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Steel 4Cr5MoSiV-ESR

Grade

GB 4Cr5MoSiV · AISI/SAE H11

ESR = electroslag remelted, annealed

Pick for large die-casting blocks, mirror-polished cavities and where NADCA-type cleanliness/isotropy is specified.

Standard cost $$

Values for the ESR condition

Other 4Cr5MoSiV tempers and conditions

4Cr5MoSiV is listed in 8 conditions; see the grade overview at 4Cr5MoSiV.

Compare all 8 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ESRThis page
Electroslag remelted, annealed
Pick for large die-casting blocks, mirror-polished cavities and where NADCA-type cleanliness/isotropy is specified.4907602414 HRC3.3 % IACS
AnnealedDefault
spheroidize annealed bar/plate (≤229 HB)
Standard as-supplied condition for machining before hardening; virtually all mill stock ships this way.50078022210 HB—
Hot rolled
Cheapest mill form for large blocks that will be annealed and machined by the tool shop.7001,0001431 HRC3.3 % IACS
hardened and high-temper (max toughness)
Choose for large forging dies, die-casting holder blocks and shock-loaded tooling where cracking risk dominates over wear.1,1501,3501342 HRC—
standard die-casting / extrusion die hardness
The default working hardness for aluminium die-casting dies and hot extrusion tooling — best balance of heat-check resistance and strength.1,3001,5501146 HRC—
Nitrided surface (core Q&T 44–48 HRC)
Gas/plasma nitrided at 480–530 °C for extrusion dies and cores needing a wear- and soldering-resistant skin.1,3501,550846 HRC3.3 % IACS
hardened and low-temper (max wear resistance)
For punches, shear blades, mandrels and small inserts where wear and compressive strength matter more than impact toughness.1,5201,800950 HRC—
maximum attainable working hardness
Only for small, well-supported wear parts; toughness is low and cracking risk in service is high.1,6501,950754 HRC—

What is 4Cr5MoSiV-ESR?

4Cr5MoSiV-ESR is 4Cr5MoSiV in the ESR grade — pick for large die-casting blocks, mirror-polished cavities and where NADCA-type cleanliness/isotropy is specified. 4Cr5MoSiV-ESR has a yield strength of 490 MPa (71.1 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 61% of steel grades. Elongation at break is 24% and the elastic modulus is 210 GPa (30.5 Msi). 4Cr5MoSiV-ESR has a density of 7.8 g/cm³ (0.282 lb/in³), lighter than 87% of steel grades. It melts at 1,420°C (2,588 °F). Annealed is the default condition FabDigit quotes; ESR is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 90/100, better than 100% of steel grades
  • High service temperature — 540°C (1,004 °F), better than 93% of steel grades

Limitations

  • Poor heat conductor — 24.5 W/m·K (14.2 BTU/hr·ft·°F), worse than 89% of steel grades
  • Low electrical conductivity — 3.3 % IACS, worse than 86% of steel grades
  • High embodied carbon — 2.5 kg CO₂/kg, worse than 82% of steel grades

4Cr5MoSiV-ESR properties

Typical room-temperature values for 4Cr5MoSiV-ESR; 24 are specific to this condition. Other listed values are 4Cr5MoSiV reference data and may not represent this condition. Bars are the position among steel grades.

Physical3

4Cr5MoSiV-ESR has a density of 7.8 g/cm³ (0.282 lb/in³), lighter than 87% of steel grades. It melts at 1,420°C (2,588 °F).

Density7.8 g/cm³0.28 lb/in³
Melting Point (Solidus)1,420°C2,588 °F
Liquidus Temperature1,480°C2,696 °F

Mechanical15

4Cr5MoSiV-ESR has a yield strength of 490 MPa (71.1 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 61% of steel grades. Elongation at break is 24% and the elastic modulus is 210 GPa (30.5 Msi).

Elastic (Young's) Modulus210 GPa30.5 Msi
Shear Modulus81 GPa11.7 Msi
Bulk Modulus168 GPa24.4 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)760 MPa110 ksi
Yield Strength (0.2% offset)490 MPa71.1 ksi
Elongation at Break24%
Reduction in Area55%
Compressive Strength510 MPa74 ksi
Shear Strength460 MPa66.7 ksi
Fatigue Strength (Endurance Limit)355 MPa51.5 ksi
Charpy V-Notch Impact (RT)26 J19.2 ft·lbf
Hardness, Brinell205 HB
Hardness, Rockwell B94 HRB
Hardness, Vickers215 HV

Thermal6

4Cr5MoSiV-ESR is rated for continuous service to 540°C (1,004 °F). It conducts heat at 24.5 W/m·K (14.2 BTU/hr·ft·°F), worse than 89% of steel grades. Thermal expansion is 11.9 µm/m·K (6.61 µin/in·°F).

Thermal Conductivity24.5 W/m·K14.2 BTU/hr·ft·°F
Specific Heat Capacity460 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)11.9 µm/m·K6.6 µin/in·°F
Latent Heat of Fusion250 J/g107 BTU/lb
Max Service Temperature (continuous)540°C1,004 °F
Min Service Temperature-20°C-4 °F

Electrical3

4Cr5MoSiV-ESR conducts electricity at 3.3 % IACS, worse than 86% of steel grades.

Electrical Conductivity3.3 % IACS
Electrical Resistivity5.2×10⁻⁷ Ω·m20.5 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is poor (18/100), better than 83% of steel grades.

