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Refractory Metal Zr 702-HW (Hot worked)

Heat-treated state

UNS R60702 · ASTM B550/B551 Grade 702

Economical condition for heavy forged sections and thick plate before final annealing; slightly higher strength, coarser structure than annealed.

High cost $$$$

Values for the HW condition

Other Zr 702 tempers and conditions

Zr 702 is listed in 5 conditions; see the grade overview at Zr 702.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
As-welded deposit
Property basis for fabricated vessels and pipe joints welded with full inert shielding; coarse weld-metal grain lowers ductility slightly, strength matches base metal.28045018165 HB4.3 % IACS
AnnealedDefault
recrystallization annealed (ASTM B550/B551/B523/B658 standard condition)
Default stocked condition for plate, sheet, bar, pipe and tube in chemical-process service; best ductility, formability and corrosion behaviour.29045030150 HB—
HWThis page
Hot worked
Economical condition for heavy forged sections and thick plate before final annealing; slightly higher strength, coarser structure than annealed.33048025165 HB4.3 % IACS
Cold worked and stress relieved
Pick for cold-drawn tubing and pipe where higher strength and tight dimensional control are needed while retaining useful ductility.4505501895 HRB—
Cold worked
Highest strength condition of Zr 702; used for fasteners, springs, wire and machined parts where ductility demands are modest.55062012100 HRB—

What is Zr 702-HW?

Zr 702-HW is Zr 702 heat treated to HW — economical condition for heavy forged sections and thick plate before final annealing; slightly higher strength, coarser structure than annealed. Zr 702-HW has a yield strength of 330 MPa (47.9 ksi) and a tensile strength of 480 MPa (69.6 ksi) — stronger than 50% of refractory metal grades. Elongation at break is 25% and the elastic modulus is 99 GPa (14.4 Msi). Zr 702-HW has a density of 6.51 g/cm³ (0.235 lb/in³), lighter than 84% of refractory metal grades. It melts at 1,852°C (3,366 °F). Annealed is the default condition FabDigit quotes; HW is available on request or by drawing note.

Advantages

  • Readily welded — 78/100, better than 86% of refractory metal grades
  • Lightweight — 6.51 g/cm³ (0.235 lb/in³), better than 84% of refractory metal grades
  • Tough — resists crack growth — 62 MPa·√m (56.4 ksi·√in), better than 80% of refractory metal grades

Limitations

  • Limited service temperature — 371°C (700 °F), worse than 87% of refractory metal grades
  • Low stiffness — 99 GPa (14.4 Msi), worse than 79% of refractory metal grades

Zr 702-HW properties

Typical room-temperature values for Zr 702-HW; 22 are specific to this condition. Other listed values are Zr 702 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Zr 702-HW has a density of 6.51 g/cm³ (0.235 lb/in³), lighter than 84% of refractory metal grades. It melts at 1,852°C (3,366 °F).

Density6.51 g/cm³0.24 lb/in³
Melting Point (Solidus)1,852°C3,366 °F
Liquidus Temperature1,852°C3,366 °F

Mechanical16

Zr 702-HW has a yield strength of 330 MPa (47.9 ksi) and a tensile strength of 480 MPa (69.6 ksi) — stronger than 50% of refractory metal grades. Elongation at break is 25% and the elastic modulus is 99 GPa (14.4 Msi).

Elastic (Young's) Modulus99 GPa14.4 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus92 GPa13.3 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)480 MPa69.6 ksi
Yield Strength (0.2% offset)330 MPa47.9 ksi
Elongation at Break25%
Reduction in Area40%
Compressive Strength340 MPa49.3 ksi
Shear Strength305 MPa44.2 ksi
Fatigue Strength (Endurance Limit)245 MPa35.5 ksi
Fracture Toughness (K_IC)62 MPa·√m56.4 ksi·√in
Charpy V-Notch Impact (RT)50 J36.9 ft·lbf
Hardness, Brinell165 HB
Hardness, Rockwell B88 HRB
Hardness, Vickers178 HV

Thermal6

Zr 702-HW is rated for continuous service to 371°C (700 °F). It conducts heat at 22 W/m·K (12.7 BTU/hr·ft·°F), worse than 66% of refractory metal grades. Thermal expansion is 5.9 µm/m·K (3.28 µin/in·°F).

Thermal Conductivity22 W/m·K12.7 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.9 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion153 J/g65.8 BTU/lb
Max Service Temperature (continuous)371°C700 °F
Min Service Temperature-196°C-321 °F

Electrical3

Zr 702-HW conducts electricity at 4.3 % IACS, worse than 62% of refractory metal grades.

Electrical Conductivity4.3 % IACS
Electrical Resistivity4×10⁻⁷ Ω·m15.7 µΩ·in
Magnetic Responsenon-magnetic (paramagnetic, µr ≈ 1.000)

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 86% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.2 V
Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryOutstanding in HCl (all concentrations to boiling), H2SO4 up to ~70%, HNO3, organic acids, alkalis and chlorides/seawater; attacked by HF, fluoride-bearing media, concentrated FeCl3/CuCl2, aqua regia, wet Cl2 and hot concentrated H2SO4 (>80%); risk of pyrophoric fines and hydriding above ~350 °C.

