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Steel A231-ANN (Annealed)

Heat-treated state

ASTM A231

Choose fully annealed bar or rod at 197 HB when parts must be machined, cold headed or re-heat-treated afterwards; strength is only 670 MPa tensile with 23% elongation.

Standard cost $$

Values for the ANN condition

Other A231 tempers and conditions

A231 is listed in 10 conditions; see the grade overview at A231.

Compare all 10 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNThis page
Annealed
Choose fully annealed bar or rod at 197 HB when parts must be machined, cold headed or re-heat-treated afterwards; strength is only 670 MPa tensile with 23% elongation.41567023197 HB—
Normalized
Use air cooling from about 870 °C to homogenise the structure and remove forging banding as a pre-treatment before hardening; 940 MPa tensile is not a final service condition.6159402227 HRC8 % IACS
Cold drawn
Pick annealed then cold-drawn bar for dimensional accuracy and straightness on turned parts that will be quenched and tempered afterwards; drawing raises yield to 640 MPa at 14% elongation.6407901421 HRC7.8 % IACS
Q&T
Choose the 650 °C temper at about 30 HRC for large-section structural parts needing maximum toughness and machinability, accepting 1000 MPa tensile and 17% elongation.9401,0001731 HRC7.5 % IACS
Q&T
Use the 540 °C temper at about 38 HRC when impact toughness leads, as on shafts and pins; tensile drops to 1290 MPa but elongation reaches 13% and service temperature 400 °C.1,2101,2901338 HRC—
OTDefault
Oil tempered spring wire
Pick the as-supplied oil-quenched and tempered chromium-vanadium spring wire for cold-coiled springs; strength is graded by wire diameter and formability is limited at a score of 30.1,4001,550946 HRC—
OT + stress relieved after coiling
Apply the 315–425 °C stress relief after coiling, a mandatory step that restores the elastic limit, stabilises free length and improves fatigue life while holding about 45 HRC.1,4301,520945 HRC7.5 % IACS
Q&T
Pick the 425 °C temper at about 43 HRC as the usual strength-toughness balance for suspension springs and high-stress fasteners, giving 1550 MPa tensile and 10% elongation.1,4301,5501043 HRC—
Q&T
Choose the 315 °C temper at about 47 HRC for leaf springs and torsion bars needing 1860 MPa tensile with slightly more ductility than the 205 °C temper.1,6201,860947 HRC—
Q&T
Use the 845 °C oil quench with 205 °C temper for maximum strength, 1930 MPa tensile at 50 HRC, in high-stress spring plates and tooling, accepting the lowest toughness of the range.1,6901,930850 HRC—

What is A231-ANN?

A231-ANN is A231 heat treated to ANN — choose fully annealed bar or rod at 197 HB when parts must be machined, cold headed or re-heat-treated afterwards; strength is only 670 MPa tensile with 23% elongation. A231-ANN has a yield strength of 415 MPa (60.2 ksi) and a tensile strength of 670 MPa (97.2 ksi) — weaker than 56% of steel grades. Elongation at break is 23% and the elastic modulus is 207 GPa (30 Msi). A231-ANN has a density of 7.85 g/cm³ (0.284 lb/in³), heavier than 56% of steel grades. It melts at 1,420°C (2,588 °F). OT is the default condition FabDigit quotes; ANN is available on request or by drawing note.

Limitations

  • Low fracture toughness — 45 MPa·√m (41 ksi·√in), worse than 90% of steel grades
  • Limited service temperature — 220°C (428 °F), worse than 89% of steel grades

A231-ANN properties

Typical room-temperature values for A231-ANN; 12 are specific to this condition. Other listed values are A231 reference data and may not represent this condition. Bars are the position among steel grades.

Physical3

A231-ANN has a density of 7.85 g/cm³ (0.284 lb/in³), heavier than 56% of steel grades. It melts at 1,420°C (2,588 °F).

Density7.85 g/cm³0.28 lb/in³
Melting Point (Solidus)1,420°C2,588 °F
Liquidus Temperature1,490°C2,714 °F

Mechanical15

A231-ANN has a yield strength of 415 MPa (60.2 ksi) and a tensile strength of 670 MPa (97.2 ksi) — weaker than 56% of steel grades. Elongation at break is 23% and the elastic modulus is 207 GPa (30 Msi).

Elastic (Young's) Modulus207 GPa30 Msi
Shear Modulus79.3 GPa11.5 Msi
Bulk Modulus160 GPa23.2 Msi
Poisson's Ratio0.29
Tensile Strength (Ultimate)670 MPa97.2 ksi
Yield Strength (0.2% offset)415 MPa60.2 ksi
Elongation at Break23%
Reduction in Area48%
Shear Strength960 MPa139 ksi
Fatigue Strength (Endurance Limit)330 MPa47.9 ksi
Fracture Toughness (K_IC)45 MPa·√m41 ksi·√in
Charpy V-Notch Impact (RT)40 J29.5 ft·lbf
Hardness, Brinell197 HB
Hardness, Rockwell C46 HRC
Hardness, Vickers465 HV

Thermal6

A231-ANN is rated for continuous service to 220°C (428 °F). It conducts heat at 44 W/m·K (25.4 BTU/hr·ft·°F), better than 57% of steel grades. Thermal expansion is 12.2 µm/m·K (6.78 µin/in·°F).

