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PHBH HIGH-HHx

Grade

also Nodax

Pick for LDPE-like flexibility: films, bags, soft tubing and elastomeric seals.

Premium cost $$$

Values for the HIGH-HHx condition

Other PHBH grades and fills

PHBH is listed in 6 conditions; see the grade overview at PHBH.

Compare all 6 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Expanded PHBH beads / foam sheet grade
Compostable EPS/EPP replacement for protective packaging and insulated boxes.0.30.4512—
HIGH-HHxThis page
High 3HHx (flexible/soft) copolymer
Pick for LDPE-like flexibility: films, bags, soft tubing and elastomeric seals.—1535045 Shore D
Injection moulding grade
Nucleated/heat-stabilised compound to speed the notoriously slow PHA crystallisation and shorten cycle time.24264062 Shore D
Mineral/talc-filled PHBH compound
Choose for lower cost, higher stiffness and faster crystallisation in rigid thin-wall parts.—248—
Low 3HHx (rigid) copolymer
Pick when stiffness and heat resistance matter more than toughness (rigid cups, cutlery, moulded lids).—301568 Shore D
PHBH/PLA blend compound
Use when PLA-level stiffness and clarity are needed with PHBH toughness and compostability; cheaper than neat PHBH.38402574 Shore D

What is PHBH HIGH-HHx?

PHBH HIGH-HHx is PHBH in the HIGH-HHx grade — pick for LDPE-like flexibility: films, bags, soft tubing and elastomeric seals. PHBH HIGH-HHx has a yield strength of 18 MPa (2.61 ksi) and a tensile strength of 15 MPa (2.18 ksi) — weaker than 82% of polymer grades. Elongation at break is 350% and the elastic modulus is 0.3 GPa (0.0435 Msi). PHBH HIGH-HHx has a density of 1.2 g/cm³ (0.0434 lb/in³), heavier than 57% of polymer grades. Its glass-transition temperature is -3°C (27 °F).

Advantages

  • Low embodied carbon — 2 kg CO₂/kg, better than 96% of polymer grades
  • Ductile — tolerates forming and impact — 350%, better than 84% of polymer grades

Limitations

  • Needs corrosion protection — 60/100, worse than 89% of polymer grades
  • Low strength — 18 MPa (2.61 ksi), worse than 82% of polymer grades
  • Difficult to machine — 45/100, worse than 78% of polymer grades
  • Limited service temperature — 70°C (158 °F), worse than 77% of polymer grades

PHBH HIGH-HHx properties

Typical room-temperature values for PHBH HIGH-HHx; 11 are specific to this condition. Other listed values are PHBH reference data and may not represent this condition. Bars are the position among polymer grades.

Physical5

PHBH HIGH-HHx has a density of 1.2 g/cm³ (0.0434 lb/in³), heavier than 57% of polymer grades. Its glass-transition temperature is -3°C (27 °F).

Density1.2 g/cm³0.04 lb/in³
Melting Temperature (Tm)120°C248 °F
Glass Transition (Tg)-3°C27 °F
Water Absorption (24 h)0.4%
Water Absorption (Saturation)1%

Mechanical10

PHBH HIGH-HHx has a yield strength of 18 MPa (2.61 ksi) and a tensile strength of 15 MPa (2.18 ksi) — weaker than 82% of polymer grades. Elongation at break is 350% and the elastic modulus is 0.3 GPa (0.0435 Msi).

Elastic (Young's) Modulus0.3 GPa0.04 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)15 MPa2.2 ksi
Yield Strength (0.2% offset)18 MPa2.6 ksi
Elongation at Break350%
Flexural Strength25 MPa3.6 ksi
Flexural Modulus0.3 GPa0.04 Msi
Izod Impact, Notched200 J/m3.7 ft·lbf/in
Hardness, Shore D45 Shore D
Hardness, Rockwell R90 HRR

Thermal11

PHBH HIGH-HHx is rated for continuous service to 70°C (158 °F). It conducts heat at 0.2 W/m·K (0.116 BTU/hr·ft·°F), worse than 56% of polymer grades. Thermal expansion is 120 µm/m·K (66.7 µin/in·°F).

Thermal Conductivity0.2 W/m·K0.12 BTU/hr·ft·°F
Specific Heat Capacity1,600 J/kg·K0.38 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)120 µm/m·K66.7 µin/in·°F
Max Service Temperature (continuous)70°C158 °F
Min Service Temperature-20°C-4 °F
Heat Deflection Temp. @ 0.45 MPa80°C176 °F
Heat Deflection Temp. @ 1.8 MPa55°C131 °F
Vicat Softening Point (B50)95°C203 °F
Flammability (UL 94)HB (no halogen FR; burns with dripping)
Limiting Oxygen Index21%
Max Service Temperature (short-term)110°C230 °F

Electrical5

PHBH HIGH-HHx is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)3
Dissipation Factor (1 MHz)0.02
Volume Resistivity1×10¹⁵ Ω·cm

Chemical & Environmental3

Corrosion resistance is good (60/100), worse than 89% of polymer grades. UV resistance is fair.

