moisture uptake — 0.01%, better than 97% of polymer grades
  • Good UV / weathering resistance — 95/100, better than 95% of polymer grades
  • Ductile — tolerates forming and impact — 250%, better than 79% of polymer grades
  • High service temperature — 150°C (302 °F), better than 79% of polymer grades

Limitations

  • Heavy — 1.68 g/cm³ (0.0607 lb/in³), worse than 94% of polymer grades
  • High embodied carbon — 11 kg CO₂/kg, worse than 90% of polymer grades
  • High mold shrinkage — 2%, worse than 81% of polymer grades
  • Poor heat conductor — 0.16 W/m·K (0.0924 BTU/hr·ft·°F), worse than 78% of polymer grades

ECTFE HP properties

Typical room-temperature values for ECTFE HP; 24 are specific to this condition. Other listed values are ECTFE reference data and may not represent this condition. Bars are the position among polymer grades.

Physical7

ECTFE HP has a density of 1.68 g/cm³ (0.0607 lb/in³), heavier than 94% of polymer grades. Its glass-transition temperature is 65°C (149 °F).

Density1.68 g/cm³0.06 lb/in³
Melting Temperature (Tm)240°C464 °F
Glass Transition (Tg)65°C149 °F
Water Absorption (24 h)0.01%
Water Absorption (Saturation)0.03%
Refractive Index1.447
Light Transmission90%

Mechanical11

ECTFE HP has a yield strength of 31 MPa (4.5 ksi) and a tensile strength of 45 MPa (6.53 ksi) — weaker than 70% of polymer grades. Elongation at break is 250% and the elastic modulus is 1.7 GPa (0.247 Msi).

Elastic (Young's) Modulus1.7 GPa0.25 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)45 MPa6.5 ksi
Yield Strength (0.2% offset)31 MPa4.5 ksi
Elongation at Break250%
Compressive Strength35 MPa5.1 ksi
Flexural Strength32 MPa4.6 ksi
Flexural Modulus1.7 GPa0.25 Msi
Izod Impact, Notched400 J/m7.5 ft·lbf/in
Hardness, Shore D75 Shore D
Hardness, Rockwell R93 HRR

Thermal11

ECTFE HP is rated for continuous service to 150°C (302 °F). It conducts heat at 0.16 W/m·K (0.0924 BTU/hr·ft·°F), worse than 78% of polymer grades. Thermal expansion is 80 µm/m·K (44.4 µin/in·°F).

Thermal Conductivity0.16 W/m·K0.09 BTU/hr·ft·°F
Specific Heat Capacity1,000 J/kg·K0.24 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)80 µm/m·K44.4 µin/in·°F
Max Service Temperature (continuous)150°C302 °F
Min Service Temperature-76°C-105 °F
Heat Deflection Temp. @ 0.45 MPa116°C241 °F
Heat Deflection Temp. @ 1.8 MPa77°C171 °F
Vicat Softening Point (B50)145°C293 °F
Flammability (UL 94)V-0 at 0.8 mm and above; low smoke, self-extinguishing (5VA reported for thicker sections)
Limiting Oxygen Index60%
Max Service Temperature (short-term)180°C356 °F

Electrical7

ECTFE HP is an electrical insulator with a dielectric strength of 80 kV/mm (2,032 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength80 kV/mm2,032 V/mil
Dielectric Constant (1 MHz)2.5
Dissipation Factor (1 MHz)0.015
Volume Resistivity1×10¹⁶ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is excellent (97/100), better than 98% of polymer grades. UV resistance is excellent.

Corrosion ResistanceExcellent97/100
UV / Weathering ResistanceExcellent95/100
Chemical Resistance SummaryEssentially inert to strong acids (incl. HCl, HF, aqua regia), caustics, chlorine, solvents and oxidizers up to ~150 °C; outstanding barrier to Cl2, HCl and water vapor permeation — much lower permeability than PTFE/PFA. Attacked/swollen by hot chlorinated and aromatic solvents, hot amines and molten alkali metals; not for fluorine at elevated temperature.

