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TP-PI ESD

Grade

ISO PI · also Kapton, Vespel

ESD = carbon/graphite loaded static-dissipative grade

Pick for wafer-handling and electronics tooling that must bleed charge (10^4–10^9 Ω/sq) while surviving 240 °C.

High cost $$$$

Values for the ESD condition

Other TP-PI grades and fills

TP-PI is listed in 6 conditions; see the grade overview at TP-PI.

Compare all 6 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
15 % graphite + 10 % PTFE low-friction grade (SP-211 type)
Pick for the lowest start-up friction in unlubricated sliding contact at moderate loads and temperatures below ~230 °C.—524—
15 % molybdenum disulfide filled
Pick for wear parts running in vacuum, dry gas or cryogenic service where graphite loses its lubricity.—603.5—
15 % graphite filled bearing grade
Pick for dry-running bushings, thrust washers and seal rings where low friction and high PV at 250 °C+ matter more than strength.—664.595 HRM
ESDThis page
Carbon/graphite loaded static-dissipative grade
Pick for wafer-handling and electronics tooling that must bleed charge (10^4–10^9 Ω/sq) while surviving 240 °C.9095390 Shore D
30 % glass-fiber reinforced
Pick when high stiffness, creep resistance and dimensional stability to ~300 °C are needed while keeping electrical insulation.—1653108 HRM
30 % carbon-fiber reinforced
Pick for maximum stiffness/strength-to-weight, low CTE, better heat dissipation and static-dissipative behaviour in structural high-temperature parts.—2102110 HRM

What is TP-PI ESD?

TP-PI ESD is TP-PI in the ESD grade — pick for wafer-handling and electronics tooling that must bleed charge (10^4–10^9 Ω/sq) while surviving 240 °C. TP-PI ESD has a yield strength of 90 MPa (13.1 ksi) and a tensile strength of 95 MPa (13.8 ksi) — stronger than 91% of polymer grades. Elongation at break is 3% and the elastic modulus is 6 GPa (0.87 Msi). TP-PI ESD has a density of 1.45 g/cm³ (0.0524 lb/in³), heavier than 86% of polymer grades. Its glass-transition temperature is 250°C (482 °F).

Advantages

  • Conducts heat well — 0.85 W/m·K (0.491 BTU/hr·ft·°F), better than 99% of polymer grades
  • High service temperature — 240°C (464 °F), better than 92% of polymer grades
  • High strength — 90 MPa (13.1 ksi), better than 91% of polymer grades
  • Stiff — 6 GPa (0.87 Msi), better than 89% of polymer grades
  • Low, predictable mold shrinkage — 0.4%, better than 82% of polymer grades

Limitations

  • High embodied carbon — 15 kg CO₂/kg, worse than 96% of polymer grades
  • Limited formability — 10/100, worse than 87% of polymer grades
  • Heavy — 1.45 g/cm³ (0.0524 lb/in³), worse than 86% of polymer grades
  • Limited ductility — 3%, worse than 83% of polymer grades
  • Difficult to weld — 15/100, worse than 78% of polymer grades

TP-PI ESD properties

Typical room-temperature values for TP-PI ESD; 28 are specific to this condition. Other listed values are TP-PI reference data and may not represent this condition. Bars are the position among polymer grades.

Physical6

TP-PI ESD has a density of 1.45 g/cm³ (0.0524 lb/in³), heavier than 86% of polymer grades. Its glass-transition temperature is 250°C (482 °F).

Density1.45 g/cm³0.05 lb/in³
Melting Temperature (Tm)388°C730 °F
Glass Transition (Tg)250°C482 °F
Water Absorption (24 h)0.24%
Water Absorption (Saturation)1.2%
Refractive Index1.7

Mechanical17

TP-PI ESD has a yield strength of 90 MPa (13.1 ksi) and a tensile strength of 95 MPa (13.8 ksi) — stronger than 91% of polymer grades. Elongation at break is 3% and the elastic modulus is 6 GPa (0.87 Msi).

Elastic (Young's) Modulus6 GPa0.87 Msi
Shear Modulus1.1 GPa0.15 Msi
Bulk Modulus4 GPa0.58 Msi
Poisson's Ratio0.38
Tensile Strength (Ultimate)95 MPa13.8 ksi
Yield Strength (0.2% offset)90 MPa13.1 ksi
Elongation at Break3%
Compressive Strength150 MPa21.8 ksi
Compressive Modulus2.8 GPa0.41 Msi
Flexural Strength145 MPa21 ksi
Flexural Modulus5.6 GPa0.81 Msi
Shear Strength85 MPa12.3 ksi
Fracture Toughness (K_IC)2.2 MPa·√m2 ksi·√in
Izod Impact, Notched25 J/m0.47 ft·lbf/in
Hardness, Shore D90 Shore D
Hardness, Rockwell M105 HRM
Hardness, Rockwell R128 HRR

Thermal11

TP-PI ESD is rated for continuous service to 240°C (464 °F). It conducts heat at 0.85 W/m·K (0.491 BTU/hr·ft·°F), better than 99% of polymer grades. Thermal expansion is 50 µm/m·K (27.8 µin/in·°F).

Thermal Conductivity0.85 W/m·K0.49 BTU/hr·ft·°F
Specific Heat Capacity1,100 J/kg·K0.26 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)50 µm/m·K27.8 µin/in·°F
Max Service Temperature (continuous)240°C464 °F
Min Service Temperature-269°C-452 °F
Heat Deflection Temp. @ 0.45 MPa255°C491 °F
Heat Deflection Temp. @ 1.8 MPa245°C473 °F
Vicat Softening Point (B50)258°C496 °F
Flammability (UL 94)V-0 at 0.8 mm (inherently flame retardant, no additives)
Limiting Oxygen Index52%
Max Service Temperature (short-term)300°C572 °F

Electrical7

TP-PI ESD is an electrical insulator with a dielectric strength of 22 kV/mm (558.8 V/mil) and a resistivity of 1,000 Ω·m.

