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PMMA-HI OPQ

Grade

ASTM D788 · JIS K6717 · GB GB/T 7134 Type 2 · ISO 8257-2 PMMA-HI

OPQ = pigmented / opaque impact grade

Coloured or white-opaque compounds for cosmetic housings, sanitary and appliance parts where gloss and scratch resistance beat ABS.

Standard cost $$

Values for the OPQ condition

Other PMMA-HI grades and fills

PMMA-HI is listed in 4 conditions; see the grade overview at PMMA-HI.

Compare all 4 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Flame-retardant impact grade
For electrical enclosures, luminaire diffusers and rail/transport parts needing a flammability rating.43451586 Shore D
High-flow impact grade
Choose for thin-wall light guides and long flow paths where fill pressure matters more than maximum toughness.45472285 Shore D
OPQThis page
Pigmented / opaque impact grade
Coloured or white-opaque compounds for cosmetic housings, sanitary and appliance parts where gloss and scratch resistance beat ABS.46482686 Shore D
Heat-resistant impact grade
Use where parts see 90–110 °C service (headlamp inner lenses, near-LED optics) and standard HI would distort.51532288 Shore D

What is PMMA-HI OPQ?

PMMA-HI OPQ is PMMA-HI in the OPQ grade — coloured or white-opaque compounds for cosmetic housings, sanitary and appliance parts where gloss and scratch resistance beat ABS. PMMA-HI OPQ has a yield strength of 46 MPa (6.67 ksi) and a tensile strength of 48 MPa (6.96 ksi) — weaker than 55% of polymer grades. Elongation at break is 26% and the elastic modulus is 2.2 GPa (0.319 Msi). PMMA-HI OPQ has a density of 1.16 g/cm³ (0.0419 lb/in³), lighter than 55% of polymer grades. Its glass-transition temperature is 102°C (216 °F).

Advantages

  • Polishes to a fine finish — 85/100, better than 92% of polymer grades
  • Good UV / weathering resistance — 85/100, better than 88% of polymer grades

Limitations

  • Needs corrosion protection — 70/100, worse than 78% of polymer grades
  • Limited service temperature — 72°C (162 °F), worse than 75% of polymer grades

PMMA-HI OPQ properties

Typical room-temperature values for PMMA-HI OPQ; 28 are specific to this condition. Other listed values are PMMA-HI reference data and may not represent this condition. Bars are the position among polymer grades.

Physical6

PMMA-HI OPQ has a density of 1.16 g/cm³ (0.0419 lb/in³), lighter than 55% of polymer grades. Its glass-transition temperature is 102°C (216 °F).

Density1.16 g/cm³0.04 lb/in³
Glass Transition (Tg)102°C216 °F
Water Absorption (24 h)0.3%
Water Absorption (Saturation)1.9%
Refractive Index1.49
Light Transmission0%

Mechanical17

PMMA-HI OPQ has a yield strength of 46 MPa (6.67 ksi) and a tensile strength of 48 MPa (6.96 ksi) — weaker than 55% of polymer grades. Elongation at break is 26% and the elastic modulus is 2.2 GPa (0.319 Msi).

Elastic (Young's) Modulus2.2 GPa0.32 Msi
Shear Modulus0.85 GPa0.12 Msi
Bulk Modulus5 GPa0.65 Msi
Poisson's Ratio0.38
Tensile Strength (Ultimate)48 MPa7 ksi
Yield Strength (0.2% offset)46 MPa6.7 ksi
Elongation at Break26%
Compressive Strength86 MPa12.5 ksi
Compressive Modulus2.3 GPa0.33 Msi
Flexural Strength76 MPa11 ksi
Flexural Modulus2.3 GPa0.33 Msi
Shear Strength44 MPa6.4 ksi
Fracture Toughness (K_IC)2.2 MPa·√m2 ksi·√in
Izod Impact, Notched65 J/m1.2 ft·lbf/in
Hardness, Shore D86 Shore D
Hardness, Rockwell M60 HRM
Hardness, Rockwell R112 HRR

Thermal11

PMMA-HI OPQ is rated for continuous service to 72°C (162 °F). It conducts heat at 0.19 W/m·K (0.11 BTU/hr·ft·°F), worse than 68% of polymer grades. Thermal expansion is 75 µm/m·K (41.7 µin/in·°F).

Thermal Conductivity0.19 W/m·K0.11 BTU/hr·ft·°F
Specific Heat Capacity1,470 J/kg·K0.35 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)75 µm/m·K41.7 µin/in·°F
Max Service Temperature (continuous)72°C162 °F
Min Service Temperature-40°C-40 °F
Heat Deflection Temp. @ 0.45 MPa87°C189 °F
Heat Deflection Temp. @ 1.8 MPa79°C174 °F
Vicat Softening Point (B50)99°C210 °F
Flammability (UL 94)HB (typical, 1.5–3 mm); FR-modified variants reach V-0
Limiting Oxygen Index18%
Max Service Temperature (short-term)90°C194 °F

Electrical7

PMMA-HI OPQ is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)2.8
Dissipation Factor (1 MHz)0.022
Volume Resistivity1×10¹⁵ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is very good (70/100), worse than 78% of polymer grades. UV resistance is excellent.