Galvanic Potential (seawater, vs SCE)-0.55 V
Corrosion ResistancePoor18/100
Chemical Resistance SummaryNot corrosion resistant: rusts in humid air and water, attacked by acids; some resistance to molten aluminium erosion/soldering, which is why it is used for die casting. Protect with oil, nitriding or PVD coating.

Sustainability4

Producing a kilogram of 4Cr5MoSiV-ESR takes about 34 MJ of energy and emits 2.5 kg of CO₂ — more than 82% of steel grades. Typical recycled content is 45%.

Embodied Energy (primary production)34 MJ/kg14,617 BTU/lb
Embodied Carbon (primary production)2.5 kg CO₂/kg
Embodied Water70 L/kg8.4 gal/lb
Typical Recycled Content45%

Manufacturability8

4Cr5MoSiV-ESR's machinability is good (58/100, better than 75% of steel grades); weldability fair (38/100); formability poor (27/100).

MachinabilityGood58/100
Machinability Rating (AISI 1212 = 100 %)63%
WeldabilityFair38/100
Formability (cold)Poor27/100
CastabilityPoor30/100
Brazeability / SolderabilityFair40/100
PolishabilityExcellent90/100
Anodizing Responsen/a — ferrous alloy; use nitriding, oxidation (blackening), PVD (CrN/AlTiN) or hard chrome instead

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with 4Cr5MoSiV-ESR

Is 4Cr5MoSiV easy to machine?

Machine in the annealed condition (≤229 HB) with rigid setups and coated carbide; above 45 HRC switch to hard milling/EDM plus a stress-relief temper before final heat treatment.

Can 4Cr5MoSiV be welded?

Weldable for repair only with matching H11/H13 filler: preheat and hold at 300–400 °C, weld continuously, slow cool, then temper 20–30 °C below the last tempering temperature.

Can 4Cr5MoSiV be formed, bent or molded?

Hot work at 1050–1120 °C finishing above 900 °C with slow furnace cooling; cold forming is not practical — austenitize 1000–1030 °C, air/vacuum quench, and double or triple temper at 540–620 °C.

What surface finishes work on 4Cr5MoSiV?

Takes a high polish (best with ESR stock); protect service surfaces by nitriding, oxidation/blackening or PVD CrN/AlTiN — no anodizing, and hard chrome may spall under thermal cycling.

4Cr5MoSiV chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
C0.33 – 0.430.38
Si0.8 – 1.21
Mn0.2 – 0.50.35
Cr4.75 – 5.55.1
Mo1.1 – 1.61.35
V0.3 – 0.60.45
P≤ 0.03—
Smax; premium/ESR often ≤0.005≤ 0.03—
Niresidual, max≤ 0.3—
Curesidual, max≤ 0.25—
Febalance—

4Cr5MoSiV-ESR — frequently asked

What is 4Cr5MoSiV-ESR used for?

4Cr5MoSiV-ESR is typically used for die-casting dies, forging dies and hot shear blades. In short: tougher than H13; lower-carbon hot-work grade; polishes well in ESR quality.

What is the yield strength of 4Cr5MoSiV-ESR?

4Cr5MoSiV-ESR has a typical yield strength of 490 MPa (71.1 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 61% of steel grades. Strength varies by condition: see the 8 listed tempers.

Is 4Cr5MoSiV-ESR easy to machine?

Reasonably — machinability is rated good (58/100, better than 75% of steel grades). Machine in the annealed condition (≤229 HB) with rigid setups and coated carbide; above 45 HRC switch to hard milling/EDM plus a stress-relief temper before final heat treatment.

Can 4Cr5MoSiV-ESR be welded?

With care — weldability is rated fair (38/100). Weldable for repair only with matching H11/H13 filler: preheat and hold at 300–400 °C, weld continuously, slow cool, then temper 20–30 °C below the last tempering temperature.

What surface finishes work on 4Cr5MoSiV-ESR?

Takes a high polish (best with ESR stock); protect service surfaces by nitriding, oxidation/blackening or PVD CrN/AlTiN — no anodizing, and hard chrome may spall under thermal cycling.

Can 4Cr5MoSiV-ESR be formed, bent or molded?

Hot work at 1050–1120 °C finishing above 900 °C with slow furnace cooling; cold forming is not practical — austenitize 1000–1030 °C, air/vacuum quench, and double or triple temper at 540–620 °C.

What is the maximum service temperature of 4Cr5MoSiV-ESR?

4Cr5MoSiV-ESR is rated for continuous use to about 540°C (1,004 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between 4Cr5MoSiV Annealed and 4Cr5MoSiV-HR?

Annealed is the default condition — standard as-supplied condition for machining before hardening; virtually all mill stock ships this way. HR: cheapest mill form for large blocks that will be annealed and machined by the tool shop. Yield strength is 500 MPa in Annealed versus 700 MPa in HR.

Sources

  1. GB/T 1299 (4Cr5MoSiV) — SAC / (2014)
  2. ASTM A681 Standard Specification for Tool Steels Alloy (H11) — ASTM International (2015)
  3. ASM Handbook Vol.1 — Properties and Selection: Irons, Steels, and High-Performance Alloys (Hot-Work Tool Steels) — ASM International (1990)
  4. Hot work tool steel W300 / H11 datasheet — voestalpine Böhler Edelstahl (2022)
  5. H11 / 1.2343 hot work die steel technical data — Daido Steel / (2021)
  6. H11/4Cr5MoSiV — Mysteel / 1688 (2026)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.