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PEKK-ESD CNT-ANN

Print state

also ESD PEKK, PEKK ESD

CNT-ANN = cNT-filled ESD, annealed / heat-treated printed part

Post-print anneal above Tg raises crystallinity, stiffness and continuous-use temperature at the cost of a little ductility and ~0.3–0.8 % shrink.

3D printingSpecialty cost $$$$$

Values for the CNT-ANN condition

Other PEKK-ESD grades and fills

PEKK-ESD is listed in 5 conditions; see the grade overview at PEKK-ESD.

Compare all 5 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
CNT-filled ESD filament, FDM printed upright
Design allowable for loads across the build layers — expect roughly 60–75 % of in-plane strength and near-brittle failure.52551.685 Shore D
CNT-XZDefault
CNT-filled ESD filament, FDM printed flat
Standard commercial form: 2–3 % carbon-nanotube PEKK filament printed in-plane; use for ESD aerospace and electronics fixtures needing best strength.7882386 Shore D
CNT-ANNThis page
CNT-filled ESD, annealed / heat-treated printed part
Post-print anneal above Tg raises crystallinity, stiffness and continuous-use temperature at the cost of a little ductility and ~0.3–0.8 % shrink.84882.288 Shore D
Carbon-black conductive/ESD PEKK injection-molding compound
Lower-cost route for volume ESD parts (wafer handling, connectors); tighter resistivity control than printed parts but needs 380–400 °C barrel and hot molds.9095587 Shore D
Carbon-fiber reinforced ESD PEKK
Pick when stiffness and dimensional stability dominate and 10⁴–10⁶ Ω surface resistance is acceptable; more anisotropic and abrasive to nozzles/tools.—1051.5—

What is PEKK-ESD CNT-ANN?

PEKK-ESD CNT-ANN is PEKK-ESD in the CNT-ANN condition — post-print anneal above Tg raises crystallinity, stiffness and continuous-use temperature at the cost of a little ductility and ~0.3–0.8 % shrink. PEKK-ESD CNT-ANN has a yield strength of 84 MPa (12.2 ksi) and a tensile strength of 88 MPa (12.8 ksi) — stronger than 89% of polymer grades. Elongation at break is 2.2% and the elastic modulus is 3.9 GPa (0.566 Msi). PEKK-ESD CNT-ANN has a density of 1.33 g/cm³ (0.048 lb/in³), heavier than 73% of polymer grades. Its glass-transition temperature is 162°C (324 °F). CNT-XZ is the default condition FabDigit quotes; CNT-ANN is available on request or by drawing note.

Advantages

  • Good corrosion resistance — 93/100, better than 95% of polymer grades
  • High service temperature — 240°C (464 °F), better than 92% of polymer grades
  • High strength — 84 MPa (12.2 ksi), better than 89% of polymer grades
  • Conducts heat well — 0.32 W/m·K (0.185 BTU/hr·ft·°F), better than 88% of polymer grades
  • Stiff — 3.9 GPa (0.566 Msi), better than 86% of polymer grades

Limitations

  • High embodied carbon — 18 kg CO₂/kg, worse than 99% of polymer grades
  • Limited ductility — 2.2%, worse than 92% of polymer grades
  • Limited formability — 15/100, worse than 79% of polymer grades

PEKK-ESD CNT-ANN properties

Typical room-temperature values for PEKK-ESD CNT-ANN; 24 are specific to this condition. Other listed values are PEKK-ESD reference data and may not represent this condition. Bars are the position among polymer grades.

Physical5

PEKK-ESD CNT-ANN has a density of 1.33 g/cm³ (0.048 lb/in³), heavier than 73% of polymer grades. Its glass-transition temperature is 162°C (324 °F).

Density1.33 g/cm³0.05 lb/in³
Melting Temperature (Tm)305°C581 °F
Glass Transition (Tg)162°C324 °F
Water Absorption (24 h)0.14%
Water Absorption (Saturation)0.5%

Mechanical16

PEKK-ESD CNT-ANN has a yield strength of 84 MPa (12.2 ksi) and a tensile strength of 88 MPa (12.8 ksi) — stronger than 89% of polymer grades. Elongation at break is 2.2% and the elastic modulus is 3.9 GPa (0.566 Msi).

