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AS4D

Grade

AS4D = higher-modulus/higher-strength member of the AS4 family

Pick when a drop-in stiffness/strength upgrade over AS4 is wanted without moving to IM7.

High cost $$$$

Values for the AS4D condition

Other AS4 grades and fills

AS4 is listed in 7 conditions; see the grade overview at AS4.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
AS4/BMI unidirectional laminate
Pick when service temperature above the epoxy limit (to ~200–230 °C) is required with the same standard-modulus fiber.—2,0501.4—
APC-2/AS4
Pick for tough, solvent-resistant, weldable thermoplastic structure and continuous service near 250 °C.—2,130——
AS4/8552 unidirectional toughened epoxy laminate
Pick for current-production primary/secondary aerospace structure needing better damage tolerance and hot/wet retention than 3501-6.—2,200——
AS4/3501-6 unidirectional epoxy laminate
Pick this classic 177 °C-cure epoxy UD system when legacy aerospace allowables and extensive published data are required.—2,280——
Fine-filament (5.1 µm) variant of AS4
Pick when thinner filaments and slightly lower fiber density improve fabric drape and translation in thin laminates.—4,3401.8—
FIBER-12KDefault
AS4 12K dry tow
Pick for filament winding, weaving, braiding or in-house prepregging where the bare standard-modulus tow is needed.—4,4331.8—
AS4DThis page
Higher-modulus/higher-strength member of the AS4 family
Pick when a drop-in stiffness/strength upgrade over AS4 is wanted without moving to IM7.—4,8302—

What is AS4D?

AS4D is AS4 in the AS4D grade — pick when a drop-in stiffness/strength upgrade over AS4 is wanted without moving to IM7. AS4D has a tensile strength of 4,830 MPa (701 ksi), stronger than 95% of composite grades. Elongation at break is 2% and the elastic modulus is 241 GPa (35 Msi). AS4D has a density of 1.79 g/cm³ (0.0647 lb/in³), heavier than 56% of composite grades. FIBER-12K is the default condition FabDigit quotes; AS4D is available on request or by drawing note.

Advantages

  • Stiff — 241 GPa (35 Msi), better than 86% of composite grades
  • Good corrosion resistance — 90/100, better than 85% of composite grades
  • High service temperature — 400°C (752 °F), better than 78% of composite grades

AS4D properties

Typical room-temperature values for AS4D; 10 are specific to this condition. Other listed values are AS4 reference data and may not represent this condition. Bars are the position among composite grades.

Physical1

AS4D has a density of 1.79 g/cm³ (0.0647 lb/in³), heavier than 56% of composite grades.

Density1.79 g/cm³0.06 lb/in³

Mechanical4

AS4D has a tensile strength of 4,830 MPa (701 ksi), stronger than 95% of composite grades. Elongation at break is 2% and the elastic modulus is 241 GPa (35 Msi).

Elastic (Young's) Modulus241 GPa35 Msi
Tensile Strength (Ultimate)4,830 MPa701 ksi
Elongation at Break2%
Compressive Strength2,900 MPa421 ksi

Thermal6

AS4D is rated for continuous service to 400°C (752 °F). It conducts heat at 7 W/m·K (4.04 BTU/hr·ft·°F), better than 69% of composite grades. Thermal expansion is -0.4 µm/m·K (-0.222 µin/in·°F).

Thermal Conductivity7 W/m·K4 BTU/hr·ft·°F
Specific Heat Capacity712 J/kg·K0.17 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)-0.4 µm/m·K-0.22 µin/in·°F
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-269°C-452 °F
Limiting Oxygen Index55%

Electrical1

AS4D has an electrical resistivity of 1.6×10⁻⁵ Ω·m.

Electrical Resistivity1.6×10⁻⁵ Ω·m630 µΩ·in

Chemical & Environmental2

Corrosion resistance is excellent (90/100), better than 85% of composite grades.