Sustainability4

Producing a kilogram of Zr 702-HW takes about 1,250 MJ of energy and emits 85 kg of CO₂ — more than 52% of refractory metal grades. Typical recycled content is 15%.

Embodied Energy (primary production)1,250 MJ/kg537,404 BTU/lb
Embodied Carbon (primary production)85 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content15%

Manufacturability8

Zr 702-HW's machinability is poor (34/100, better than 73% of refractory metal grades); weldability very good (78/100); formability good (60/100).

MachinabilityPoor34/100
Machinability Rating (AISI 1212 = 100 %)29%
WeldabilityVery good78/100
Formability (cold)Good60/100
CastabilityPoor30/100
Brazeability / SolderabilityPoor25/100
PolishabilityVery good70/100
Anodizing Responsegood — anodic ZrO2 films give controllable interference colours; used decoratively and for medical/implant surfaces, but not a load-bearing wear coating

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Zr 702-HW

Is Zr 702 easy to machine?

Machine like a gummy austenitic stainless — sharp uncoated carbide, slow speeds, heavy positive rake, generous flood coolant; collect chips wet, fine turnings and grinding dust are pyrophoric.

Can Zr 702 be welded?

GTAW (or EB/plasma) with high-purity argon plus trailing shield and back purge; keep the weld and HAZ bright-silver — straw/blue/grey tint means oxygen pickup and must be removed.

Can Zr 702 be formed, bent or molded?

Cold forms readily at 3–5t bend radii but springs back strongly; warm forming at 200–350 °C is used for tight bends and heads, and hydrogen/oxygen pickup must be avoided in any heating.

What surface finishes work on Zr 702?

Pickle in HNO3–HF to remove oxide/contaminated layers, then descale-free passivation; can be electropolished or anodized to coloured oxide, avoid iron contamination from steel tooling.

Zr 702 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Hfmax per ASTM B550/B551≤ 4.52
Fe+Cr≤ 0.20.1
Oprincipal strengthening interstitial≤ 0.160.1
C≤ 0.050.02
N≤ 0.030.01
Hhydrogen embrittlement control≤ 0.010
Zr+HfHf is not removed in commercial grade≥ 99.2 (balance)—

Zr 702-HW — frequently asked

What is Zr 702-HW used for?

Zr 702-HW is typically used for acid plant piping, heat exchangers, chemical reactor vessels and nuclear-adjacent process equipment. In short: default corrosion-service zirconium; handles hot acids and alkalis; weldable and cold formable.

What is the yield strength of Zr 702-HW?

Zr 702-HW has a typical yield strength of 330 MPa (47.9 ksi) and a tensile strength of 480 MPa (69.6 ksi) — stronger than 50% of refractory metal grades. Strength varies by condition: see the 5 listed tempers.

Is Zr 702-HW easy to machine?

Not especially — machinability is rated poor (34/100, better than 73% of refractory metal grades). Machine like a gummy austenitic stainless — sharp uncoated carbide, slow speeds, heavy positive rake, generous flood coolant; collect chips wet, fine turnings and grinding dust are pyrophoric.

Can Zr 702-HW be welded?

Yes — weldability is rated very good (78/100). GTAW (or EB/plasma) with high-purity argon plus trailing shield and back purge; keep the weld and HAZ bright-silver — straw/blue/grey tint means oxygen pickup and must be removed.

What surface finishes work on Zr 702-HW?

Pickle in HNO3–HF to remove oxide/contaminated layers, then descale-free passivation; can be electropolished or anodized to coloured oxide, avoid iron contamination from steel tooling.

Can Zr 702-HW be formed, bent or molded?

Cold forms readily at 3–5t bend radii but springs back strongly; warm forming at 200–350 °C is used for tight bends and heads, and hydrogen/oxygen pickup must be avoided in any heating.

What is the maximum service temperature of Zr 702-HW?

Zr 702-HW is rated for continuous use to about 371°C (700 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Zr 702 Annealed and Zr 702-CW?

Annealed is the default condition — default stocked condition for plate, sheet, bar, pipe and tube in chemical-process service; best ductility, formability and corrosion behaviour. CW: highest strength condition of Zr 702; used for fasteners, springs, wire and machined parts where ductility demands are modest. Yield strength is 290 MPa in Annealed versus 550 MPa in CW.

Sources

  1. ASTM B551/B551M — Zirconium and Zirconium Alloy Strip, Sheet, and Plate — ASTM International (2019)
  2. ASTM B550/B550M — Zirconium and Zirconium Alloy Bar and Wire — ASTM International (2020)
  3. ASTM B523 / B658 — Zirconium alloy seamless tube and pipe — ASTM International (2020)
  4. ASM Handbook Vol. 2 — Properties of Nonferrous Alloys (Zirconium and Hafnium) — ASM International (1990)
  5. Zirconium 702 alloy data and corrosion tables — ATI (Wah Chang) (2018)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.