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EMAA ION-Zn

Grade

ISO E/MAA · also Nucrel

ION-Zn = zinc-neutralized ionomer

Pick when higher clarity, abrasion/puncture resistance and oil-resistant sealing are needed (golf-ball covers, tough packaging skins).

Premium cost $$$

Values for the ION-Zn condition

Other EMAA grades and fills

EMAA is listed in 5 conditions; see the grade overview at EMAA.

Compare all 5 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
High melt-flow extrusion-coating / adhesive grade
Use for high-speed extrusion coating of foil and paper, or as hot-melt / powder-coating adhesive base.71630052 Shore D
High acid content (~11–15% MAA)
Choose for maximum adhesion to aluminium foil, nylon and EVOH, better clarity and low-temperature sealing.93335048 Shore D
Low acid content
Pick when higher melting point, stiffness and PE-like processing matter more than adhesion strength.122550058 Shore D
ION-ZnThis page
Zinc-neutralized ionomer
Pick when higher clarity, abrasion/puncture resistance and oil-resistant sealing are needed (golf-ball covers, tough packaging skins).143438062 Shore D
Sodium-neutralized ionomer
Use where highest optical clarity and hot-tack through contamination are wanted; more moisture-sensitive than the Zn type.153635064 Shore D

What is EMAA ION-Zn?

EMAA ION-Zn is EMAA in the ION-Zn grade — pick when higher clarity, abrasion/puncture resistance and oil-resistant sealing are needed (golf-ball covers, tough packaging skins). EMAA ION-Zn has a yield strength of 14 MPa (2.03 ksi) and a tensile strength of 34 MPa (4.93 ksi) — weaker than 84% of polymer grades. Elongation at break is 380% and the elastic modulus is 0.3 GPa (0.0435 Msi). EMAA ION-Zn has a density of 0.96 g/cm³ (0.0345 lb/in³), lighter than 74% of polymer grades. Its glass-transition temperature is -20°C (-4 °F).

Advantages

  • Readily welded — 92/100, better than 97% of polymer grades
  • Low embodied carbon — 2.6 kg CO₂/kg, better than 89% of polymer grades
  • Ductile — tolerates forming and impact — 380%, better than 85% of polymer grades
  • Forms and bends easily — 85/100, better than 81% of polymer grades

Limitations

  • Limited service temperature — 60°C (140 °F), worse than 87% of polymer grades
  • Difficult to machine — 30/100, worse than 87% of polymer grades
  • Low strength — 14 MPa (2.03 ksi), worse than 84% of polymer grades
  • High mold shrinkage — 2%, worse than 81% of polymer grades
  • Needs corrosion protection — 70/100, worse than 78% of polymer grades

EMAA ION-Zn properties

Typical room-temperature values for EMAA ION-Zn; 11 are specific to this condition. Other listed values are EMAA reference data and may not represent this condition. Bars are the position among polymer grades.

Physical7

EMAA ION-Zn has a density of 0.96 g/cm³ (0.0345 lb/in³), lighter than 74% of polymer grades. Its glass-transition temperature is -20°C (-4 °F).

Density0.96 g/cm³0.03 lb/in³
Melting Temperature (Tm)90°C194 °F
Glass Transition (Tg)-20°C-4 °F
Water Absorption (24 h)0.15%
Water Absorption (Saturation)0.6%
Refractive Index1.51
Light Transmission91%

Mechanical8

EMAA ION-Zn has a yield strength of 14 MPa (2.03 ksi) and a tensile strength of 34 MPa (4.93 ksi) — weaker than 84% of polymer grades. Elongation at break is 380% and the elastic modulus is 0.3 GPa (0.0435 Msi).

Elastic (Young's) Modulus0.3 GPa0.04 Msi
Poisson's Ratio0.45
Tensile Strength (Ultimate)34 MPa4.9 ksi
Yield Strength (0.2% offset)14 MPa2 ksi
Elongation at Break380%
Flexural Modulus0.3 GPa0.04 Msi
Hardness, Shore A94 Shore A
Hardness, Shore D62 Shore D

Thermal10

EMAA ION-Zn is rated for continuous service to 60°C (140 °F). It conducts heat at 0.25 W/m·K (0.144 BTU/hr·ft·°F), better than 72% of polymer grades. Thermal expansion is 180 µm/m·K (100 µin/in·°F).

Thermal Conductivity0.25 W/m·K0.14 BTU/hr·ft·°F
Specific Heat Capacity2,100 J/kg·K0.5 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)180 µm/m·K100 µin/in·°F
Max Service Temperature (continuous)60°C140 °F
Min Service Temperature-60°C-76 °F
Heat Deflection Temp. @ 0.45 MPa48°C118 °F
Vicat Softening Point (B50)62°C144 °F
Flammability (UL 94)HB (not FR; burns like polyethylene, drips)
Limiting Oxygen Index18%
Max Service Temperature (short-term)80°C176 °F

Electrical5

EMAA ION-Zn is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)2.8
Dissipation Factor (1 MHz)0.015
Volume Resistivity1×10¹⁵ Ω·cm

Chemical & Environmental3

Corrosion resistance is very good (70/100), worse than 78% of polymer grades. UV resistance is poor.

