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TPU-Caprolactone 55D

Hardness band

ISO 18064 TPU-C

55D = shore 55D

Semi-rigid grade for ski boots, gears, couplings and structural wear parts needing stiffness plus toughness.

Premium cost $$$

Values for the 55D condition

Other TPU-Caprolactone grades and fills

TPU-Caprolactone is listed in 7 conditions; see the grade overview at TPU-Caprolactone.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Flame retardant, halogen-free
Pick for cable jackets, industrial connectors and rail/E&E parts requiring UL 94 V-0 at 1.5–3 mm.—3038037 Shore D
Antistatic / ESD conductive
Carbon-black or ionic-antistat compound for fuel-line covers, mining belts and ESD-safe hoses and rollers.—3540038 Shore D
Solution / adhesive & coating grade
Linear, solvent-soluble (MEK/DMF/THF) high-molecular-weight TPU-C for shoe adhesives, laminating films and textile coatings.—3565028 Shore D
Shore 80A
Choose for flexible tubing, soft films and adhesive/laminating layers needing high elongation.—3862029 Shore D
Shore 90A
Best all-round abrasion/oil grade for rollers, seals, conveyor components and shoe soles.—5050038 Shore D
Shore 95A
For high-load wear parts, wheels, hydraulic seals and stiff jacketing where creep resistance matters.—5545046 Shore D
55DThis page
Shore 55D
Semi-rigid grade for ski boots, gears, couplings and structural wear parts needing stiffness plus toughness.—5538055 Shore D

What is TPU-Caprolactone 55D?

TPU-Caprolactone 55D is TPU-Caprolactone heat treated to 55D — semi-rigid grade for ski boots, gears, couplings and structural wear parts needing stiffness plus toughness. TPU-Caprolactone 55D has a tensile strength of 55 MPa (7.98 ksi), stronger than 61% of polymer grades. Elongation at break is 380% and the elastic modulus is 0.2 GPa (0.029 Msi). TPU-Caprolactone 55D has a density of 1.23 g/cm³ (0.0444 lb/in³), heavier than 62% of polymer grades. Its glass-transition temperature is -50°C (-58 °F).

Advantages

  • Forms and bends easily — 90/100, better than 91% of polymer grades
  • Readily welded — 85/100, better than 89% of polymer grades
  • Ductile — tolerates forming and impact — 380%, better than 85% of polymer grades

Limitations

  • Absorbs moisture — dry before molding — 0.6%, worse than 75% of polymer grades

TPU-Caprolactone 55D properties

Typical room-temperature values for TPU-Caprolactone 55D; 11 are specific to this condition. Other listed values are TPU-Caprolactone reference data and may not represent this condition. Bars are the position among polymer grades.

Physical5

TPU-Caprolactone 55D has a density of 1.23 g/cm³ (0.0444 lb/in³), heavier than 62% of polymer grades. Its glass-transition temperature is -50°C (-58 °F).

Density1.23 g/cm³0.04 lb/in³
Melting Temperature (Tm)195°C383 °F
Glass Transition (Tg)-50°C-58 °F
Water Absorption (24 h)0.6%
Water Absorption (Saturation)1.5%

Mechanical8

TPU-Caprolactone 55D has a tensile strength of 55 MPa (7.98 ksi), stronger than 61% of polymer grades. Elongation at break is 380% and the elastic modulus is 0.2 GPa (0.029 Msi).

Elastic (Young's) Modulus0.2 GPa0.03 Msi
Poisson's Ratio0.48
Tensile Strength (Ultimate)55 MPa8 ksi
Elongation at Break380%
Hardness, Shore A86 Shore A
Hardness, Shore D55 Shore D
Tear Strength180 kN/m1,028 lbf/in
Compression Set (22 h, 70 °C)30%

Thermal9

TPU-Caprolactone 55D is rated for continuous service to 95°C (203 °F). It conducts heat at 0.2 W/m·K (0.116 BTU/hr·ft·°F), worse than 56% of polymer grades. Thermal expansion is 175 µm/m·K (97.2 µin/in·°F).

Thermal Conductivity0.2 W/m·K0.12 BTU/hr·ft·°F
Specific Heat Capacity1,700 J/kg·K0.41 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)175 µm/m·K97.2 µin/in·°F
Max Service Temperature (continuous)95°C203 °F
Min Service Temperature-40°C-40 °F
Vicat Softening Point (B50)105°C221 °F
Flammability (UL 94)HB (unmodified); V-0 achievable only with halogen-free FR compounds
Limiting Oxygen Index21%
Max Service Temperature (short-term)120°C248 °F

Electrical6

TPU-Caprolactone 55D is an electrical insulator with a dielectric strength of 25 kV/mm (635 V/mil) and a resistivity of 1×10⁹ Ω·m.

Electrical Resistivity1×10⁹ Ω·m3.94×10¹⁶ µΩ·in
Dielectric Strength25 kV/mm635 V/mil
Dielectric Constant (1 MHz)5
Dissipation Factor (1 MHz)0.05
Volume Resistivity1×10¹² Ω·cm
Surface Resistivity1×10¹² Ω

Chemical & Environmental3

Corrosion resistance is very good (78/100), worse than 61% of polymer grades. UV resistance is fair.