Thermal Conductivity44 W/m·K25.4 BTU/hr·ft·°F
Specific Heat Capacity475 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)12.2 µm/m·K6.8 µin/in·°F
Latent Heat of Fusion250 J/g107 BTU/lb
Max Service Temperature (continuous)220°C428 °F
Min Service Temperature-40°C-40 °F

Electrical3

A231-ANN conducts electricity at 7.5 % IACS, worse than 67% of steel grades.

Electrical Conductivity7.5 % IACS
Electrical Resistivity2.3×10⁻⁷ Ω·m9.06 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is not recommended (14/100), better than 70% of steel grades.

Galvanic Potential (seawater, vs SCE)-0.6 V
Corrosion ResistanceNot recommended14/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of A231-ANN takes about 34 MJ of energy and emits 2.3 kg of CO₂ — more than 82% of steel grades. Typical recycled content is 25%.

Embodied Energy (primary production)34 MJ/kg14,617 BTU/lb
Embodied Carbon (primary production)2.3 kg CO₂/kg
Embodied Water60 L/kg7.2 gal/lb
Typical Recycled Content25%

Manufacturability6

A231-ANN's machinability is good (55/100, better than 62% of steel grades); weldability fair (35/100); formability good (60/100).

MachinabilityGood55/100
Machinability Rating (AISI 1212 = 100 %)60%
WeldabilityFair35/100
Formability (cold)Good60/100
Brazeability / SolderabilityFair35/100
PolishabilityGood60/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with A231-ANN

Is A231 easy to machine?

Turns and mills normally in the annealed condition at roughly 55–60 % of AISI 1212. In the oil-quenched-and-tempered state at 46 HRC, plan on grinding or hard turning with CBN or ceramic inserts.

Can A231 be welded?

A medium-carbon alloy steel with poor weldability: 200–300 °C preheat, low-hydrogen consumables and post-weld tempering are required. Finished springs should not be welded as a matter of practice.

Can A231 be formed, bent or molded?

Oil-tempered wire can be cold coiled with a spring index C of 4 or greater, and must be stress relieved at 315–425 °C after forming. Large sections are hot coiled and then through-quenched and tempered.

What surface finishes work on A231?

Corrosion resistance is poor, so use black oxide, phosphate plus oil, Dacromet or epoxy powder. After zinc or chrome electroplating, bake at 190–220 °C for at least 4 h to remove hydrogen; shot peening markedly increases fatigue life.

A231 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
C0.48 – 0.530.5
Mn0.7 – 0.90.8
SiSAE 6150 permits up to 0.350.15 – 0.30.22
Cr0.8 – 1.10.95
V0.15% minimum≥ 0.150.18
P≤ 0.04—
S≤ 0.04—
Febalance—

A231-ANN — frequently asked

What is A231-ANN used for?

A231-ANN is typically used for coil springs, torsion bars and valve springs. In short: cr-V fatigue spring bar; 1550 MPa oil-tempered; not for welded assemblies.

What is the yield strength of A231-ANN?

A231-ANN has a typical yield strength of 415 MPa (60.2 ksi) and a tensile strength of 670 MPa (97.2 ksi) — weaker than 56% of steel grades. Strength varies by condition: see the 10 listed tempers.

Is A231-ANN easy to machine?

Reasonably — machinability is rated good (55/100, better than 62% of steel grades). Turns and mills normally in the annealed condition at roughly 55–60 % of AISI 1212. In the oil-quenched-and-tempered state at 46 HRC, plan on grinding or hard turning with CBN or ceramic inserts.

Can A231-ANN be welded?

With care — weldability is rated fair (35/100). A medium-carbon alloy steel with poor weldability: 200–300 °C preheat, low-hydrogen consumables and post-weld tempering are required. Finished springs should not be welded as a matter of practice.

What surface finishes work on A231-ANN?

Corrosion resistance is poor, so use black oxide, phosphate plus oil, Dacromet or epoxy powder. After zinc or chrome electroplating, bake at 190–220 °C for at least 4 h to remove hydrogen; shot peening markedly increases fatigue life.

Can A231-ANN be formed, bent or molded?

Oil-tempered wire can be cold coiled with a spring index C of 4 or greater, and must be stress relieved at 315–425 °C after forming. Large sections are hot coiled and then through-quenched and tempered.

What is the maximum service temperature of A231-ANN?

A231-ANN is rated for continuous use to about 220°C (428 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between A231-OT and A231-ANN?

OT is the default condition — pick the as-supplied oil-quenched and tempered chromium-vanadium spring wire for cold-coiled springs; strength is graded by wire diameter and formability is limited at a score of 30. ANN: choose fully annealed bar or rod at 197 HB when parts must be machined, cold headed or re-heat-treated afterwards; strength is only 670 MPa tensile with 23% elongation. Yield strength is 1,400 MPa in OT versus 415 MPa in ANN.

Sources

  1. ASTM A231/A231M — Chromium-Vanadium Alloy Steel Spring Wire — ASTM International (2022)
  2. SAE J404 / J1249 — Chemical Compositions of SAE Alloy Steels (6150) — SAE International (2020)
  3. GB/T 1222 (50CrVA) (2016)
  4. ASM Handbook Vol.1 — Properties and Selection: Irons, Steels, and High-Performance Alloys — ASM International (1990)
  5. Handbook of Spring Design — Spring Manufacturers Institute (SMI) (2013)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.