Corrosion ResistanceExcellent90/100
Chemical Resistance SummaryFiber itself is inert to most acids, alkalis and solvents; performance of a part is governed by the matrix. Strong oxidizers (hot nitric acid, chromic acid) and air above ~400 °C degrade the fiber; direct contact with aluminium causes galvanic corrosion of the metal.

Sustainability3

Producing a kilogram of AS4D takes about 320 MJ of energy and emits 24 kg of CO₂ — more than 72% of composite grades. Typical recycled content is 0%.

Embodied Energy (primary production)320 MJ/kg137,575 BTU/lb
Embodied Carbon (primary production)24 kg CO₂/kg
Typical Recycled Content0%

Manufacturability1

AS4D's machinability is poor (30/100, worse than 54% of composite grades).

MachinabilityPoor30/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with AS4D

Is AS4 easy to machine?

Highly abrasive and delamination-prone — use PCD/diamond-coated tools, high speed with low feed, sharp compression routers, backing plates and dust extraction (conductive dust).

Can AS4 be welded?

Not weldable in epoxy/BMI form (bond or bolt); APC-2/PEEK versions can be resistance-, induction- or ultrasonically welded.

Can AS4 be formed, bent or molded?

Autoclave cure of prepreg (177 °C / 0.6–0.7 MPa for 3501-6 and 8552), or filament winding/RTM with dry tow; thermoplastic AS4/PEEK tape is press- or AFP-consolidated at 380–400 °C.

What surface finishes work on AS4?

Peel-ply or light abrasion plus solvent wipe before bonding; UV-protective primer/topcoat is needed outdoors, and glass or fiberglass isolation plies plus sealant are required at aluminium interfaces to prevent galvanic corrosion.

AS4 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
carbon (C)PAN-based fiber, non-graphitized standard modulus93.5 – 95.594
nitrogen (N)residual from PAN precursor3.5 – 65
oxygen + hydrogen (surface/residual)surface-treated (oxidized) fiber0.3 – 1.50.8
sizing (epoxy-compatible)GP/unsized/thermoplastic-compatible options available0.6 – 1.51

AS4D — frequently asked

What is AS4D used for?

AS4D is typically used for aircraft secondary structures, industrial tooling, sporting goods and automotive parts. In short: standard-modulus workhorse fiber; lowest-cost aerospace prepreg fiber; deepest allowables database.

What is the tensile strength of AS4D?

AS4D has a typical tensile strength of 4,830 MPa (701 ksi) — stronger than 95% of composite grades. Strength varies by condition: see the 7 listed tempers.

Is AS4D easy to machine?

Not especially — machinability is rated poor (30/100, worse than 54% of composite grades). Highly abrasive and delamination-prone — use PCD/diamond-coated tools, high speed with low feed, sharp compression routers, backing plates and dust extraction (conductive dust).

Can AS4D be welded?

Not weldable in epoxy/BMI form (bond or bolt); APC-2/PEEK versions can be resistance-, induction- or ultrasonically welded.

What surface finishes work on AS4D?

Peel-ply or light abrasion plus solvent wipe before bonding; UV-protective primer/topcoat is needed outdoors, and glass or fiberglass isolation plies plus sealant are required at aluminium interfaces to prevent galvanic corrosion.

Can AS4D be formed, bent or molded?

Autoclave cure of prepreg (177 °C / 0.6–0.7 MPa for 3501-6 and 8552), or filament winding/RTM with dry tow; thermoplastic AS4/PEEK tape is press- or AFP-consolidated at 380–400 °C.

What is the maximum service temperature of AS4D?

AS4D is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. HexTow AS4 / AS4C / AS4D Carbon Fiber Product Data — Hexcel (2020)
  2. HexPly 8552 Epoxy Matrix Product Data Sheet — Hexcel (2020)
  3. ASM Handbook Vol. 21: Composites — ASM International (2001)
  4. MIL-HDBK-17 / CMH-17 Composite Materials Handbook (AS4/3501-6, AS4/8552 data sets) — SAE / CMH-17 (2012)
  5. APC-2/AS4 Thermoplastic Composite Tape Data — Cytec/Solvay (2015)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.