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Steel 4Cr5MoSiV1-ANN (Annealed)

Heat-treated state · default condition

AISI/SAE H13 · EN 1.2343

Standard mill-supplied condition for machining the die cavity before hardening.

Standard cost $$

Values for the ANN condition

Other 4Cr5MoSiV1 tempers and conditions

4Cr5MoSiV1 is listed in 8 conditions; see the grade overview at 4Cr5MoSiV1.

Compare all 8 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNDefaultThis page
Annealed
Standard mill-supplied condition for machining the die cavity before hardening.46076020210 HB26 W/m·K
Electroslag remelted premium quality
Choose for large die-casting dies, mirror-polished cavities and where NADCA #207 cleanliness/isotropy is specified.4707702314 HRC3.3 % IACS
hardened and high-temperature tempered
Toughest working hardness — large forging dies, hot shear blades and heavily shock-loaded inserts.1,1801,3601242 HRC25 W/m·K
Nitrided
Surface treatment for soldering/washout and abrasive wear resistance on die-casting and extrusion tooling; keep case thin (<0.1 mm) to limit heat-check cracking.1,2801,500847 HRC3.1 % IACS
hardened and double tempered
Standard hardness for large aluminium die-casting dies and extrusion tooling where heat checking dominates.1,3001,5001145 HRC—
Q&T 46–48 HRC
Most common all-round working hardness for die-casting inserts, cores and hot-extrusion dies.1,4201,650947 HRC—
Q&T 48–50 HRC
Higher wear resistance for small inserts, cores, ejector components and plastic-mould applications.1,5401,790849 HRC—
maximum hardness condition
Maximum wear resistance for hot punches, mandrels and small tooling where toughness is secondary.1,6501,960652 HRC—

What is 4Cr5MoSiV1-ANN?

4Cr5MoSiV1-ANN is 4Cr5MoSiV1 heat treated to ANN — standard mill-supplied condition for machining the die cavity before hardening. 4Cr5MoSiV1-ANN has a yield strength of 460 MPa (66.7 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 55% of steel grades. Elongation at break is 20% and the elastic modulus is 210 GPa (30.5 Msi). 4Cr5MoSiV1-ANN has a density of 7.8 g/cm³ (0.282 lb/in³), lighter than 87% of steel grades. It melts at 1,315°C (2,399 °F).

Advantages

  • Polishes to a fine finish — 75/100, better than 94% of steel grades

Limitations

  • High embodied carbon — 2.9 kg CO₂/kg, worse than 91% of steel grades
  • Poor heat conductor — 26 W/m·K (15 BTU/hr·ft·°F), worse than 87% of steel grades
  • Low electrical conductivity — 3.3 % IACS, worse than 86% of steel grades

4Cr5MoSiV1-ANN properties

Typical room-temperature values for 4Cr5MoSiV1-ANN; 11 are specific to this condition. Other listed values are 4Cr5MoSiV1 reference data and may not represent this condition. Bars are the position among steel grades.

Physical3

4Cr5MoSiV1-ANN has a density of 7.8 g/cm³ (0.282 lb/in³), lighter than 87% of steel grades. It melts at 1,315°C (2,399 °F).

Density7.8 g/cm³0.28 lb/in³
Melting Point (Solidus)1,315°C2,399 °F
Liquidus Temperature1,454°C2,649 °F

Mechanical14

4Cr5MoSiV1-ANN has a yield strength of 460 MPa (66.7 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 55% of steel grades. Elongation at break is 20% and the elastic modulus is 210 GPa (30.5 Msi).

Elastic (Young's) Modulus210 GPa30.5 Msi
Shear Modulus81 GPa11.7 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)760 MPa110 ksi
Yield Strength (0.2% offset)460 MPa66.7 ksi
Elongation at Break20%
Reduction in Area45%
Compressive Strength900 MPa131 ksi
Shear Strength460 MPa66.7 ksi
Charpy V-Notch Impact (RT)40 J29.5 ft·lbf
Hardness, Brinell210 HB
Hardness, Rockwell B95 HRB
Hardness, Vickers220 HV

Thermal6

4Cr5MoSiV1-ANN is rated for continuous service to 400°C (752 °F). It conducts heat at 26 W/m·K (15 BTU/hr·ft·°F), worse than 87% of steel grades. Thermal expansion is 10.9 µm/m·K (6.06 µin/in·°F).

Thermal Conductivity26 W/m·K15 BTU/hr·ft·°F
Specific Heat Capacity460 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)10.9 µm/m·K6.1 µin/in·°F
Latent Heat of Fusion250 J/g107 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-30°C-22 °F

Electrical3

4Cr5MoSiV1-ANN conducts electricity at 3.3 % IACS, worse than 86% of steel grades.

Electrical Conductivity3.3 % IACS
Electrical Resistivity5.2×10⁻⁷ Ω·m20.5 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is poor (20/100), better than 87% of steel grades.

Galvanic Potential (seawater, vs SCE)-0.55 V
Corrosion ResistancePoor20/100
Chemical Resistance SummaryNot corrosion resistant: rusts in humid air and in water-based die lubricants/coolants; attacked by acids and chlorides. Resists molten aluminium erosion moderately (main die-casting use) but is dissolved by molten Al on prolonged contact; needs oiling, nitriding or PVD coating for storage and service.

Sustainability4

Producing a kilogram of 4Cr5MoSiV1-ANN takes about 36 MJ of energy and emits 2.9 kg of CO₂ — more than 89% of steel grades. Typical recycled content is 40%.