Corrosion ResistanceVery good78/100
UV / Weathering ResistanceFair40/100
Chemical Resistance SummaryGood against mineral oils, greases, aliphatic hydrocarbons, and dilute acids; markedly better hydrolysis and microbial resistance than adipate polyester TPU. Attacked/swollen by polar solvents (DMF, THF, ketones, esters), hot water above ~70 °C over long periods, strong acids/bases and steam.

Sustainability4

Producing a kilogram of TPU-Caprolactone 55D takes about 125 MJ of energy and emits 6 kg of CO₂ — more than 75% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)125 MJ/kg53,740 BTU/lb
Embodied Carbon (primary production)6 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content0%

Manufacturability8

TPU-Caprolactone 55D's machinability is fair (50/100, worse than 73% of polymer grades); weldability excellent (85/100); formability excellent (90/100).

MachinabilityFair50/100
WeldabilityExcellent85/100
Formability (cold)Excellent90/100
PolishabilityFair40/100
Mold Shrinkage0.9%
Melt Flow Rate25 g/10 min
Processing Melt Temperature (typ.)210°C410 °F
Mold Temperature (typ.)30°C86 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with TPU-Caprolactone 55D

Is TPU-Caprolactone easy to machine?

Machinable only on rigid (55D+) grades with sharp, high-rake tools, high speed and low feed; soft grades smear and need freezing or water-jet/die cutting.

Can TPU-Caprolactone be welded?

Excellent HF (dielectric), ultrasonic, hot-plate and hot-air welding; solvent bonding with DMF/THF blends and polyurethane adhesives works well.

Can TPU-Caprolactone be formed, bent or molded?

Dry 2–3 h at 100–110 °C to <0.02 % moisture, inject at 190–225 °C melt / 20–50 °C mold, avoid shear-degradation and long residence times; extrudable into film, tube and profile.

What surface finishes work on TPU-Caprolactone?

Takes PU-based paints, flock and printing after corona/flame or primer treatment; can be textured directly in the mold, but polishing to a high gloss is limited by its elastomeric surface.

TPU-Caprolactone chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
polycaprolactone diol (soft segment)PCL polyol, typ. Mn 1000–2000 g/mol; source of hydrolysis/microbial resistance50 – 7060
4,4'-MDI (diisocyanate)aromatic; TDI/HDI/H12MDI used for light-stable variants22 – 3529
1,4-butanediol (chain extender)forms hard segment with MDI5 – 129
additives (waxes, antioxidant, UV, FR, pprocess aids and stabilizers0.2 – 31

TPU-Caprolactone 55D — frequently asked

What is TPU-Caprolactone 55D used for?

TPU-Caprolactone 55D is typically used for hot-melt adhesives, coatings, specialty films and cable insulation. In short: balanced ester/ether TPU; highest TPU service temperature; adhesive and coating grade.

What is the tensile strength of TPU-Caprolactone 55D?

TPU-Caprolactone 55D has a typical tensile strength of 55 MPa (7.98 ksi) — stronger than 61% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is TPU-Caprolactone 55D easy to machine?

Reasonably — machinability is rated fair (50/100, worse than 73% of polymer grades). Machinable only on rigid (55D+) grades with sharp, high-rake tools, high speed and low feed; soft grades smear and need freezing or water-jet/die cutting.

Can TPU-Caprolactone 55D be welded?

Yes — weldability is rated excellent (85/100). Excellent HF (dielectric), ultrasonic, hot-plate and hot-air welding; solvent bonding with DMF/THF blends and polyurethane adhesives works well.

What surface finishes work on TPU-Caprolactone 55D?

Takes PU-based paints, flock and printing after corona/flame or primer treatment; can be textured directly in the mold, but polishing to a high gloss is limited by its elastomeric surface.

Can TPU-Caprolactone 55D be formed, bent or molded?

Dry 2–3 h at 100–110 °C to <0.02 % moisture, inject at 190–225 °C melt / 20–50 °C mold, avoid shear-degradation and long residence times; extrudable into film, tube and profile.

What is the maximum service temperature of TPU-Caprolactone 55D?

TPU-Caprolactone 55D is rated for continuous use to about 95°C (203 °F), and briefly to 120°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ISO 18064 — Thermoplastic elastomers, nomenclature and abbreviated terms — ISO (2014)
  2. ISO 37 / ISO 868 / ISO 34-1 / ISO 815 — rubber test methods — ISO (2019)
  3. Elastollan C-series (polycaprolactone TPU) product range and processing guide — BASF Polyurethanes (2023)
  4. Desmopan / Texin TPU selection and processing data — Covestro (2023)
  5. CAPA polycaprolactone polyols for TPU technical brochure — Perstorp (2022)
  6. Engineered Materials Handbook, Vol. 2: Engineering Plastics — ASM International (1988)
  7. CAMPUS plastics database — TPU (ester) property sets — CWFG / CAMPUS consortium (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.