Sustainability3

Producing a kilogram of ECTFE HP takes about 210 MJ of energy and emits 11 kg of CO₂ — more than 89% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)210 MJ/kg90,284 BTU/lb
Embodied Carbon (primary production)11 kg CO₂/kg
Typical Recycled Content0%

Manufacturability8

ECTFE HP's machinability is good (55/100, worse than 64% of polymer grades); weldability very good (70/100); formability good (60/100).

MachinabilityGood55/100
WeldabilityVery good70/100
Formability (cold)Good60/100
PolishabilityFair40/100
Mold Shrinkage2%
Melt Flow Rate12 g/10 min
Processing Melt Temperature (typ.)280°C536 °F
Mold Temperature (typ.)90°C194 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ECTFE HP

Is ECTFE easy to machine?

Machinable with sharp, high-rake carbide tools, high speed and low feed; the material is tough and gummy, so use coolant/air blast and expect springback on tight tolerances.

Can ECTFE be welded?

Readily fusion, hot-gas and extrusion welded (liners and sheet) at 280–320 °C; adhesive bonding requires plasma or chemical surface activation.

Can ECTFE be formed, bent or molded?

Injection mould/extrude at 260–310 °C with corrosion-resistant (Hastelloy/nickel-alloy) barrels and hot runners; shrinkage 1.5–3.5 %, sheet thermoforms at 180–230 °C, powder applied electrostatically then fused at 260–290 °C.

What surface finishes work on ECTFE?

Non-stick, low-energy surface — no paint or plating without corona/plasma treatment; pigmented or textured grades preferred over polishing, and coatings are spark-tested for pinholes.

ECTFE chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
chlorotrifluoroethylene (CTFE)≈50 mol%, alternating copolymer78 – 8280.6
termonomer / stabilizerminor modifier in some commercial grades0 – 1—
ethylene≈50 mol%≥ 18 (balance)—

ECTFE HP — frequently asked

What is ECTFE HP used for?

ECTFE HP is typically used for tank and pipe interior linings, wire and cable jacketing, chemical process equipment coatings and battery separator films. In short: low-cost fluoropolymer lining; strong permeation barrier; electrostatically applied powder coating.

What is the yield strength of ECTFE HP?

ECTFE HP has a typical yield strength of 31 MPa (4.5 ksi) and a tensile strength of 45 MPa (6.53 ksi) — weaker than 70% of polymer grades. Strength varies by condition: see the 5 listed tempers.

Is ECTFE HP easy to machine?

Reasonably — machinability is rated good (55/100, worse than 64% of polymer grades). Machinable with sharp, high-rake carbide tools, high speed and low feed; the material is tough and gummy, so use coolant/air blast and expect springback on tight tolerances.

Can ECTFE HP be welded?

Yes — weldability is rated very good (70/100). Readily fusion, hot-gas and extrusion welded (liners and sheet) at 280–320 °C; adhesive bonding requires plasma or chemical surface activation.

What surface finishes work on ECTFE HP?

Non-stick, low-energy surface — no paint or plating without corona/plasma treatment; pigmented or textured grades preferred over polishing, and coatings are spark-tested for pinholes.

Can ECTFE HP be formed, bent or molded?

Injection mould/extrude at 260–310 °C with corrosion-resistant (Hastelloy/nickel-alloy) barrels and hot runners; shrinkage 1.5–3.5 %, sheet thermoforms at 180–230 °C, powder applied electrostatically then fused at 260–290 °C.

What is the maximum service temperature of ECTFE HP?

ECTFE HP is rated for continuous use to about 150°C (302 °F), and briefly to 180°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASTM D3275 — Standard Specification for E-CTFE Fluoroplastic Molding, Extrusion, and Coating Materials — ASTM International (2019)
  2. Halar ECTFE Design & Processing Guide / grade data sheets — Solvay Specialty Polymers (Syensqo) (2022)
  3. Engineered Materials Handbook Vol.2 — Engineering Plastics (fluoropolymers) — ASM International (1988)
  4. CAMPUS / UL Prospector fluoropolymer property records — CWFG / UL Solutions (2024)
  5. Fluoroplastics, Volume 2: Melt Processible Fluoropolymers — Elsevier (Plastics Design Library) (2015)
  6. ECTFE/ETFE (2026)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.