Corrosion ResistanceVery good70/100
UV / Weathering ResistancePoor30/100
Chemical Resistance SummaryGood to water, brines, dilute acids, alcohols and most oils at RT; carboxyl groups are attacked (neutralized/saponified) by alkalis, amines and ammonia; swells in aromatic and chlorinated hydrocarbons and softens above ~60 °C.

Sustainability4

Producing a kilogram of EMAA ION-Zn takes about 82 MJ of energy and emits 2.6 kg of CO₂ — less than 83% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)82 MJ/kg35,254 BTU/lb
Embodied Carbon (primary production)2.6 kg CO₂/kg
Embodied Water110 L/kg13.2 gal/lb
Typical Recycled Content0%

Manufacturability7

EMAA ION-Zn's machinability is poor (30/100, worse than 87% of polymer grades); weldability excellent (92/100); formability excellent (85/100).

MachinabilityPoor30/100
WeldabilityExcellent92/100
Formability (cold)Excellent85/100
Mold Shrinkage2%
Melt Flow Rate2.5 g/10 min
Processing Melt Temperature (typ.)210°C410 °F
Mold Temperature (typ.)30°C86 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with EMAA ION-Zn

Is EMAA easy to machine?

Rarely machined; if needed use sharp positive-rake tools, high speed, low feed and cooling air — the resin is soft and smears.

Can EMAA be welded?

Excellent heat sealing, impulse sealing, hot-plate and ultrasonic welding; seals to itself at 90–120 °C and bonds to foil/nylon without adhesive.

Can EMAA be formed, bent or molded?

Extrudes and blow/cast-films easily at 180–230 °C (extrusion coating up to ~320 °C); keep melt below ~320 °C to avoid acid-induced degradation, use corrosion-resistant (stainless/Hastelloy) screws and dies, dry pellets 3 h at 50–60 °C for high-acid or ionomer grades.

What surface finishes work on EMAA?

Corona or flame treat only if printing/laminating a non-acid side; no plating or painting needed — the carboxyl groups themselves act as the primer to metals; avoid alkaline cleaners which saponify the surface.

EMAA chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
methacrylic acidcarboxyl comonomer providing adhesion; ~30–60 mol% may be neutralized with Zn²⁺/Na⁺ in ionomer variants4 – 159
antioxidant / process stabilizerphenolic/phosphite package0 – 0.50.2
ethylenebackbone comonomer≥ 85 (balance)—

EMAA ION-Zn — frequently asked

What is EMAA ION-Zn used for?

EMAA ION-Zn is typically used for extrusion coating, adhesive tie layers, flexible packaging, ionomer feedstock and golf ball cover blends. In short: bonds directly to foil; base resin for ionomers; very low seal initiation.

What is the yield strength of EMAA ION-Zn?

EMAA ION-Zn has a typical yield strength of 14 MPa (2.03 ksi) and a tensile strength of 34 MPa (4.93 ksi) — weaker than 84% of polymer grades. Strength varies by condition: see the 5 listed tempers.

Is EMAA ION-Zn easy to machine?

Not especially — machinability is rated poor (30/100, worse than 87% of polymer grades). Rarely machined; if needed use sharp positive-rake tools, high speed, low feed and cooling air — the resin is soft and smears.

Can EMAA ION-Zn be welded?

Yes — weldability is rated excellent (92/100). Excellent heat sealing, impulse sealing, hot-plate and ultrasonic welding; seals to itself at 90–120 °C and bonds to foil/nylon without adhesive.

What surface finishes work on EMAA ION-Zn?

Corona or flame treat only if printing/laminating a non-acid side; no plating or painting needed — the carboxyl groups themselves act as the primer to metals; avoid alkaline cleaners which saponify the surface.

Can EMAA ION-Zn be formed, bent or molded?

Extrudes and blow/cast-films easily at 180–230 °C (extrusion coating up to ~320 °C); keep melt below ~320 °C to avoid acid-induced degradation, use corrosion-resistant (stainless/Hastelloy) screws and dies, dry pellets 3 h at 50–60 °C for high-acid or ionomer grades.

What is the maximum service temperature of EMAA ION-Zn?

EMAA ION-Zn is rated for continuous use to about 60°C (140 °F), and briefly to 80°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Nucrel™ ethylene acid copolymer resins — product data — Dow (formerly DuPont Packaging & Industrial Polymers) (2023)
  2. Escor™ acid copolymers technical data — ExxonMobil Chemical (2022)
  3. Surlyn™ ionomer resins property guide — Dow (2023)
  4. Engineered Materials Handbook Vol.2: Engineering Plastics — ASM International (1988)
  5. ASTM D1238 — Melt Flow Rates of Thermoplastics by Extrusion Plastometer — ASTM (2020)
  6. ASTM D638 / D882 / D1525 / D2240 — ASTM (2022)
  7. CAMPUS / UL Prospector ethylene acid copolymer entries — CAMPUS, UL Solutions (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.