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PMMA-GP FR (Flame-retardant grade)

Flame-retardant grade

ASTM D788 · JIS K6717 · GB GB/T 8834 · ISO 8257-1 PMMA

Only where a flame rating is mandatory — expect reduced clarity, lower impact and higher cost versus HB base resin.

Standard cost $$

Values for the FR condition

Other PMMA-GP grades and fills

PMMA-GP is listed in 6 conditions; see the grade overview at PMMA-GP.

Compare all 6 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Impact-modified (rubber-toughened) PMMA
Use when brittle fracture or snap-fit/assembly stress is the failure mode and 2–4× notched impact is worth some clarity and stiffness loss.—522570 HRM
FRThis page
Flame-retardant grade
Only where a flame rating is mandatory — expect reduced clarity, lower impact and higher cost versus HB base resin.6062388 Shore D
Light-diffusing grade
Pick for LED luminaire covers needing uniform luminance and LED hot-spot hiding rather than clarity.6466489 Shore D
High-flow / thin-wall optical molding grade
Pick for light guides, thin lenses and long flow paths where fill pressure and birefringence must stay low.66683.589 Shore D
Heat-resistant (high-Tg copolymer) PMMA
Choose for lamp lenses, automotive interiors and parts seeing 90–110 °C where standard GP would distort.73753.590 Shore D
Cell-cast sheet
Use cast sheet for machined/laser-engraved parts, aquaria and premium glazing where the highest MW, stiffness and solvent-crack resistance matter.7476592 Shore D

What is PMMA-GP FR?

PMMA-GP FR is PMMA-GP in the FR grade — only where a flame rating is mandatory — expect reduced clarity, lower impact and higher cost versus HB base resin. PMMA-GP FR has a yield strength of 60 MPa (8.7 ksi) and a tensile strength of 62 MPa (8.99 ksi) — stronger than 69% of polymer grades. Elongation at break is 3% and the elastic modulus is 3 GPa (0.435 Msi). PMMA-GP FR has a density of 1.24 g/cm³ (0.0448 lb/in³), heavier than 63% of polymer grades. Its glass-transition temperature is 105°C (221 °F).

Advantages

  • Polishes to a fine finish — 98/100, better than 100% of polymer grades
  • Good UV / weathering resistance — 95/100, better than 95% of polymer grades

Limitations

  • Needs corrosion protection — 58/100, worse than 92% of polymer grades
  • Limited ductility — 3%, worse than 83% of polymer grades
  • Low fracture toughness — 1.1 MPa·√m (1 ksi·√in), worse than 82% of polymer grades
  • Limited service temperature — 70°C (158 °F), worse than 77% of polymer grades

PMMA-GP FR properties

Typical room-temperature values for PMMA-GP FR; 29 are specific to this condition. Other listed values are PMMA-GP reference data and may not represent this condition. Bars are the position among polymer grades.

Physical6

PMMA-GP FR has a density of 1.24 g/cm³ (0.0448 lb/in³), heavier than 63% of polymer grades. Its glass-transition temperature is 105°C (221 °F).

Density1.24 g/cm³0.04 lb/in³
Glass Transition (Tg)105°C221 °F
Water Absorption (24 h)0.3%
Water Absorption (Saturation)2%
Refractive Index1.491
Light Transmission80%

Mechanical17

PMMA-GP FR has a yield strength of 60 MPa (8.7 ksi) and a tensile strength of 62 MPa (8.99 ksi) — stronger than 69% of polymer grades. Elongation at break is 3% and the elastic modulus is 3 GPa (0.435 Msi).

Elastic (Young's) Modulus3 GPa0.44 Msi
Shear Modulus1.2 GPa0.17 Msi
Bulk Modulus5 GPa0.73 Msi
Poisson's Ratio0.38
Tensile Strength (Ultimate)62 MPa9 ksi
Yield Strength (0.2% offset)60 MPa8.7 ksi
Elongation at Break3%
Compressive Strength100 MPa14.5 ksi
Compressive Modulus3.1 GPa0.45 Msi
Flexural Strength90 MPa13.1 ksi
Flexural Modulus3 GPa0.44 Msi
Shear Strength50 MPa7.3 ksi
Fracture Toughness (K_IC)1.1 MPa·√m1 ksi·√in
Izod Impact, Notched14 J/m0.26 ft·lbf/in
Hardness, Shore D88 Shore D
Hardness, Rockwell M90 HRM
Hardness, Rockwell R122 HRR

Thermal11

PMMA-GP FR is rated for continuous service to 70°C (158 °F). It conducts heat at 0.2 W/m·K (0.116 BTU/hr·ft·°F), worse than 56% of polymer grades. Thermal expansion is 70 µm/m·K (38.9 µin/in·°F).

Thermal Conductivity0.2 W/m·K0.12 BTU/hr·ft·°F
Specific Heat Capacity1,470 J/kg·K0.35 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)70 µm/m·K38.9 µin/in·°F
Max Service Temperature (continuous)70°C158 °F
Min Service Temperature-40°C-40 °F
Heat Deflection Temp. @ 0.45 MPa92°C198 °F
Heat Deflection Temp. @ 1.8 MPa85°C185 °F
Vicat Softening Point (B50)100°C212 °F
Flammability (UL 94)V-0 or V-2 at 1.5–3.0 mm depending on additive package
Limiting Oxygen Index27%
Max Service Temperature (short-term)90°C194 °F

Electrical7

PMMA-GP FR is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 5×10¹² Ω·m.

