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PHB NUCL

Additive grade

also Biopol

NUCL = nucleated / talc-filled PHB

Specify the 1–15% talc or boron-nitride nucleated grade for thin-wall molded tableware: shorter cycles, no secondary-crystallization embrittlement, highest stiffness at 4.2 GPa but only 3% elongation.

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Values for the NUCL condition

Other PHB grades and fills

PHB is listed in 6 conditions; see the grade overview at PHB.

Compare all 6 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Poly
Use the adjustable-4HB copolymer where flexibility dominates — up to 200% elongation at 0.5 GPa — for films, straws and resorbable medical parts, accepting rigid-to-elastomeric low stiffness.142020050 Shore D
Plasticized / impact-modified PHB compound
Pick the citrate/ATBC-plasticized or rubber/PBAT-toughened compound for production films and molded parts: 40% elongation and usable impact traded against 1.2 GPa stiffness and 70 °C service.18204062 Shore D
Poly
Choose the HHx copolymer for straws, films and cutlery coatings needing 80% elongation and the best seawater degradation; stiffness drops to 0.8 GPa and service temperature to 75 °C.—228060 Shore D
Natural-fiber / wood-flour filled PHB
Choose the 20–30% wood-flour, bamboo or wheat-straw filled fully bio-based compound for disposable containers and garden parts, accepting 2% elongation, higher brittleness and water uptake.2828278 Shore D
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate), 3–12 mol% HV
Pick the 3–12 mol% HV copolymer for cutlery, packaging and molded parts: HV units lower melting point and crystallinity, widening the processing window and raising elongation to 12% at 30 MPa.—3012—
NUCLThis page
Nucleated / talc-filled PHB
Specify the 1–15% talc or boron-nitride nucleated grade for thin-wall molded tableware: shorter cycles, no secondary-crystallization embrittlement, highest stiffness at 4.2 GPa but only 3% elongation.3232380 Shore D

What is PHB NUCL?

PHB NUCL is PHB in the NUCL grade — specify the 1–15% talc or boron-nitride nucleated grade for thin-wall molded tableware: shorter cycles, no secondary-crystallization embrittlement, highest stiffness at 4.2 GPa but only 3% elongation. PHB NUCL has a yield strength of 32 MPa (4.64 ksi) and a tensile strength of 32 MPa (4.64 ksi) — weaker than 69% of polymer grades. Elongation at break is 3% and the elastic modulus is 4.2 GPa (0.609 Msi). PHB NUCL has a density of 1.32 g/cm³ (0.0477 lb/in³), heavier than 72% of polymer grades. Its glass-transition temperature is 4°C (39 °F).

Advantages

  • Low embodied carbon — 2.2 kg CO₂/kg, better than 93% of polymer grades
  • Stiff — 4.2 GPa (0.609 Msi), better than 87% of polymer grades
  • Conducts heat well — 0.28 W/m·K (0.162 BTU/hr·ft·°F), better than 79% of polymer grades

Limitations

  • Limited ductility — 3%, worse than 83% of polymer grades
  • Limited formability — 15/100, worse than 79% of polymer grades

PHB NUCL properties

Typical room-temperature values for PHB NUCL; 28 are specific to this condition. Other listed values are PHB reference data and may not represent this condition. Bars are the position among polymer grades.

Physical6

PHB NUCL has a density of 1.32 g/cm³ (0.0477 lb/in³), heavier than 72% of polymer grades. Its glass-transition temperature is 4°C (39 °F).

Density1.32 g/cm³0.05 lb/in³
Melting Temperature (Tm)175°C347 °F
Glass Transition (Tg)4°C39 °F
Water Absorption (24 h)0.4%
Water Absorption (Saturation)1%
Refractive Index1.46

Mechanical11

PHB NUCL has a yield strength of 32 MPa (4.64 ksi) and a tensile strength of 32 MPa (4.64 ksi) — weaker than 69% of polymer grades. Elongation at break is 3% and the elastic modulus is 4.2 GPa (0.609 Msi).

Elastic (Young's) Modulus4.2 GPa0.61 Msi
Poisson's Ratio0.38
Tensile Strength (Ultimate)32 MPa4.6 ksi
Yield Strength (0.2% offset)32 MPa4.6 ksi
Elongation at Break3%
Compressive Strength65 MPa9.4 ksi
Flexural Strength56 MPa8.1 ksi
Flexural Modulus4 GPa0.58 Msi
Izod Impact, Notched25 J/m0.47 ft·lbf/in
Hardness, Shore D80 Shore D
Hardness, Rockwell R108 HRR

Thermal11

PHB NUCL is rated for continuous service to 105°C (221 °F). It conducts heat at 0.28 W/m·K (0.162 BTU/hr·ft·°F), better than 79% of polymer grades. Thermal expansion is 70 µm/m·K (38.9 µin/in·°F).

