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Aluminum 4004-O (Annealed)

Temper · default condition

AA 4004 · UNS A94004 · EN AW-4004, AlSi10Mg1.5

Default supply condition for 4004 braze foil and roll-bonded clad brazing sheet; maximum formability before the brazing cycle.

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Values for the O condition

Other 4004 tempers and conditions

4004 is listed in 7 conditions; see the grade overview at 4004.

Compare all 7 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
after vacuum brazing thermal cycle (~600 °C)
Condition of the solidified 4004 fillet/clad after the brazing cycle; fully annealed, coarse Si structure, use for joint-strength design.75170655 HB40 % IACS
ODefaultThis page
Annealed
Default supply condition for 4004 braze foil and roll-bonded clad brazing sheet; maximum formability before the brazing cycle.902001060 HB38 % IACS
Strain hardened, quarter hard
Light cold work for slightly stiffer fin/clad strip that still needs to be corrugated.155225770 HB37 % IACS
Strain hardened, half hard
Most common hard condition for 4004-clad brazing sheet supplied for fin forming and stamped plates.195250580 HB37 % IACS
Strain hardened, three-quarter hard
Stiffer strip where fin collapse resistance during brazing matters more than bend ductility.225270488 HB37 % IACS
Strain hardened, full hard
Full-hard thin foil/strip supplied as-rolled without interanneal; maximum strength, minimum ductility.255290395 HB37 % IACS
Strain hardened, extra hard
Very thin heavily cold-rolled braze foil used as a free-standing interlayer shim in vacuum brazing.2803102100 HB37 % IACS

What is 4004-O?

4004-O is 4004 in the O temper — default supply condition for 4004 braze foil and roll-bonded clad brazing sheet; maximum formability before the brazing cycle. 4004-O has a yield strength of 90 MPa (13.1 ksi) and a tensile strength of 200 MPa (29 ksi) — weaker than 87% of aluminum grades. Elongation at break is 10% and the elastic modulus is 71 GPa (10.3 Msi). 4004-O has a density of 2.66 g/cm³ (0.0961 lb/in³), lighter than 84% of aluminum grades. It melts at 559°C (1,038 °F).

Limitations

  • Hard to polish — 35/100, worse than 98% of aluminum grades
  • Difficult to machine — 30/100, worse than 92% of aluminum grades
  • Low strength — 90 MPa (13.1 ksi), worse than 87% of aluminum grades

4004-O properties

Typical room-temperature values for 4004-O; 11 are specific to this condition. Other listed values are 4004 reference data and may not represent this condition. Bars are the position among aluminum grades.

Physical3

4004-O has a density of 2.66 g/cm³ (0.0961 lb/in³), lighter than 84% of aluminum grades. It melts at 559°C (1,038 °F).

Density2.66 g/cm³0.1 lb/in³
Melting Point (Solidus)559°C1,038 °F
Liquidus Temperature596°C1,105 °F

Mechanical10

4004-O has a yield strength of 90 MPa (13.1 ksi) and a tensile strength of 200 MPa (29 ksi) — weaker than 87% of aluminum grades. Elongation at break is 10% and the elastic modulus is 71 GPa (10.3 Msi).

Elastic (Young's) Modulus71 GPa10.3 Msi
Shear Modulus26.5 GPa3.8 Msi
Bulk Modulus70 GPa10.2 Msi
Poisson's Ratio0.33
Tensile Strength (Ultimate)200 MPa29 ksi
Yield Strength (0.2% offset)90 MPa13.1 ksi
Elongation at Break10%
Shear Strength125 MPa18.1 ksi
Fatigue Strength (Endurance Limit)60 MPa8.7 ksi
Hardness, Brinell60 HB

Thermal6

4004-O is rated for continuous service to 150°C (302 °F). It conducts heat at 155 W/m·K (89.6 BTU/hr·ft·°F), better than 71% of aluminum grades. Thermal expansion is 20.5 µm/m·K (11.4 µin/in·°F).

Thermal Conductivity155 W/m·K89.6 BTU/hr·ft·°F
Specific Heat Capacity880 J/kg·K0.21 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)20.5 µm/m·K11.4 µin/in·°F
Latent Heat of Fusion460 J/g198 BTU/lb
Max Service Temperature (continuous)150°C302 °F
Min Service Temperature-196°C-321 °F

Electrical3

4004-O conducts electricity at 38 % IACS, better than 61% of aluminum grades.

Electrical Conductivity38 % IACS
Electrical Resistivity4.66×10⁻⁸ Ω·m1.83 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is good (55/100), worse than 51% of aluminum grades.

Galvanic Potential (seawater, vs SCE)-0.82 V
Corrosion ResistanceGood55/100
Chemical Resistance SummaryGood in neutral atmospheres and dry refrigerant/coolant circuits; attacked by strong acids and alkalis, and Mg-rich clad is more sensitive to chloride pitting than 1000 series/7072 cladding.