Corrosion ResistanceVery good70/100
UV / Weathering ResistanceExcellent85/100
Chemical Resistance SummaryGood against water, dilute acids/alkalis, aliphatic hydrocarbons, greases and mineral oils; attacked or stress-cracked by ketones, esters, chlorinated solvents, aromatics, alcohols (esp. ethanol/IPA cleaners) and concentrated oxidising acids. Notch- and solvent-stress-crack sensitivity is lower than GP PMMA but still the main field failure mode.

Sustainability4

Producing a kilogram of PMMA-HI OPQ takes about 103 MJ of energy and emits 5.6 kg of CO₂ — less than 54% of polymer grades. Typical recycled content is 2%.

Embodied Energy (primary production)103 MJ/kg44,282 BTU/lb
Embodied Carbon (primary production)5.6 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content2%

Manufacturability8

PMMA-HI OPQ's machinability is good (65/100, better than 66% of polymer grades); weldability poor (20/100); formability fair (45/100).

MachinabilityGood65/100
WeldabilityPoor20/100
Formability (cold)Fair45/100
PolishabilityExcellent85/100
Mold Shrinkage0.5%
Melt Flow Rate8 g/10 min
Processing Melt Temperature (typ.)235°C455 °F
Mold Temperature (typ.)70°C158 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PMMA-HI OPQ

Is PMMA-HI easy to machine?

Machines cleanly with sharp positive-rake carbide, high speed and low feed; less crazing/chipping than GP acrylic but still use coolant/air blast and avoid dwelling to prevent local softening.

Can PMMA-HI be welded?

No true fusion welding in practice — join by solvent cement (MMA/dichloromethane blends), acrylic structural adhesive, ultrasonic or hot-plate welding; anneal before solvent bonding to avoid stress crazing.

Can PMMA-HI be formed, bent or molded?

Dry 4 h at 80–90 °C before moulding; melt 210–260 °C, mould 50–90 °C, moderate injection speed and generous gates; thermoform sheet at 150–175 °C with shrinkage allowance ~0.4–0.7 %.

What surface finishes work on PMMA-HI?

Flame or diamond polishing restores gloss (haze slightly higher than GP PMMA); can be hard-coated for abrasion/UV, vacuum metallised or pad/screen printed with acrylic-compatible inks; anneal 80 °C to relieve stress before coating.

PMMA-HI chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
methyl methacrylate (MMA) unitsPMMA matrix70 – 9282
acrylate comonomer (methyl/ethyl acrylatthermal stability / flow modifier1 – 63
core-shell acrylic elastomer (butyl acryimpact modifier; MBS/butadiene types used in some non-weatherable grades8 – 2515
UV absorber / stabiliser / lubricant add0.1 – 1.50.5

PMMA-HI OPQ — frequently asked

What is PMMA-HI OPQ used for?

PMMA-HI OPQ is typically used for skylights, aircraft canopies, machine guards and impact-resistant glazing. In short: highest-impact acrylic grade; about 30 % elongation; less crazing when machined.

What is the yield strength of PMMA-HI OPQ?

PMMA-HI OPQ has a typical yield strength of 46 MPa (6.67 ksi) and a tensile strength of 48 MPa (6.96 ksi) — weaker than 55% of polymer grades. Strength varies by condition: see the 4 listed tempers.

Is PMMA-HI OPQ easy to machine?

Reasonably — machinability is rated good (65/100, better than 66% of polymer grades). Machines cleanly with sharp positive-rake carbide, high speed and low feed; less crazing/chipping than GP acrylic but still use coolant/air blast and avoid dwelling to prevent local softening.

Can PMMA-HI OPQ be welded?

Not readily — weldability is rated poor (20/100). No true fusion welding in practice — join by solvent cement (MMA/dichloromethane blends), acrylic structural adhesive, ultrasonic or hot-plate welding; anneal before solvent bonding to avoid stress crazing.

What surface finishes work on PMMA-HI OPQ?

Flame or diamond polishing restores gloss (haze slightly higher than GP PMMA); can be hard-coated for abrasion/UV, vacuum metallised or pad/screen printed with acrylic-compatible inks; anneal 80 °C to relieve stress before coating.

Can PMMA-HI OPQ be formed, bent or molded?

Dry 4 h at 80–90 °C before moulding; melt 210–260 °C, mould 50–90 °C, moderate injection speed and generous gates; thermoform sheet at 150–175 °C with shrinkage allowance ~0.4–0.7 %.

What is the maximum service temperature of PMMA-HI OPQ?

PMMA-HI OPQ is rated for continuous use to about 72°C (162 °F), and briefly to 90°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ISO 8257-2 Plastics — PMMA moulding and extrusion materials — Preparation of test specimens and determination of properties — ISO (2021)
  2. ASTM D788 Standard Classification System for Poly(Methyl Methacrylate) Molding and Extrusion Compounds — ASTM (2018)
  3. Impact-modified acrylic moulding compound datasheets (Plexiglas zk / Altuglas HFI / Sumipex HT / Acrypet IR series) — Röhm, Trinseo/Altuglas, Sumitomo, Mitsubishi Chemical (2023)
  4. CAMPUS plastics database — PMMA impact-modified grade property sets (ISO 10350-1) — CWFG/CAMPUS (2024)
  5. ASM Engineered Materials Handbook, Vol. 2: Engineering Plastics — ASM International (1988)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.