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PPA · grade

PPA Heat Stabilized

Properties of the Heat Stabilized condition, compared with the other PPA grades.

Specify for long-term air exposure at 160–200 °C (turbo/charge-air, EGR, motor parts) where unstabilized PPA embrittles.

Injection moldingSpecialty cost $$$$$

What is PPA Heat Stabilized?

PPA Heat Stabilized is PPA in the Heat Stabilized grade — specify for long-term air exposure at 160–200 °C (turbo/charge-air, EGR, motor parts) where unstabilized PPA embrittles. PPA Heat Stabilized has a tensile strength of 200 MPa (29 ksi), stronger than 98% of polymer grades. Elongation at break is 2.2% and the elastic modulus is 11 GPa (1.6 Msi). PPA Heat Stabilized has a density of 1.46 g/cm³ (0.0527 lb/in³), heavier than 85% of polymer grades. Its glass-transition temperature is 123°C (253 °F). GF30 is the default condition FabDigit quotes; Heat Stabilized is available on request or by drawing note.

Advantages

  • Stiff — 11 GPa (1.6 Msi), better than 96% of polymer grades
  • Conducts heat well — 0.32 W/m·K (0.185 BTU/hr·ft·°F), better than 87% of polymer grades
  • Low, predictable mold shrinkage — 0.35%, better than 87% of polymer grades
  • High service temperature — 190°C (374 °F), better than 86% of polymer grades

Limitations

  • Limited ductility — 2.2%, worse than 92% of polymer grades
  • Limited formability — 10/100, worse than 87% of polymer grades
  • Heavy — 1.46 g/cm³ (0.0527 lb/in³), worse than 85% of polymer grades
  • High embodied carbon — 8 kg CO₂/kg, worse than 83% of polymer grades
  • Hard to polish — 30/100, worse than 80% of polymer grades

PPA Heat Stabilized properties

Typical room-temperature values for PPA Heat Stabilized — 10 properties are specific to this condition; the rest are grade-level values shared by every PPA grade. Each bar shows where the value sits among the polymer grades in FabDigit's library — further right is higher.

Physical5

PPA Heat Stabilized has a density of 1.46 g/cm³ (0.0527 lb/in³), heavier than 85% of polymer grades. Its glass-transition temperature is 123°C (253 °F).

Density1.46 g/cm³0.05 lb/in³
Melting Temperature (Tm)315°C599 °F
Glass Transition (Tg)123°C253 °F
Water Absorption (24 h)0.25%
Water Absorption (Saturation)1.3%

Mechanical9

PPA Heat Stabilized has a tensile strength of 200 MPa (29 ksi), stronger than 98% of polymer grades. Elongation at break is 2.2% and the elastic modulus is 11 GPa (1.6 Msi).

Elastic (Young's) Modulus11 GPa1.6 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)200 MPa29 ksi
Elongation at Break2.2%
Compressive Strength165 MPa23.9 ksi
Flexural Strength290 MPa42.1 ksi
Flexural Modulus9.8 GPa1.4 Msi
Izod Impact, Notched100 J/m1.9 ft·lbf/in
Hardness, Rockwell M95 HRM

Thermal10

PPA Heat Stabilized is rated for continuous service to 190°C (374 °F). It conducts heat at 0.32 W/m·K (0.185 BTU/hr·ft·°F), better than 87% of polymer grades. Thermal expansion is 22 µm/m·K (12.2 µin/in·°F).

Thermal Conductivity0.32 W/m·K0.18 BTU/hr·ft·°F
Specific Heat Capacity1,300 J/kg·K0.31 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)22 µm/m·K12.2 µin/in·°F
Max Service Temperature (continuous)190°C374 °F
Min Service Temperature-40°C-40 °F
Heat Deflection Temp. @ 0.45 MPa300°C572 °F
Heat Deflection Temp. @ 1.8 MPa285°C545 °F
Flammability (UL 94)HB at 0.8 mm for standard GF30 grades; V-0 available only in flame-retardant (halogen-free) versions
Limiting Oxygen Index26%
Max Service Temperature (short-term)260°C500 °F

Electrical7

PPA Heat Stabilized is an electrical insulator with a dielectric strength of 28 kV/mm (711.2 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength28 kV/mm711 V/mil
Dielectric Constant (1 MHz)4
Dissipation Factor (1 MHz)0.017
Volume Resistivity1×10¹⁶ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is very good (82/100), better than 54% of polymer grades. UV resistance is fair.

Corrosion ResistanceVery good82/100
UV / Weathering ResistanceFair40/100
Chemical Resistance SummaryVery good against engine coolants (glycol/water), oils, greases, automotive fuels, brake fluid, salt solutions and most solvents; attacked by strong acids, phenols, formic/trifluoroacetic acid and hot concentrated alkali; long-term hot aqueous glycol needs hydrolysis-stabilized grades.