Sustainability4

Producing a kilogram of 4004-O takes about 200 MJ of energy and emits 12 kg of CO₂ — less than 60% of aluminum grades. Typical recycled content is 25%.

Embodied Energy (primary production)200 MJ/kg85,985 BTU/lb
Embodied Carbon (primary production)12 kg CO₂/kg
Embodied Water1,150 L/kg138 gal/lb
Typical Recycled Content25%

Manufacturability8

4004-O's machinability is poor (30/100, worse than 92% of aluminum grades); weldability good (55/100); formability good (55/100).

MachinabilityPoor30/100
Machinability Rating (AISI 1212 = 100 %)30%
WeldabilityGood55/100
Formability (cold)Good55/100
CastabilityVery good80/100
Brazeability / SolderabilityExcellent97/100
PolishabilityFair35/100
Anodizing Responsepoor — high Si content gives a dark grey to charcoal, often blotchy anodic film; decorative anodizing is not recommended

Common Calculations5

Specific Strength (UTS / density)calculated75 kN·m/kg
Specific Stiffness (E / density)calculated26.7 MN·m/kg
Modulus of Resiliencecalculated57 kJ/m³
Thermal Diffusivitycalculated66.2 mm²/s
Thermal Shock Resistance Indexcalculated21

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with 4004-O

Is 4004 easy to machine?

Rarely machined; when required use PCD or diamond-coated carbide, high speed and flood coolant because ~10 % primary/eutectic Si is very abrasive.

Can 4004 be welded?

Mainly used as a braze filler; GTAW/GMAW is possible but the 1–2 % Mg with 10 % Si makes the deposit hot-short and porosity-prone, so pre-clean and keep heat input low.

Can 4004 be formed, bent or molded?

Form in O or H12 temper — clad brazing sheet corrugates and stamps well, but bend radii must be generous in H16/H18 since the Si-rich layer cracks readily.

What surface finishes work on 4004?

Do not decorative-anodize (dark grey, blotchy); after brazing, the surface is normally left as-brazed, chromate-free conversion coated, or e-coated for corrosion protection.

4004 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Sisets the low melting range9 – 10.59.8
Mgoxide getter for fluxless vacuum brazing1 – 21.5
Fe≤ 0.8—
Cu≤ 0.25—
Mn≤ 0.1—
Zn≤ 0.2—
Others (each)≤ 0.05—
Others (total)≤ 0.15—
Albalance—

4004-O — frequently asked

What is 4004-O used for?

4004-O is typically used for automotive radiator/HVAC brazing clad sheet, vacuum brazed heat exchangers and clad fin stock. In short: vacuum brazing clad layer; low melting Al-Si filler; not a structural mill product.

What is the yield strength of 4004-O?

4004-O has a typical yield strength of 90 MPa (13.1 ksi) and a tensile strength of 200 MPa (29 ksi) — weaker than 87% of aluminum grades. Strength varies by condition: see the 7 listed tempers.

Is 4004-O easy to machine?

Not especially — machinability is rated poor (30/100, worse than 92% of aluminum grades). Rarely machined; when required use PCD or diamond-coated carbide, high speed and flood coolant because ~10 % primary/eutectic Si is very abrasive.

Can 4004-O be welded?

Yes — weldability is rated good (55/100). Mainly used as a braze filler; GTAW/GMAW is possible but the 1–2 % Mg with 10 % Si makes the deposit hot-short and porosity-prone, so pre-clean and keep heat input low.

What surface finishes work on 4004-O?

Do not decorative-anodize (dark grey, blotchy); after brazing, the surface is normally left as-brazed, chromate-free conversion coated, or e-coated for corrosion protection.

Can 4004-O be formed, bent or molded?

Form in O or H12 temper — clad brazing sheet corrugates and stamps well, but bend radii must be generous in H16/H18 since the Si-rich layer cracks readily.

What is the maximum service temperature of 4004-O?

4004-O is rated for continuous use to about 150°C (302 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between 4004-O and 4004-H19?

O is the default condition — default supply condition for 4004 braze foil and roll-bonded clad brazing sheet; maximum formability before the brazing cycle. H19: very thin heavily cold-rolled braze foil used as a free-standing interlayer shim in vacuum brazing. Yield strength is 90 MPa in O versus 280 MPa in H19.

Sources

  1. International Alloy Designations and Chemical Composition Limits for Wrought Aluminum (Teal Sheets) — The Aluminum Association (2018)
  2. AWS A5.8/A5.8M — Specification for Filler Metals for Brazing and Braze Welding (BAlSi-7) — AWS (2019)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys — ASM International (1990)
  4. ASM Handbook Vol. 6 — Welding, Brazing and Soldering (Aluminum Brazing) — ASM International (1993)
  5. Aluminium brazing sheet / cladding alloy data (4004, 4104, 4343) — Multiple rolling mills (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.