Electrical Resistivity1,000 Ω·m3.94×10¹⁰ µΩ·in
Dielectric Strength22 kV/mm559 V/mil
Dielectric Constant (1 MHz)3.2
Dissipation Factor (1 MHz)0.002
Volume Resistivity100,000 Ω·cm
Surface Resistivity1,000,000 Ω
Comparative Tracking Index (CTI)175 V

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 65% of polymer grades. UV resistance is good.

Corrosion ResistanceExcellent85/100
UV / Weathering ResistanceGood60/100
Chemical Resistance SummaryExcellent against hydrocarbons, fuels, oils, ketones, chlorinated solvents, and ionizing radiation; resists most acids at moderate temperature. Attacked by strong bases, amines, hydrazine, and hot concentrated alkali; hydrolyzes in steam/hot water above ~120 °C.

Sustainability4

Producing a kilogram of TP-PI ESD takes about 300 MJ of energy and emits 15 kg of CO₂ — more than 97% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)300 MJ/kg128,977 BTU/lb
Embodied Carbon (primary production)15 kg CO₂/kg
Embodied Water500 L/kg59.9 gal/lb
Typical Recycled Content0%

Manufacturability8

TP-PI ESD's machinability is fair (50/100, worse than 73% of polymer grades); weldability poor (15/100); formability not recommended (10/100).

MachinabilityFair50/100
WeldabilityPoor15/100
Formability (cold)Not recommended10/100
PolishabilityGood60/100
Mold Shrinkage0.4%
Melt Flow Rate3 g/10 min
Processing Melt Temperature (typ.)410°C770 °F
Mold Temperature (typ.)200°C392 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with TP-PI ESD

Is TP-PI easy to machine?

Machines like a hard, abrasive engineering plastic: sharp PCD or carbide tools, high speed, light depth, air or mist cooling; anneal stock and stress-relieve after roughing to hold tight tolerances.

Can TP-PI be welded?

Melt welding is impractical at 400 °C-class melt temperature; join by mechanical fastening, or bond with polyimide/epoxy adhesives after plasma or alkaline surface activation.

Can TP-PI be formed, bent or molded?

Dry pellets 5 h at 180 °C; injection mould at 400–420 °C melt with 170–230 °C tool and generous gates, or compression-mould/sinter powder for grades that will not flow; thin films are solvent cast from polyamic acid.

What surface finishes work on TP-PI?

Naturally amber-to-black and needs no flame retardant or paint; can be plasma-treated, sputter-metallised or laser-marked, and lapped to mirror finish for seal faces.

TP-PI chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
aromatic dianhydride (PMDA / BPDA / BTDAbackbone anhydride component45 – 6055
glass fiberGF variants only0 – 400
carbon fiberCF variants only0 – 400
graphite / PTFE / MoS2bearing-grade solid lubricants0 – 250
aromatic diamine (ODA / m-phenylenediamiflexible ether linkages give melt processability≥ 40 (balance)—

TP-PI ESD — frequently asked

What is TP-PI ESD used for?

TP-PI ESD is typically used for semiconductor wafer-handling components, aerospace seals and bushings, high-temperature electrical insulators and piston rings in jet engines. In short: highest-temperature thermoplastic family; low outgassing for vacuum; sintered or compression moulded.

What is the yield strength of TP-PI ESD?

TP-PI ESD has a typical yield strength of 90 MPa (13.1 ksi) and a tensile strength of 95 MPa (13.8 ksi) — stronger than 91% of polymer grades. Strength varies by condition: see the 6 listed tempers.

Is TP-PI ESD easy to machine?

Reasonably — machinability is rated fair (50/100, worse than 73% of polymer grades). Machines like a hard, abrasive engineering plastic: sharp PCD or carbide tools, high speed, light depth, air or mist cooling; anneal stock and stress-relieve after roughing to hold tight tolerances.

Can TP-PI ESD be welded?

Not readily — weldability is rated poor (15/100). Melt welding is impractical at 400 °C-class melt temperature; join by mechanical fastening, or bond with polyimide/epoxy adhesives after plasma or alkaline surface activation.

What surface finishes work on TP-PI ESD?

Naturally amber-to-black and needs no flame retardant or paint; can be plasma-treated, sputter-metallised or laser-marked, and lapped to mirror finish for seal faces.

Can TP-PI ESD be formed, bent or molded?

Dry pellets 5 h at 180 °C; injection mould at 400–420 °C melt with 170–230 °C tool and generous gates, or compression-mould/sinter powder for grades that will not flow; thin films are solvent cast from polyamic acid.

What is the maximum service temperature of TP-PI ESD?

TP-PI ESD is rated for continuous use to about 240°C (464 °F), and briefly to 300°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Aurum Thermoplastic Polyimide PL450C / JGN3030 / JCN3030 data sheets — Mitsui Chemicals (2022)
  2. Vespel SP Polyimide Parts and Shapes Design Handbook (SP-1, SP-21, SP-211, SP-3) — DuPont (2021)
  3. Meldin 7000 series polyimide properties — Saint-Gobain Performance Plastics (2021)
  4. Engineered Materials Handbook Vol.2: Engineering Plastics — ASM International (1988)
  5. CAMPUS / UL Prospector polyimide grade data — CWFG / UL (2023)
  6. ISO 527 / ISO 178 / ISO 75 / ASTM D256 test methods — ISO / ASTM (2019)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.