Sustainability4

Producing a kilogram of PPA Heat Stabilized takes about 140 MJ of energy and emits 8 kg of CO₂ — more than 82% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)140 MJ/kg60,189 BTU/lb
Embodied Carbon (primary production)8 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content0%

Manufacturability7

PPA Heat Stabilized's machinability is fair (50/100, worse than 73% of polymer grades); weldability fair (40/100); formability not recommended (10/100).

MachinabilityFair50/100
WeldabilityFair40/100
Formability (cold)Not recommended10/100
PolishabilityPoor30/100
Mold Shrinkage0.35%
Processing Melt Temperature (typ.)330°C626 °F
Mold Temperature (typ.)150°C302 °F

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Other PPA grades and fills

PPA is also supplied in 12 other conditions. The full side-by-side table is on the PPA overview.

Working with PPA Heat Stabilized

Is PPA easy to machine?

Machine with sharp carbide or PCD tooling, high speed and light feed; glass fiber is abrasive and dust must be extracted — best used as-molded to near-net shape.

Can PPA be welded?

No solvent or hot-gas welding; use ultrasonic, laser (natural/carbon-black pairs) or heat-staking, and expect reduced strength across fiber-poor weld lines.

Can PPA be formed, bent or molded?

Dry to <0.10% moisture (80–100 °C, 4–8 h in desiccant dryer), melt 320–345 °C with hot-runner or insulated nozzle, mold 135–165 °C for full crystallinity and best HDT.

What surface finishes work on PPA?

Takes paint/adhesive after plasma or flame treatment; laser marking is clean, plating is unusual, and fiber bloom limits high-gloss cosmetic surfaces.

PPA chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
glass fiberchopped E-glass, aminosilane sized; 30% in default GF30 grade0 – 5030
carbon fiberin CF grades only0 – 300
mineral filler (talc/wollastonite/kaolinlow-warpage hybrid grades0 – 400
heat stabilizers, lubricants, pigment (cpackage varies by grade0.5 – 41.5
halogen-free flame retardant (phosphinatFR V-0 grades only0 – 200
hexamethylene terephthalamide/adipamide terephthalic (and/or isophthalic) acid + adipic acid with hexamethylenediamine / 2-MPMD≥ 45 (balance)

PPA Heat Stabilized — frequently asked

What is PPA Heat Stabilized used for?

PPA Heat Stabilized is typically used for under-hood engine components, electrical connectors for lead-free reflow, coolant and thermostat housings, sensor bodies and housings, structural brackets replacing die castings and fuel system components. In short: high-performance glass-filled nylon.

What is the tensile strength of PPA Heat Stabilized?

PPA Heat Stabilized has a typical tensile strength of 200 MPa (29 ksi) — stronger than 98% of polymer grades. Strength varies by condition: see the 13 listed tempers.

Is PPA Heat Stabilized easy to machine?

Reasonably — machinability is rated fair (50/100, worse than 73% of polymer grades). Machine with sharp carbide or PCD tooling, high speed and light feed; glass fiber is abrasive and dust must be extracted — best used as-molded to near-net shape.

Can PPA Heat Stabilized be welded?

With care — weldability is rated fair (40/100). No solvent or hot-gas welding; use ultrasonic, laser (natural/carbon-black pairs) or heat-staking, and expect reduced strength across fiber-poor weld lines.

What surface finishes work on PPA Heat Stabilized?

Takes paint/adhesive after plasma or flame treatment; laser marking is clean, plating is unusual, and fiber bloom limits high-gloss cosmetic surfaces.

Can PPA Heat Stabilized be formed, bent or molded?

Dry to <0.10% moisture (80–100 °C, 4–8 h in desiccant dryer), melt 320–345 °C with hot-runner or insulated nozzle, mold 135–165 °C for full crystallinity and best HDT.

What is the maximum service temperature of PPA Heat Stabilized?

PPA Heat Stabilized is rated for continuous use to about 190°C (374 °F), and briefly to 260°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PPA-GF30 and PPA-DAM?

GF30 is the default condition — default workhorse PPA: high hot stiffness and HDT ≈285 °C for under-hood brackets, pump housings and SMT connectors. DAM: unfilled injection-molded PPA tested dry-as-molded — stiffest, strongest state before moisture uptake.

Can FabDigit make parts in PPA Heat Stabilized?

Yes — PPA Heat Stabilized is available for injection molding with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. Amodel PPA product and design guide (A-1133 HS, A-1145 HS, AS-1133, AFA grades)Solvay/Syensqo (2023)
  2. Zytel HTN / Vydyne semi-aromatic PA (PPA) datasheetsDuPont / Ascend (2023)
  3. CAMPUS plastics database — PA6T/6I and PA6T/66 GF gradesCWFG (2024)
  4. ISO 527 / ISO 178 / ISO 75 test methods for plasticsISO (2019)
  5. Engineering Plastics Handbook — high-temperature polyamidesMcGraw-Hill (2006)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.