Corrosion ResistanceGood60/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryGood against water, oils, fats, alcohols and dilute acids at ambient; attacked by dilute alkali, hot water/steam (hydrolysis) and chlorinated solvents/chloroform (soluble); biodegrades in soil, compost and seawater by design.

Sustainability4

Producing a kilogram of PHBH HIGH-HHx takes about 55 MJ of energy and emits 2 kg of CO₂ — less than 98% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)55 MJ/kg23,646 BTU/lb
Embodied Carbon (primary production)2 kg CO₂/kg
Embodied Water350 L/kg41.9 gal/lb
Typical Recycled Content0%

Manufacturability8

PHBH HIGH-HHx's machinability is fair (45/100, worse than 78% of polymer grades); weldability very good (70/100); formability good (60/100).

MachinabilityFair45/100
WeldabilityVery good70/100
Formability (cold)Good60/100
PolishabilityFair40/100
Mold Shrinkage1.5%
Melt Flow Rate8 g/10 min
Processing Melt Temperature (typ.)160°C320 °F
Mold Temperature (typ.)50°C122 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PHBH HIGH-HHx

Is PHBH easy to machine?

Machinable but soft and heat-sensitive — sharp tools, high rake, air blast only, avoid frictional heat that melts/smears the cut.

Can PHBH be welded?

Heat sealing, hot-plate and ultrasonic welding all work within a narrow 150–170 °C window; solvent bonding possible with chlorinated solvents.

Can PHBH be formed, bent or molded?

Dry to <0.05 % moisture, keep melt below ~175 °C and residence time short (hydrolytic/thermal chain scission); expect slow crystallisation, so use nucleated grades, 40–60 °C tools and longer hold times.

What surface finishes work on PHBH?

Takes in-mould texture and water-based/UV inks after corona treatment; avoid hot alkaline cleaning and steam, and do not autoclave.

PHBH chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
3-hydroxybutyrate (3HB) unitmol% of copolymer backbone85 – 9591
3-hydroxyhexanoate (3HHx) unitmol%; higher 3HHx = softer, lower Tm5 – 159
nucleating agent / lubricant / stabilisecompound-dependent additives0 – 31

PHBH HIGH-HHx — frequently asked

What is PHBH HIGH-HHx used for?

PHBH HIGH-HHx is typically used for flexible biodegradable packaging film, drinking straws, marine-degradable products and compostable cutlery. In short: most flexible PHA grade; marine-biodegradable polyolefin substitute; slow-crystallising film resin.

What is the yield strength of PHBH HIGH-HHx?

PHBH HIGH-HHx has a typical yield strength of 18 MPa (2.61 ksi) and a tensile strength of 15 MPa (2.18 ksi) — weaker than 82% of polymer grades. Strength varies by condition: see the 6 listed tempers.

Is PHBH HIGH-HHx easy to machine?

Reasonably — machinability is rated fair (45/100, worse than 78% of polymer grades). Machinable but soft and heat-sensitive — sharp tools, high rake, air blast only, avoid frictional heat that melts/smears the cut.

Can PHBH HIGH-HHx be welded?

Yes — weldability is rated very good (70/100). Heat sealing, hot-plate and ultrasonic welding all work within a narrow 150–170 °C window; solvent bonding possible with chlorinated solvents.

What surface finishes work on PHBH HIGH-HHx?

Takes in-mould texture and water-based/UV inks after corona treatment; avoid hot alkaline cleaning and steam, and do not autoclave.

Can PHBH HIGH-HHx be formed, bent or molded?

Dry to <0.05 % moisture, keep melt below ~175 °C and residence time short (hydrolytic/thermal chain scission); expect slow crystallisation, so use nucleated grades, 40–60 °C tools and longer hold times.

What is the maximum service temperature of PHBH HIGH-HHx?

PHBH HIGH-HHx is rated for continuous use to about 70°C (158 °F), and briefly to 110°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Green Planet PHBH resin grades and processing guide — Kaneka Corporation (2023)
  2. Nodax PHA (P3HB-co-3HHx) technical literature — Danimer Scientific / Procter & Gamble (originator) (2022)
  3. EN 13432 / ASTM D6400 — compostable plastics; ASTM D7081 marine biodegradation — CEN / ASTM (2020)
  4. Handbook of Biodegradable Polymers — polyhydroxyalkanoate property chapters — Wiley / De Gruyter (2020)
  5. CAMPUS / UL Prospector biopolymer property listings — CWFG / UL (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.