Elastic (Young's) Modulus3.9 GPa0.57 Msi
Shear Modulus1.3 GPa0.18 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)88 MPa12.8 ksi
Yield Strength (0.2% offset)84 MPa12.2 ksi
Elongation at Break2.2%
Compressive Strength125 MPa18.1 ksi
Compressive Modulus3.2 GPa0.46 Msi
Flexural Strength138 MPa20 ksi
Flexural Modulus4 GPa0.58 Msi
Shear Strength58 MPa8.4 ksi
Fracture Toughness (K_IC)2.8 MPa·√m2.5 ksi·√in
Izod Impact, Notched28 J/m0.52 ft·lbf/in
Hardness, Shore D88 Shore D
Hardness, Rockwell M102 HRM
Hardness, Rockwell R126 HRR

Thermal11

PEKK-ESD CNT-ANN is rated for continuous service to 240°C (464 °F). It conducts heat at 0.32 W/m·K (0.185 BTU/hr·ft·°F), better than 88% of polymer grades. Thermal expansion is 42 µm/m·K (23.3 µin/in·°F).

Thermal Conductivity0.32 W/m·K0.18 BTU/hr·ft·°F
Specific Heat Capacity1,050 J/kg·K0.25 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)42 µm/m·K23.3 µin/in·°F
Max Service Temperature (continuous)240°C464 °F
Min Service Temperature-50°C-58 °F
Heat Deflection Temp. @ 0.45 MPa190°C374 °F
Heat Deflection Temp. @ 1.8 MPa175°C347 °F
Vicat Softening Point (B50)185°C365 °F
Flammability (UL 94)V-0 at 1.5 mm (inherently flame retardant, halogen free); very low smoke and heat release
Limiting Oxygen Index40%
Max Service Temperature (short-term)280°C536 °F

Electrical3

PEKK-ESD CNT-ANN has an electrical resistivity of 8,000 Ω·m.

Electrical Resistivity8,000 Ω·m3.15×10¹¹ µΩ·in
Volume Resistivity1,000,000 Ω·cm
Surface Resistivity1×10⁸ Ω

Chemical & Environmental3

Corrosion resistance is excellent (93/100), better than 95% of polymer grades. UV resistance is very good.

Corrosion ResistanceExcellent93/100
UV / Weathering ResistanceVery good70/100
Chemical Resistance SummaryExcellent against hydrocarbons, jet fuel, hydraulic fluids, dilute acids/bases, steam and radiation; attacked only by concentrated sulfuric acid and some halogenated/aromatic solvents at elevated temperature.

Sustainability4

Producing a kilogram of PEKK-ESD CNT-ANN takes about 350 MJ of energy and emits 18 kg of CO₂ — more than 100% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)350 MJ/kg150,473 BTU/lb
Embodied Carbon (primary production)18 kg CO₂/kg
Embodied Water600 L/kg71.9 gal/lb
Typical Recycled Content0%

Manufacturability8

PEKK-ESD CNT-ANN's machinability is good (60/100, better than 51% of polymer grades); weldability poor (25/100); formability poor (15/100).

MachinabilityGood60/100
WeldabilityPoor25/100
Formability (cold)Poor15/100
PolishabilityFair50/100
Mold Shrinkage1%
Melt Flow Rate4 g/10 min
Processing Melt Temperature (typ.)390°C734 °F
Mold Temperature (typ.)190°C374 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PEKK-ESD CNT-ANN

Is PEKK-ESD easy to machine?

Machines like PEEK but the CNT/carbon filler is abrasive — use sharp polished carbide or diamond-coated tools, high speed, light feeds, air or mist cooling, and stress-relieve near Tg before final passes.

Can PEKK-ESD be welded?

No solvent bonding; joining is by ultrasonic/laser/hot-plate welding at PAEK temperatures or by mechanical fasteners and high-temperature epoxy after plasma/abrasion prep.