Electrical Resistivity5×10¹² Ω·m1.97×10²⁰ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)2.7
Dissipation Factor (1 MHz)0.02
Volume Resistivity1×10¹⁵ Ω·cm
Surface Resistivity1×10¹⁶ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is good (58/100), worse than 92% of polymer grades. UV resistance is excellent.

Corrosion ResistanceGood58/100
UV / Weathering ResistanceExcellent95/100
Chemical Resistance SummaryGood against water, dilute acids/alkalis, aliphatic hydrocarbons, mineral oils and greases; attacked or stress-cracked by ketones (acetone/MEK), esters, chlorinated solvents, aromatic hydrocarbons, ethanol/IPA and concentrated acids.

Sustainability4

Producing a kilogram of PMMA-GP FR takes about 100 MJ of energy and emits 6 kg of CO₂ — less than 61% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)100 MJ/kg42,992 BTU/lb
Embodied Carbon (primary production)6 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content0%

Manufacturability8

PMMA-GP FR's machinability is good (68/100, better than 71% of polymer grades); weldability fair (40/100); formability poor (25/100).

MachinabilityGood68/100
WeldabilityFair40/100
Formability (cold)Poor25/100
PolishabilityExcellent98/100
Mold Shrinkage0.5%
Melt Flow Rate2.5 g/10 min
Processing Melt Temperature (typ.)240°C464 °F
Mold Temperature (typ.)70°C158 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PMMA-GP FR

Is PMMA-GP easy to machine?

Machines cleanly with sharp, polished, high-rake carbide tools at high speed and light feed; use coolant/air blast to avoid gumming, anneal (80 °C) before and after heavy cuts to prevent crazing and cracking at drilled holes.

Can PMMA-GP be welded?

Not hot-gas/ultrasonic-friendly for optics — join by solvent cementing (dichloromethane, MMA-based cements) or UV-cure acrylic adhesive; hot-plate and vibration welding are possible for opaque parts.

Can PMMA-GP be formed, bent or molded?

Dry 4–6 h at 80–90 °C to <0.05 % moisture; inject at 220–260 °C melt with 50–90 °C mold, slow fill and high hold pressure for low internal stress; sheet thermoforms at 150–180 °C.

What surface finishes work on PMMA-GP?

Excellent flame, diamond and buff polishing to optical clarity; accepts hard-coat, anti-reflective and metallizing (vacuum Al) — avoid alcohol/ammonia cleaners and ester-based paints that cause stress crazing.

PMMA-GP chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
methyl acrylate / ethyl acrylate comonomthermal-stability comonomer in most molding grades0 – 83
processing lubricant / mold releasestearate or fatty alcohol0 – 0.50.2
chain transfer agent residue / antioxida0 – 0.30.1
methyl methacrylate (MMA)polymer backbone≥ 90 (balance)—

PMMA-GP FR — frequently asked

What is PMMA-GP FR used for?

PMMA-GP FR is typically used for injection molded lenses, signage letters, consumer housings and automotive light covers. In short: baseline optical moulding grade; polishes to optical clarity; brittle versus polycarbonate.

What is the yield strength of PMMA-GP FR?

PMMA-GP FR has a typical yield strength of 60 MPa (8.7 ksi) and a tensile strength of 62 MPa (8.99 ksi) — stronger than 69% of polymer grades. Strength varies by condition: see the 6 listed tempers.

Is PMMA-GP FR easy to machine?

Reasonably — machinability is rated good (68/100, better than 71% of polymer grades). Machines cleanly with sharp, polished, high-rake carbide tools at high speed and light feed; use coolant/air blast to avoid gumming, anneal (80 °C) before and after heavy cuts to prevent crazing and cracking at drilled holes.

Can PMMA-GP FR be welded?

With care — weldability is rated fair (40/100). Not hot-gas/ultrasonic-friendly for optics — join by solvent cementing (dichloromethane, MMA-based cements) or UV-cure acrylic adhesive; hot-plate and vibration welding are possible for opaque parts.

What surface finishes work on PMMA-GP FR?

Excellent flame, diamond and buff polishing to optical clarity; accepts hard-coat, anti-reflective and metallizing (vacuum Al) — avoid alcohol/ammonia cleaners and ester-based paints that cause stress crazing.

Can PMMA-GP FR be formed, bent or molded?

Dry 4–6 h at 80–90 °C to <0.05 % moisture; inject at 220–260 °C melt with 50–90 °C mold, slow fill and high hold pressure for low internal stress; sheet thermoforms at 150–180 °C.

What is the maximum service temperature of PMMA-GP FR?

PMMA-GP FR is rated for continuous use to about 70°C (158 °F), and briefly to 90°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ISO 8257-1/-2 Plastics — Poly(methyl methacrylate) moulding and extrusion materials — ISO (2021)
  2. ASTM D788 Standard Classification System for Poly(Methyl Methacrylate) Molding and Extrusion Compounds — ASTM (2018)
  3. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)
  4. PLEXIGLAS / ACRYLITE moulding compound data sheets — Röhm GmbH (2023)
  5. ACRYPET PMMA resin grade data — Mitsubishi Chemical (2023)
  6. CAMPUS plastics database — PMMA moulding grades (ISO 10350 datasets) — CWFG / CAMPUS consortium (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.