FabDigitFabDigit

PMMA-FR LS-FR

Flame-retardant grade

GB GB/T 7134-2008 Type 4

LS-FR = low-smoke FR

Use when smoke density and toxicity limits (EN 45545 HL2, GB/T 8627) govern, not just ignition resistance.

Premium cost $$$

Values for the LS-FR condition

Other PMMA-FR grades and fills

PMMA-FR is listed in 8 conditions; see the grade overview at PMMA-FR.

Compare all 8 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Impact-modified FR
For FR glazing and covers that must survive handling/impact; trades stiffness, hardness and heat resistance for 2–4× notched impact.—452560 HRM
LS-FRThis page
Low-smoke FR
Use when smoke density and toxicity limits (EN 45545 HL2, GB/T 8627) govern, not just ignition resistance.5456388 Shore D
UL 94 V-0 grade
Pick when a V-0 listing at 1.5–3 mm is mandatory (electrical enclosures, rail interiors); accept lower clarity and toughness.—553—
Extruded FR sheet
Lower-cost FR sheet with tighter thickness tolerance and easier thermoforming/solvent bonding; slightly lower heat and solvent resistance than cast.58604.586 Shore D
Halogen-free FR
Choose for RoHS/REACH-sensitive rail, marine and electronics parts where halogenated FR and corrosive smoke are prohibited.58603.587 Shore D
UV-stabilized FR
Adds HALS/UV absorbers to offset yellowing of the FR package for exterior signage, canopies and skylights.6164488 Shore D
UL 94 V-2 grade
Standard commercial FR acrylic where B1 / V-2 is sufficient and transparency must stay near virgin PMMA.6366488 Shore D
CAST-FRDefault
Cast FR sheet
Default choice for architectural glazing, partitions and signage that must pass B1 / UL 94 V-2 fire tests with high clarity.—684.5—

What is PMMA-FR LS-FR?

PMMA-FR LS-FR is PMMA-FR in the LS-FR grade — use when smoke density and toxicity limits (EN 45545 HL2, GB/T 8627) govern, not just ignition resistance. PMMA-FR LS-FR has a yield strength of 54 MPa (7.83 ksi) and a tensile strength of 56 MPa (8.12 ksi) — stronger than 60% of polymer grades. Elongation at break is 3% and the elastic modulus is 3.4 GPa (0.493 Msi). PMMA-FR LS-FR has a density of 1.26 g/cm³ (0.0455 lb/in³), heavier than 66% of polymer grades. Its glass-transition temperature is 103°C (217 °F). CAST-FR is the default condition FabDigit quotes; LS-FR is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 95/100, better than 98% of polymer grades
  • Good UV / weathering resistance — 80/100, better than 86% of polymer grades
  • Low, predictable mold shrinkage — 0.35%, better than 86% of polymer grades
  • Stiff — 3.4 GPa (0.493 Msi), better than 82% of polymer grades

Limitations

  • Low fracture toughness — 0.95 MPa·√m (0.865 ksi·√in), worse than 89% of polymer grades
  • Limited ductility — 3%, worse than 83% of polymer grades
  • Limited service temperature — 72°C (162 °F), worse than 75% of polymer grades

PMMA-FR LS-FR properties

Typical room-temperature values for PMMA-FR LS-FR; 29 are specific to this condition. Other listed values are PMMA-FR reference data and may not represent this condition. Bars are the position among polymer grades.

Physical6

PMMA-FR LS-FR has a density of 1.26 g/cm³ (0.0455 lb/in³), heavier than 66% of polymer grades. Its glass-transition temperature is 103°C (217 °F).

Density1.26 g/cm³0.05 lb/in³
Glass Transition (Tg)103°C217 °F
Water Absorption (24 h)0.3%
Water Absorption (Saturation)2%
Refractive Index1.49
Light Transmission80%

Mechanical16

PMMA-FR LS-FR has a yield strength of 54 MPa (7.83 ksi) and a tensile strength of 56 MPa (8.12 ksi) — stronger than 60% of polymer grades. Elongation at break is 3% and the elastic modulus is 3.4 GPa (0.493 Msi).

Elastic (Young's) Modulus3.4 GPa0.49 Msi
Shear Modulus1.2 GPa0.17 Msi
Bulk Modulus5 GPa0.73 Msi
Poisson's Ratio0.37
Tensile Strength (Ultimate)56 MPa8.1 ksi
Yield Strength (0.2% offset)54 MPa7.8 ksi
Elongation at Break3%
Compressive Strength105 MPa15.2 ksi
Compressive Modulus3 GPa0.44 Msi
Flexural Strength88 MPa12.8 ksi
Flexural Modulus3.3 GPa0.48 Msi
Shear Strength47 MPa6.8 ksi
Fracture Toughness (K_IC)0.95 MPa·√m0.86 ksi·√in
Izod Impact, Notched13 J/m0.24 ft·lbf/in
Hardness, Shore D88 Shore D
Hardness, Rockwell M89 HRM

Thermal11

PMMA-FR LS-FR is rated for continuous service to 72°C (162 °F). It conducts heat at 0.22 W/m·K (0.127 BTU/hr·ft·°F), better than 60% of polymer grades. Thermal expansion is 72 µm/m·K (40 µin/in·°F).

Thermal Conductivity0.22 W/m·K0.13 BTU/hr·ft·°F
Specific Heat Capacity1,470 J/kg·K0.35 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)72 µm/m·K40 µin/in·°F
Max Service Temperature (continuous)72°C162 °F
Min Service Temperature-40°C-40 °F
Heat Deflection Temp. @ 0.45 MPa88°C190 °F
Heat Deflection Temp. @ 1.8 MPa78°C172 °F
Vicat Softening Point (B50)96°C205 °F
Flammability (UL 94)V-0 at 3 mm with low smoke density (Ds4 < 300)
Limiting Oxygen Index32%
Max Service Temperature (short-term)95°C203 °F

Electrical7

PMMA-FR LS-FR is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)2.8
Dissipation Factor (1 MHz)0.02
Volume Resistivity1×10¹⁵ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is very good (78/100), worse than 61% of polymer grades. UV resistance is very good.