Thermal Conductivity0.28 W/m·K0.16 BTU/hr·ft·°F
Specific Heat Capacity1,500 J/kg·K0.36 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)70 µm/m·K38.9 µin/in·°F
Max Service Temperature (continuous)105°C221 °F
Min Service Temperature-30°C-22 °F
Heat Deflection Temp. @ 0.45 MPa150°C302 °F
Heat Deflection Temp. @ 1.8 MPa112°C234 °F
Vicat Softening Point (B50)158°C316 °F
Flammability (UL 94)—
Limiting Oxygen Index23%
Max Service Temperature (short-term)140°C284 °F

Electrical4

PHB NUCL is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)3
Volume Resistivity1×10¹⁵ Ω·cm

Chemical & Environmental2

UV resistance is fair.

UV / Weathering ResistanceFair35/100
Chemical Resistance Summary—

Sustainability3

Producing a kilogram of PHB NUCL takes about 60 MJ of energy and emits 2.2 kg of CO₂ — less than 96% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)60 MJ/kg25,795 BTU/lb
Embodied Carbon (primary production)2.2 kg CO₂/kg
Typical Recycled Content0%

Manufacturability8

PHB NUCL's machinability is good (55/100, worse than 64% of polymer grades); weldability fair (45/100); formability poor (15/100).

MachinabilityGood55/100
WeldabilityFair45/100
Formability (cold)Poor15/100
PolishabilityFair50/100
Mold Shrinkage1.1%
Melt Flow Rate20 g/10 min
Processing Melt Temperature (typ.)175°C347 °F
Mold Temperature (typ.)55°C131 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PHB NUCL

Is PHB easy to machine?

Turns, mills and drills, but the material is brittle and a poor conductor of heat. Use sharp tools, high speed, light feed and ample cooling to avoid stress cracking and edge chipping.

Can PHB be welded?

Hot-plate, ultrasonic and hot-air welding all work, but temperature must be held close to 175 °C. Overheating causes immediate thermal degradation with yellowing and odour.

Can PHB be formed, bent or molded?

Dry before injection moulding or extrusion (80 °C for 2-4 h, moisture below 0.05 %) and hold melt strictly at 165-180 °C with the shortest possible residence time. High crystallinity causes marked post-moulding shrinkage, so use a nucleating agent and 50-60 °C tools; thermoforming and blown film normally need copolymer or plasticised grades.

What surface finishes work on PHB?

Printable and labellable, and takes water-based or UV coatings, preferably after corona treatment. Not suitable for high-temperature bake finishes or solvent cleaning, since chlorinated solvents dissolve it.

PHB chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
residual biomass / ashfermentation extraction residue; lower for medical grade0 – 1.50.5
3-hydroxybutyrate (3HB)homopolymer; partly replaced by 3HV/3HHx/4HB in copolymers≥ 97 (balance)—

PHB NUCL — frequently asked

What is PHB NUCL used for?

PHB NUCL is typically used for rigid biodegradable packaging, PHA blend base resin, agricultural film additive and medical microcapsules. In short: stiffest PHA grade; highest-temperature PHA; brittle base blending resin.

What is the yield strength of PHB NUCL?

PHB NUCL has a typical yield strength of 32 MPa (4.64 ksi) and a tensile strength of 32 MPa (4.64 ksi) — weaker than 69% of polymer grades. Strength varies by condition: see the 6 listed tempers.

Is PHB NUCL easy to machine?

Reasonably — machinability is rated good (55/100, worse than 64% of polymer grades). Turns, mills and drills, but the material is brittle and a poor conductor of heat. Use sharp tools, high speed, light feed and ample cooling to avoid stress cracking and edge chipping.

Can PHB NUCL be welded?

With care — weldability is rated fair (45/100). Hot-plate, ultrasonic and hot-air welding all work, but temperature must be held close to 175 °C. Overheating causes immediate thermal degradation with yellowing and odour.

What surface finishes work on PHB NUCL?

Printable and labellable, and takes water-based or UV coatings, preferably after corona treatment. Not suitable for high-temperature bake finishes or solvent cleaning, since chlorinated solvents dissolve it.

Can PHB NUCL be formed, bent or molded?

Dry before injection moulding or extrusion (80 °C for 2-4 h, moisture below 0.05 %) and hold melt strictly at 165-180 °C with the shortest possible residence time. High crystallinity causes marked post-moulding shrinkage, so use a nucleating agent and 50-60 °C tools; thermoforming and blown film normally need copolymer or plasticised grades.

What is the maximum service temperature of PHB NUCL?

PHB NUCL is rated for continuous use to about 105°C (221 °F), and briefly to 140°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Handbook of Biodegradable Polymers — polyhydroxyalkanoates chapter — De Gruyter / Rapra (2020)
  2. ENMAT Y1000 series PHBV resin data — TianAn Biopolymer (2023)
  3. Green Planet PHBH resin technical data — Kaneka (2023)
  4. CAMPUS / UL Prospector — CAMPUS (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.