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Steel 4Cr5MoSiV1-NIT (Nitrided)

Finish state

AISI/SAE H13 · EN 1.2343

Surface treatment for soldering/washout and abrasive wear resistance on die-casting and extrusion tooling; keep case thin (<0.1 mm) to limit heat-check cracking.

Standard cost $$

Values for the NIT condition

Other 4Cr5MoSiV1 tempers and conditions

4Cr5MoSiV1 is listed in 8 conditions; see the grade overview at 4Cr5MoSiV1.

Compare all 8 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNDefault
Annealed
Standard mill-supplied condition for machining the die cavity before hardening.46076020210 HB26 W/m·K
Electroslag remelted premium quality
Choose for large die-casting dies, mirror-polished cavities and where NADCA #207 cleanliness/isotropy is specified.4707702314 HRC3.3 % IACS
hardened and high-temperature tempered
Toughest working hardness — large forging dies, hot shear blades and heavily shock-loaded inserts.1,1801,3601242 HRC25 W/m·K
NITThis page
Nitrided
Surface treatment for soldering/washout and abrasive wear resistance on die-casting and extrusion tooling; keep case thin (<0.1 mm) to limit heat-check cracking.1,2801,500847 HRC3.1 % IACS
hardened and double tempered
Standard hardness for large aluminium die-casting dies and extrusion tooling where heat checking dominates.1,3001,5001145 HRC—
Q&T 46–48 HRC
Most common all-round working hardness for die-casting inserts, cores and hot-extrusion dies.1,4201,650947 HRC—
Q&T 48–50 HRC
Higher wear resistance for small inserts, cores, ejector components and plastic-mould applications.1,5401,790849 HRC—
maximum hardness condition
Maximum wear resistance for hot punches, mandrels and small tooling where toughness is secondary.1,6501,960652 HRC—

What is 4Cr5MoSiV1-NIT?

4Cr5MoSiV1-NIT is 4Cr5MoSiV1 supplied in the NIT condition — surface treatment for soldering/washout and abrasive wear resistance on die-casting and extrusion tooling; keep case thin (<0.1 mm) to limit heat-check cracking. 4Cr5MoSiV1-NIT has a yield strength of 1,280 MPa (186 ksi) and a tensile strength of 1,500 MPa (218 ksi) — stronger than 95% of steel grades. Elongation at break is 8% and the elastic modulus is 210 GPa (30.5 Msi). 4Cr5MoSiV1-NIT has a density of 7.8 g/cm³ (0.282 lb/in³), lighter than 87% of steel grades. It melts at 1,315°C (2,399 °F). ANN is the default condition FabDigit quotes; NIT is available on request or by drawing note.

Advantages

  • High strength — 1,280 MPa (186 ksi), better than 95% of steel grades
  • Good corrosion resistance — 28/100, better than 94% of steel grades
  • Polishes to a fine finish — 75/100, better than 94% of steel grades
  • High service temperature — 540°C (1,004 °F), better than 93% of steel grades

Limitations

  • Difficult to machine — 5/100, worse than 100% of steel grades
  • Limited formability — 2/100, worse than 100% of steel grades
  • Difficult to weld — 8/100, worse than 99% of steel grades
  • Limited ductility — 8%, worse than 95% of steel grades
  • High embodied carbon — 2.9 kg CO₂/kg, worse than 91% of steel grades

4Cr5MoSiV1-NIT properties

Typical room-temperature values for 4Cr5MoSiV1-NIT; 22 are specific to this condition. Other listed values are 4Cr5MoSiV1 reference data and may not represent this condition. Bars are the position among steel grades.

Physical3

4Cr5MoSiV1-NIT has a density of 7.8 g/cm³ (0.282 lb/in³), lighter than 87% of steel grades. It melts at 1,315°C (2,399 °F).

