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ASA FR (Flame retardant)

Flame-retardant grade

ASTM D4785 · GB GB/T 24151 · ISO 2580-2 ASA · also Centrex, Geloy

Pick the flame-retardant modification when UL 94 V-0 is required, as in outdoor electrical enclosures and PV junction boxes; impact toughness and melt flow drop slightly.

Values for the FR condition

Other ASA grades and fills

ASA is listed in 7 conditions; see the grade overview at ASA.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
FDM part, XY orientation, as built
Use for FDM parts as built in the XY orientation, 34 MPa tensile and 1.9 GPa modulus, and design around the anisotropy because Z interlayer strength is markedly lower.3234876 Shore D
High impact / impact modified
Choose the impact-modified grade with higher acrylate rubber content for outdoor structural parts needing 40% elongation or toughness at low temperature; modulus stays 1.9 GPa.38404074 Shore D
FDM filament grade
Use the 1.75/2.85 mm filament grade optimized for FDM extrusion when outdoor prints need weatherability and less warp than ABS; print in an enclosed, heated chamber.42442077 Shore D
FRThis page
Flame retardant
Pick the flame-retardant modification when UL 94 V-0 is required, as in outdoor electrical enclosures and PV junction boxes; impact toughness and melt flow drop slightly.43441279 Shore D
pigmented weather-resistant compound
Pick the pigmented weather-resistant compound (usually carbon black or inorganic colors) when outdoor color and gloss retention govern; tensile stays 46 MPa, elongation 22%.44462278 Shore D
Heat resistant / high heat grade
Pick the heat-resistant grade, copolymerized or alloyed for a higher glass transition, for dark automotive exterior parts that heat up under solar load; service to 90 °C.49501580 Shore D
20% glass fiber reinforced
Choose 20% glass fiber reinforcement when stiffness of 5.5 GPa, creep resistance and lower CTE govern; elongation falls to 3% and impact toughness and surface appearance drop.—85385 HRM

What is ASA FR?

ASA FR is ASA in the FR grade — pick the flame-retardant modification when UL 94 V-0 is required, as in outdoor electrical enclosures and PV junction boxes; impact toughness and melt flow drop slightly. ASA FR has a yield strength of 43 MPa (6.24 ksi) and a tensile strength of 44 MPa (6.38 ksi) — weaker than 61% of polymer grades. Elongation at break is 12% and the elastic modulus is 2.5 GPa (0.363 Msi). ASA FR has a density of 1.18 g/cm³ (0.0426 lb/in³), heavier than 50% of polymer grades. Its glass-transition temperature is 105°C (221 °F).

Advantages

  • Good UV / weathering resistance — 88/100, better than 90% of polymer grades
  • Polishes to a fine finish — 70/100, better than 77% of polymer grades
  • Low, predictable mold shrinkage — 0.45%, better than 77% of polymer grades

Limitations

  • Needs corrosion protection — 70/100, worse than 78% of polymer grades

ASA FR properties

Typical room-temperature values for ASA FR; 28 are specific to this condition. Other listed values are ASA reference data and may not represent this condition. Bars are the position among polymer grades.

Physical5

ASA FR has a density of 1.18 g/cm³ (0.0426 lb/in³), heavier than 50% of polymer grades. Its glass-transition temperature is 105°C (221 °F).

Density1.18 g/cm³0.04 lb/in³
Glass Transition (Tg)105°C221 °F
Water Absorption (24 h)0.3%
Water Absorption (Saturation)1%
Refractive Index1.57

Mechanical15

ASA FR has a yield strength of 43 MPa (6.24 ksi) and a tensile strength of 44 MPa (6.38 ksi) — weaker than 61% of polymer grades. Elongation at break is 12% and the elastic modulus is 2.5 GPa (0.363 Msi).

Elastic (Young's) Modulus2.5 GPa0.36 Msi
Shear Modulus0.8 GPa0.12 Msi
Bulk Modulus4 GPa0.51 Msi
Poisson's Ratio0.37
Tensile Strength (Ultimate)44 MPa6.4 ksi
Yield Strength (0.2% offset)43 MPa6.2 ksi
Elongation at Break12%
Compressive Strength60 MPa8.7 ksi
Flexural Strength68 MPa9.9 ksi
Flexural Modulus2.5 GPa0.36 Msi
Shear Strength33 MPa4.8 ksi
Izod Impact, Notched80 J/m1.5 ft·lbf/in
Hardness, Shore D79 Shore D
Hardness, Rockwell M72 HRM
Hardness, Rockwell R108 HRR

Thermal11

ASA FR is rated for continuous service to 80°C (176 °F). It conducts heat at 0.19 W/m·K (0.11 BTU/hr·ft·°F), worse than 68% of polymer grades. Thermal expansion is 85 µm/m·K (47.2 µin/in·°F).