Can PEKK-ESD be formed, bent or molded?

FDM needs ~400 °C liquefier with a 190–200 °C heated chamber and dried filament (<0.05 % moisture); injection molding needs 370–400 °C melt, 175–200 °C mold and slow cooling for consistent crystallinity.

What surface finishes work on PEKK-ESD?

Vapor smoothing is not applicable; bead-blast or sand and lightly buff. Do not paint or coat with insulating films if the ESD surface path must be preserved — conductivity comes from the bulk filler network.

PEKK-ESD chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
carbon nanotubes (MWCNT)conductive network for 10^6–10^9 Ω surface resistance1 – 42.5
processing additives / pigments0 – 10.3
poly(ether ketone ketone) (PEKK) resinterephthaloyl/isophthaloyl (T/I) ratio sets Tm and crystallization rate≥ 95 (balance)—

PEKK-ESD CNT-ANN — frequently asked

What is PEKK-ESD CNT-ANN used for?

PEKK-ESD CNT-ANN is typically used for aerospace ducting, fuel system parts and ESD-critical tooling. In short: ESD-safe high-performance PEKK.

What is the yield strength of PEKK-ESD CNT-ANN?

PEKK-ESD CNT-ANN has a typical yield strength of 84 MPa (12.2 ksi) and a tensile strength of 88 MPa (12.8 ksi) — stronger than 89% of polymer grades. Strength varies by condition: see the 5 listed tempers.

Is PEKK-ESD CNT-ANN easy to machine?

Reasonably — machinability is rated good (60/100, better than 51% of polymer grades). Machines like PEEK but the CNT/carbon filler is abrasive — use sharp polished carbide or diamond-coated tools, high speed, light feeds, air or mist cooling, and stress-relieve near Tg before final passes.

Can PEKK-ESD CNT-ANN be welded?

Not readily — weldability is rated poor (25/100). No solvent bonding; joining is by ultrasonic/laser/hot-plate welding at PAEK temperatures or by mechanical fasteners and high-temperature epoxy after plasma/abrasion prep.

What surface finishes work on PEKK-ESD CNT-ANN?

Vapor smoothing is not applicable; bead-blast or sand and lightly buff. Do not paint or coat with insulating films if the ESD surface path must be preserved — conductivity comes from the bulk filler network.

Can PEKK-ESD CNT-ANN be formed, bent or molded?

FDM needs ~400 °C liquefier with a 190–200 °C heated chamber and dried filament (<0.05 % moisture); injection molding needs 370–400 °C melt, 175–200 °C mold and slow cooling for consistent crystallinity.

What is the maximum service temperature of PEKK-ESD CNT-ANN?

PEKK-ESD CNT-ANN is rated for continuous use to about 240°C (464 °F), and briefly to 280°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PEKK-ESD CNT-XZ and PEKK-ESD CNT-ZX?

CNT-XZ is the default condition — standard commercial form: 2–3 % carbon-nanotube PEKK filament printed in-plane; use for ESD aerospace and electronics fixtures needing best strength. CNT-ZX: design allowable for loads across the build layers — expect roughly 60–75 % of in-plane strength and near-brittle failure. Yield strength is 78 MPa in CNT-XZ versus 52 MPa in CNT-ZX.

Can FabDigit make parts in PEKK-ESD CNT-ANN?

Yes — PEKK-ESD CNT-ANN is available for 3D printing; every part is priced by an engineer rather than instantly. Upload a STEP file to get a price and a DFM check.

Sources

  1. Antero 840CN03 (PEKK-based ESD FDM material) datasheet — Stratasys (2023)
  2. Kepstan PEKK 6000/7000 series product data — Arkema (2022)
  3. PAEK/high-temperature thermoplastics property overview — ASM International (2016)
  4. CAMPUS / UL Prospector PAEK compound entries — CAMPUS Plastics (2024)
  5. ANSI/ESD S541 and IEC 61340-5-1 surface resistance classification — ESD Association / IEC (2019)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.