Density7.8 g/cm³0.28 lb/in³
Melting Point (Solidus)1,315°C2,399 °F
Liquidus Temperature1,454°C2,649 °F

Mechanical14

4Cr5MoSiV1-NIT has a yield strength of 1,280 MPa (186 ksi) and a tensile strength of 1,500 MPa (218 ksi) — stronger than 95% of steel grades. Elongation at break is 8% and the elastic modulus is 210 GPa (30.5 Msi).

Elastic (Young's) Modulus210 GPa30.5 Msi
Shear Modulus81 GPa11.7 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)1,500 MPa218 ksi
Yield Strength (0.2% offset)1,280 MPa186 ksi
Elongation at Break8%
Reduction in Area30%
Compressive Strength2,100 MPa305 ksi
Shear Strength900 MPa131 ksi
Charpy V-Notch Impact (RT)8 J5.9 ft·lbf
Hardness, Brinell450 HB
Hardness, Rockwell B95 HRB
Hardness, Vickers1,100 HV

Thermal6

4Cr5MoSiV1-NIT is rated for continuous service to 540°C (1,004 °F). It conducts heat at 25 W/m·K (14.4 BTU/hr·ft·°F), worse than 88% of steel grades. Thermal expansion is 10.9 µm/m·K (6.06 µin/in·°F).

Thermal Conductivity25 W/m·K14.4 BTU/hr·ft·°F
Specific Heat Capacity460 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)10.9 µm/m·K6.1 µin/in·°F
Latent Heat of Fusion250 J/g107 BTU/lb
Max Service Temperature (continuous)540°C1,004 °F
Min Service Temperature-30°C-22 °F

Electrical3

4Cr5MoSiV1-NIT conducts electricity at 3.1 % IACS, worse than 89% of steel grades.

Electrical Conductivity3.1 % IACS
Electrical Resistivity5.5×10⁻⁷ Ω·m21.7 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is poor (28/100), better than 94% of steel grades.

Galvanic Potential (seawater, vs SCE)-0.55 V
Corrosion ResistancePoor28/100
Chemical Resistance SummaryNot corrosion resistant: rusts in humid air and in water-based die lubricants/coolants; attacked by acids and chlorides. Resists molten aluminium erosion moderately (main die-casting use) but is dissolved by molten Al on prolonged contact; needs oiling, nitriding or PVD coating for storage and service.

Sustainability4

Producing a kilogram of 4Cr5MoSiV1-NIT takes about 36 MJ of energy and emits 2.9 kg of CO₂ — more than 89% of steel grades. Typical recycled content is 40%.

Embodied Energy (primary production)36 MJ/kg15,477 BTU/lb
Embodied Carbon (primary production)2.9 kg CO₂/kg
Embodied Water80 L/kg9.6 gal/lb
Typical Recycled Content40%

Manufacturability7

4Cr5MoSiV1-NIT's machinability is not recommended (5/100, worse than 100% of steel grades); weldability not recommended (8/100); formability not recommended (2/100).

MachinabilityNot recommended5/100
Machinability Rating (AISI 1212 = 100 %)5%
WeldabilityNot recommended8/100
Formability (cold)Not recommended2/100
CastabilityPoor30/100
Brazeability / SolderabilityFair35/100
PolishabilityVery good75/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with 4Cr5MoSiV1-NIT

Is 4Cr5MoSiV1 easy to machine?

Machine in the annealed state (≤235 HB) with carbide tooling and rigid setups; hardened 45–52 HRC work needs coated carbide/CBN, low feeds or EDM, and EDM white layer must be stoned or polished off and re-tempered.

Can 4Cr5MoSiV1 be welded?

Repair welding only: preheat/interpass 300–425 °C with matched H13 or softer filler, slow cool, then temper 15–30 °C below the previous tempering temperature.

Can 4Cr5MoSiV1 be formed, bent or molded?

Hot forge 1120–900 °C followed by slow cooling and full spheroidize anneal at 845–900 °C; harden 1000–1030 °C, air/gas quench, then double or triple temper 550–620 °C for secondary hardening.