Thermal Conductivity0.19 W/m·K0.11 BTU/hr·ft·°F
Specific Heat Capacity1,450 J/kg·K0.35 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)85 µm/m·K47.2 µin/in·°F
Max Service Temperature (continuous)80°C176 °F
Min Service Temperature-30°C-22 °F
Heat Deflection Temp. @ 0.45 MPa90°C194 °F
Heat Deflection Temp. @ 1.8 MPa82°C180 °F
Vicat Softening Point (B50)95°C203 °F
Flammability (UL 94)V-0 @ 1.5 mm ( 5VB)
Limiting Oxygen Index28%
Max Service Temperature (short-term)95°C203 °F

Electrical7

ASA FR is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)3
Dissipation Factor (1 MHz)0.015
Volume Resistivity1×10¹⁶ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is very good (70/100), worse than 78% of polymer grades. UV resistance is excellent.

Corrosion ResistanceVery good70/100
UV / Weathering ResistanceExcellent88/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of ASA FR takes about 96 MJ of energy and emits 3.9 kg of CO₂ — less than 67% of polymer grades. Typical recycled content is 5%.

Embodied Energy (primary production)96 MJ/kg41,273 BTU/lb
Embodied Carbon (primary production)3.9 kg CO₂/kg
Embodied Water200 L/kg24 gal/lb
Typical Recycled Content5%

Manufacturability8

ASA FR's machinability is good (55/100, worse than 64% of polymer grades); weldability fair (50/100); formability fair (35/100).

MachinabilityGood55/100
WeldabilityFair50/100
Formability (cold)Fair35/100
PolishabilityVery good70/100
Mold Shrinkage0.45%
Melt Flow Rate4 g/10 min
Processing Melt Temperature (typ.)245°C473 °F
Mold Temperature (typ.)65°C149 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ASA FR

Is ASA easy to machine?

Amorphous and easy to cut with sharp positive-rake tools at high spindle speed and low feed; keep chips clear and cool the cut so frictional heat does not melt and re-weld the surface. Glass-filled grades require carbide tooling.

Can ASA be welded?

Ultrasonic, hot-plate and vibration/friction welding all work, and solvent bonding with MEK or dichloromethane is possible; cyanoacrylate and epoxy adhesives also bond well.

Can ASA be formed, bent or molded?

Dry 2–4 h at 80 °C before moulding, run 230–260 °C melt with 50–80 °C tool, and allow about 0.4–0.7 % shrinkage. Sheet vacuum-thermoforms.

What surface finishes work on ASA?

Weatherability is in the polymer, so outdoor parts often need no paint; high-gloss and grained tool textures reproduce well. Electroplating uses ABS-type pretreatment with slightly lower adhesion than ABS, and acrylic or PU paints can be sprayed.

ASA chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
styrenestyrene monomer unit55 – 7565
acrylonitrileacrylonitrile monomer unit15 – 2521
acrylate rubber (n-butyl acrylate)saturated acrylate rubber graft phase, gives weatherability8 – 3014
stabilizers/pigmentsantioxidant/HALS/UV absorber/pigments0.2 – 31

ASA FR — frequently asked

What is ASA FR used for?

ASA FR is typically used for outdoor equipment housings, automotive mirror housings and exterior trim, building and window profiles, roof drainage and gutter components, antenna radomes and garden tool bodies. In short: weather resistant tough.

What is the yield strength of ASA FR?

ASA FR has a typical yield strength of 43 MPa (6.24 ksi) and a tensile strength of 44 MPa (6.38 ksi) — weaker than 61% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is ASA FR easy to machine?

Reasonably — machinability is rated good (55/100, worse than 64% of polymer grades). Amorphous and easy to cut with sharp positive-rake tools at high spindle speed and low feed; keep chips clear and cool the cut so frictional heat does not melt and re-weld the surface. Glass-filled grades require carbide tooling.

Can ASA FR be welded?

With care — weldability is rated fair (50/100). Ultrasonic, hot-plate and vibration/friction welding all work, and solvent bonding with MEK or dichloromethane is possible; cyanoacrylate and epoxy adhesives also bond well.

What surface finishes work on ASA FR?

Weatherability is in the polymer, so outdoor parts often need no paint; high-gloss and grained tool textures reproduce well. Electroplating uses ABS-type pretreatment with slightly lower adhesion than ABS, and acrylic or PU paints can be sprayed.

Can ASA FR be formed, bent or molded?

Dry 2–4 h at 80 °C before moulding, run 230–260 °C melt with 50–80 °C tool, and allow about 0.4–0.7 % shrinkage. Sheet vacuum-thermoforms.

What is the maximum service temperature of ASA FR?

ASA FR is rated for continuous use to about 80°C (176 °F), and briefly to 95°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in ASA FR?

Yes — ASA FR is available for CNC machining, sheet metal, injection molding and 3D printing with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. Luran S ASA — INEOS Styrolution (2022)
  2. Geloy ASA Resin Product Data — SABIC (2021)
  3. Centrex ASA/AES Weatherable Polymers — INEOS Styrolution (2020)
  4. CAMPUS Plastics ISO 10350 (ASA) — CAMPUS/CWFG (2023)
  5. Engineered Materials Handbook Vol.2: Engineering Plastics — ASM International (1988)
  6. ISO 19064-1 Plastics — ASA moulding and extrusion materials — ISO (2015)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.