Corrosion ResistanceVery good78/100
UV / Weathering ResistanceVery good80/100
Chemical Resistance SummaryGood against dilute acids/alkalis, water, aliphatic hydrocarbons and mineral oils; attacked or stress-cracked by ketones, esters, chlorinated solvents, aromatic solvents and alcohols (methanol, IPA).

Sustainability4

Producing a kilogram of PMMA-FR LS-FR takes about 105 MJ of energy and emits 6.6 kg of CO₂ — more than 54% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)105 MJ/kg45,142 BTU/lb
Embodied Carbon (primary production)6.6 kg CO₂/kg
Embodied Water280 L/kg33.6 gal/lb
Typical Recycled Content0%

Manufacturability8

PMMA-FR LS-FR's machinability is very good (70/100, better than 74% of polymer grades); weldability fair (45/100); formability good (60/100).

MachinabilityVery good70/100
WeldabilityFair45/100
Formability (cold)Good60/100
PolishabilityExcellent95/100
Mold Shrinkage0.35%
Melt Flow Rate2 g/10 min
Processing Melt Temperature (typ.)235°C455 °F
Mold Temperature (typ.)70°C158 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PMMA-FR LS-FR

Is PMMA-FR easy to machine?

Machines and laser-cuts cleanly with sharp positive-rake tools, high speed and low feed; anneal at 75–80 °C before and after machining to avoid crazing, and avoid coolants containing alcohols.

Can PMMA-FR be welded?

Not fusion-welded in practice — join by solvent cementing (methylene chloride/MMA syrup) or acrylic structural adhesives; hot-gas and ultrasonic welding possible but give lower-strength joints.

Can PMMA-FR be formed, bent or molded?

Thermoform sheet at 140–160 °C after drying 2–4 h at 80 °C; injection mold at 210–245 °C melt / 55–85 °C mold and keep residence time short so the flame retardant does not decompose and discolor.

What surface finishes work on PMMA-FR?

Flame- or diamond-polish edges for optical clarity; can be screen-printed, hard-coated for abrasion resistance or vacuum-metallized — avoid solvent-based cleaners that craze the surface.

PMMA-FR chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
flame retardant (organophosphate ester /type determines halogen-free vs halogenated variant4 – 1810
antimony trioxide (synergist, halogenateomitted in halogen-free grades0 – 31
impact modifier (acrylic core-shell rubbimpact-modified variants only0 – 150
UV absorber / HALS, processing aids0.1 – 10.4
poly(methyl methacrylate) (MMA units)base resin; cast grades may include small methyl acrylate comonomer≥ 80 (balance)—

PMMA-FR LS-FR — frequently asked

What is PMMA-FR LS-FR used for?

PMMA-FR LS-FR is typically used for rail vehicle glazing, building interior panels, fire-rated signage and public transit windows. In short: fire-rated acrylic sheet; V-0 and low-smoke options; narrow processing window.

What is the yield strength of PMMA-FR LS-FR?

PMMA-FR LS-FR has a typical yield strength of 54 MPa (7.83 ksi) and a tensile strength of 56 MPa (8.12 ksi) — stronger than 60% of polymer grades. Strength varies by condition: see the 8 listed tempers.

Is PMMA-FR LS-FR easy to machine?

Yes — machinability is rated very good (70/100, better than 74% of polymer grades). Machines and laser-cuts cleanly with sharp positive-rake tools, high speed and low feed; anneal at 75–80 °C before and after machining to avoid crazing, and avoid coolants containing alcohols.

Can PMMA-FR LS-FR be welded?

With care — weldability is rated fair (45/100). Not fusion-welded in practice — join by solvent cementing (methylene chloride/MMA syrup) or acrylic structural adhesives; hot-gas and ultrasonic welding possible but give lower-strength joints.

What surface finishes work on PMMA-FR LS-FR?

Flame- or diamond-polish edges for optical clarity; can be screen-printed, hard-coated for abrasion resistance or vacuum-metallized — avoid solvent-based cleaners that craze the surface.

Can PMMA-FR LS-FR be formed, bent or molded?

Thermoform sheet at 140–160 °C after drying 2–4 h at 80 °C; injection mold at 210–245 °C melt / 55–85 °C mold and keep residence time short so the flame retardant does not decompose and discolor.

What is the maximum service temperature of PMMA-FR LS-FR?

PMMA-FR LS-FR is rated for continuous use to about 72°C (162 °F), and briefly to 95°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PMMA-FR CAST-FR and PMMA-FR V2?

CAST-FR is the default condition — default choice for architectural glazing, partitions and signage that must pass B1 / UL 94 V-2 fire tests with high clarity. V2: standard commercial FR acrylic where B1 / V-2 is sufficient and transparency must stay near virgin PMMA. Yield strength is 54 MPa in CAST-FR versus 63 MPa in V2.

Sources

  1. UL 94 Tests for Flammability of Plastic Materials — UL Solutions (2021)
  2. ISO 4589-2 Determination of burning behaviour by oxygen index — ISO (2017)
  3. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)
  4. CAMPUS plastics datasheets — PMMA (ISO 10350 property set) — CWFG (2024)
  5. Cast and extruded flame-retardant acrylic sheet technical data — Röhm / Mitsubishi Chemical / Chinese sheet producers (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.