Embodied Energy (primary production)36 MJ/kg15,477 BTU/lb
Embodied Carbon (primary production)2.9 kg CO₂/kg
Embodied Water80 L/kg9.6 gal/lb
Typical Recycled Content40%

Manufacturability7

4Cr5MoSiV1-ANN's machinability is fair (45/100, worse than 65% of steel grades); weldability fair (40/100); formability poor (25/100).

MachinabilityFair45/100
Machinability Rating (AISI 1212 = 100 %)55%
WeldabilityFair40/100
Formability (cold)Poor25/100
CastabilityPoor30/100
Brazeability / SolderabilityFair35/100
PolishabilityVery good75/100

Common Calculations5

Specific Strength (UTS / density)calculated97 kN·m/kg
Specific Stiffness (E / density)calculated26.9 MN·m/kg
Modulus of Resiliencecalculated504 kJ/m³
Thermal Diffusivitycalculated7.2 mm²/s
Thermal Shock Resistance Indexcalculated9

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with 4Cr5MoSiV1-ANN

Is 4Cr5MoSiV1 easy to machine?

Machine in the annealed state (≤235 HB) with carbide tooling and rigid setups; hardened 45–52 HRC work needs coated carbide/CBN, low feeds or EDM, and EDM white layer must be stoned or polished off and re-tempered.

Can 4Cr5MoSiV1 be welded?

Repair welding only: preheat/interpass 300–425 °C with matched H13 or softer filler, slow cool, then temper 15–30 °C below the previous tempering temperature.

Can 4Cr5MoSiV1 be formed, bent or molded?

Hot forge 1120–900 °C followed by slow cooling and full spheroidize anneal at 845–900 °C; harden 1000–1030 °C, air/gas quench, then double or triple temper 550–620 °C for secondary hardening.

What surface finishes work on 4Cr5MoSiV1?

Nitride, oxidize or PVD-coat (CrN/AlTiN) working faces for soldering and wear resistance; ESR stock takes a high polish, but all surfaces must be oiled or coated since the 5% Cr gives no rust protection.

4Cr5MoSiV1 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
C0.32 – 0.450.39
Si0.8 – 1.21
Mn0.2 – 0.50.35
Cr4.75 – 5.55.1
Mo1.1 – 1.751.4
V0.8 – 1.21
P≤0.015 for premium/ESR (NADCA #207)≤ 0.03—
S≤0.005 for premium/ESR≤ 0.03—
Niresidual≤ 0.3—
Curesidual≤ 0.25—
Febalance—

4Cr5MoSiV1-ANN — frequently asked

What is 4Cr5MoSiV1-ANN used for?

4Cr5MoSiV1-ANN is typically used for die-casting dies, extrusion dies, forging dies and hot punches. In short: industry-standard hot-work steel; H13 equivalent; good thermal-fatigue resistance.

What is the yield strength of 4Cr5MoSiV1-ANN?

4Cr5MoSiV1-ANN has a typical yield strength of 460 MPa (66.7 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 55% of steel grades. Strength varies by condition: see the 8 listed tempers.

Is 4Cr5MoSiV1-ANN easy to machine?

Reasonably — machinability is rated fair (45/100, worse than 65% of steel grades). Machine in the annealed state (≤235 HB) with carbide tooling and rigid setups; hardened 45–52 HRC work needs coated carbide/CBN, low feeds or EDM, and EDM white layer must be stoned or polished off and re-tempered.

Can 4Cr5MoSiV1-ANN be welded?

With care — weldability is rated fair (40/100). Repair welding only: preheat/interpass 300–425 °C with matched H13 or softer filler, slow cool, then temper 15–30 °C below the previous tempering temperature.

What surface finishes work on 4Cr5MoSiV1-ANN?

Nitride, oxidize or PVD-coat (CrN/AlTiN) working faces for soldering and wear resistance; ESR stock takes a high polish, but all surfaces must be oiled or coated since the 5% Cr gives no rust protection.

Can 4Cr5MoSiV1-ANN be formed, bent or molded?

Hot forge 1120–900 °C followed by slow cooling and full spheroidize anneal at 845–900 °C; harden 1000–1030 °C, air/gas quench, then double or triple temper 550–620 °C for secondary hardening.

What is the maximum service temperature of 4Cr5MoSiV1-ANN?

4Cr5MoSiV1-ANN is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between 4Cr5MoSiV1-ANN and 4Cr5MoSiV1-NIT?

ANN is the default condition — standard mill-supplied condition for machining the die cavity before hardening. NIT: surface treatment for soldering/washout and abrasive wear resistance on die-casting and extrusion tooling; keep case thin (<0.1 mm) to limit heat-check cracking. Yield strength is 460 MPa in ANN versus 1,280 MPa in NIT.

Sources

  1. GB/T 1299 (4Cr5MoSiV1) (2014)
  2. ASTM A681 Standard Specification for Tool Steels Alloy (H13) — ASTM International (2015)
  3. ASM Handbook Vol.1 — Properties and Selection: Irons, Steels, and High-Performance Alloys — ASM International (1990)
  4. Orvar Supreme / Orvar 2 Microdized H13 datasheet — Uddeholm (2022)
  5. BÖHLER W302 hot work tool steel datasheet — voestalpine BÖHLER Edelstahl (2021)
  6. NADCA #207 Special Quality Die Steel & Heat Treatment Acceptance Criteria — North American Die Casting Association (2020)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.