What surface finishes work on 4Cr5MoSiV1?

Nitride, oxidize or PVD-coat (CrN/AlTiN) working faces for soldering and wear resistance; ESR stock takes a high polish, but all surfaces must be oiled or coated since the 5% Cr gives no rust protection.

4Cr5MoSiV1 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
C0.32 – 0.450.39
Si0.8 – 1.21
Mn0.2 – 0.50.35
Cr4.75 – 5.55.1
Mo1.1 – 1.751.4
V0.8 – 1.21
P≤0.015 for premium/ESR (NADCA #207)≤ 0.03—
S≤0.005 for premium/ESR≤ 0.03—
Niresidual≤ 0.3—
Curesidual≤ 0.25—
Febalance—

4Cr5MoSiV1-NIT — frequently asked

What is 4Cr5MoSiV1-NIT used for?

4Cr5MoSiV1-NIT is typically used for die-casting dies, extrusion dies, forging dies and hot punches. In short: industry-standard hot-work steel; H13 equivalent; good thermal-fatigue resistance.

What is the yield strength of 4Cr5MoSiV1-NIT?

4Cr5MoSiV1-NIT has a typical yield strength of 1,280 MPa (186 ksi) and a tensile strength of 1,500 MPa (218 ksi) — stronger than 95% of steel grades. Strength varies by condition: see the 8 listed tempers.

Is 4Cr5MoSiV1-NIT easy to machine?

Not especially — machinability is rated not recommended (5/100, worse than 100% of steel grades). Machine in the annealed state (≤235 HB) with carbide tooling and rigid setups; hardened 45–52 HRC work needs coated carbide/CBN, low feeds or EDM, and EDM white layer must be stoned or polished off and re-tempered.

Can 4Cr5MoSiV1-NIT be welded?

Not readily — weldability is rated not recommended (8/100). Repair welding only: preheat/interpass 300–425 °C with matched H13 or softer filler, slow cool, then temper 15–30 °C below the previous tempering temperature.

What surface finishes work on 4Cr5MoSiV1-NIT?

Nitride, oxidize or PVD-coat (CrN/AlTiN) working faces for soldering and wear resistance; ESR stock takes a high polish, but all surfaces must be oiled or coated since the 5% Cr gives no rust protection.

Can 4Cr5MoSiV1-NIT be formed, bent or molded?

Hot forge 1120–900 °C followed by slow cooling and full spheroidize anneal at 845–900 °C; harden 1000–1030 °C, air/gas quench, then double or triple temper 550–620 °C for secondary hardening.

What is the maximum service temperature of 4Cr5MoSiV1-NIT?

4Cr5MoSiV1-NIT is rated for continuous use to about 540°C (1,004 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between 4Cr5MoSiV1-ANN and 4Cr5MoSiV1-NIT?

ANN is the default condition — standard mill-supplied condition for machining the die cavity before hardening. NIT: surface treatment for soldering/washout and abrasive wear resistance on die-casting and extrusion tooling; keep case thin (<0.1 mm) to limit heat-check cracking. Yield strength is 460 MPa in ANN versus 1,280 MPa in NIT.

Sources

  1. GB/T 1299 (4Cr5MoSiV1) (2014)
  2. ASTM A681 Standard Specification for Tool Steels Alloy (H13) — ASTM International (2015)
  3. ASM Handbook Vol.1 — Properties and Selection: Irons, Steels, and High-Performance Alloys — ASM International (1990)
  4. Orvar Supreme / Orvar 2 Microdized H13 datasheet — Uddeholm (2022)
  5. BÖHLER W302 hot work tool steel datasheet — voestalpine BÖHLER Edelstahl (2021)
  6. NADCA #207 Special Quality Die Steel & Heat Treatment Acceptance Criteria — North American Die Casting Association (2020)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.