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Elastomers

Elastomers are the rubbers: lightly cross-linked or physically networked polymers that stretch 200–800 % and recover. Thermoset rubbers (NBR, EPDM, FKM, Silicone, natural rubber) are vulcanized and cannot be remelted; thermoplastic elastomers (TPU, TPE, TPV) mold and print like a plastic and behave like a rubber. Hardness runs from about 10 Shore A gels to 95 Shore A urethanes, and the choice is made by what the part touches and how hot it gets.

Popular elastomer grades

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Choose elastomers for

O-rings, gaskets and lip seals matched to the fluid (NBR, HNBR, FKM, EPDM); grips, bumpers, feet, wheels and straps (TPU, PU Cast, TPE); overmolded soft-touch zones on rigid housings (TPE, SEBS, TPU); vibration mounts and dampers (NR, SBR, Silicone); printed flexible parts (TPU, Agilus); and any part that has to stretch, seal, cushion or grip.

Look elsewhere when

The part must carry load without deflecting (a rigid engineering plastic or a spring), it needs a precise dimension held under compression (elastomers creep and take a compression set — design the seal groove, not the seal, to control it), the service temperature exceeds about 250 °C (FFKM, then metal or graphite seals), or the volume is a few hundred pieces of a simple soft shape, where PU Cast or cast silicone in a silicone mold is faster than a rubber compression tool.

Tensile strength against max service temp, Elastomers among every polymer grade

No materials in view have both of these properties.

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Elastomer by application

Seals in oil and fuel
NBR for mineral oil, grease and hydraulic fluid; HNBR for the same fluids above 100 °C or in sour gas; FKM for fuels, hot engine oil and most chemicals to 200 °C; FFKM for aggressive solvents and semiconductor process chemistries.
Outdoor and hot-water seals
EPDM for sunlight, ozone, steam and glycol coolant (it swells in oil); Silicone where the temperature range is wider (–60 to 200 °C) or the part touches food or skin; CR (neoprene) as the general-purpose weather-and-oil compromise.
Grips, wheels and bumpers
TPU (85–95 Shore A) for molded and printed grips, cases and wheels; PU Cast for the toughest rollers, bumpers and wear pads; TPE and SEBS overmolds for soft-touch handles that cost less and bond to PP.
Printed flexible parts
TPU on FDM, SLS and MJF for functional gaskets, hinges and lattices (about 85–95 Shore A); Agilus on PolyJet for 30–95 Shore A multi-material rubber-like prototypes that look and feel molded.

Working with elastomer

Molding and casting
Thermoset rubbers (NBR, EPDM, FKM, Silicone) are compression-, transfer- or injection-molded and vulcanized at 150–200 °C in steel tools; TPU, TPE and TPV injection mold like a plastic, with 1–2 % shrinkage and no cure step, and overmold directly onto PC, ABS or PP. For 10–200 soft parts, casting PU Cast or silicone in a silicone mold avoids tooling.
Machining and cutting
Rubber does not machine well: soft grades deflect and tear. Gaskets and pads are die-cut, waterjet-cut or laser-cut from sheet; hard urethane above 90 Shore A and PU Cast turn and grind with sharp tools and coolant, or are frozen first. Design for cut sheet, molded or cast shapes rather than machined ones.
Bonding and assembly
TPU and TPE bond to their base plastic by overmolding and take cyanoacrylate and polyurethane adhesives; NBR, EPDM and NR bond with cyanoacrylate or rubber cement after abrasion; FKM needs a fluoroelastomer primer; Silicone bonds only to silicone or a primed surface. Ultrasonic welding works for TPU, not for thermoset rubbers.
Durometer and compression set
Specify Shore A hardness (typical tolerance ±5 A) and compression set at temperature, not just tensile strength. Seals usually run 60–90 Shore A; grips 40–70 A; cushioning 10–40 A. Every elastomer hardens with heat and time — EPDM and Silicone the least, NBR and NR the most — so state the service temperature and the fluid on the drawing.

Other polymer series

Elastomers — frequently asked

What is elastomer?

Elastomers are the rubbers: lightly cross-linked or physically networked polymers that stretch 200–800 % and recover. Thermoset rubbers (NBR, EPDM, FKM, Silicone, natural rubber) are vulcanized and cannot be remelted; thermoplastic elastomers (TPU, TPE, TPV) mold and print like a plastic and behave like a rubber. Hardness runs from about 10 Shore A gels to 95 Shore A urethanes, and the choice is made by what the part touches and how hot it gets.

Which grade of elastomer should I use?

TPU for anything molded or printed that must be tough and flexible — grips, wheels, belts, cable jackets, protective cases — with TPU-Ether for hydrolysis resistance and TPU-Ester for oil and abrasion. NBR for oil, fuel and hydraulic seals to about 100 °C; HNBR when the same seal runs hotter. EPDM for weather, ozone, steam and hot water (not oils) — outdoor gaskets, coolant hoses, window seals. FKM for fuel, hot oil and chemicals to 200 °C; FFKM only when nothing else survives the chemistry. Silicone for food, skin, medical and –60 to 200 °C. PU Cast for the toughest wheels, bumpers and wear pads; TPE and SEBS for soft-touch overmolds and low-cost grips.

Which grade of elastomer is the strongest?

TPA (PEBA) has the highest yield strength in the series at 20 MPa; TPC (COPE/TPEE) follows at 18 MPa. Values are for each grade's default condition.

Which grade of elastomer is easiest to machine?

TPO (machinability fair, 50/100), then CSM (35/100).

TPU or cast polyurethane?

TPU is a thermoplastic: it injection molds, extrudes and 3D prints, comes in 60 Shore A to 75 Shore D, and is the choice for volume parts and printed flexible prototypes. PU Cast is a thermoset poured into a mold and cured: it reaches higher tear and abrasion resistance, larger and thicker sections without sink, and any durometer per batch, but each part needs a mold cycle. Low volume, thick, or the toughest wheels and pads: cast. High volume or printed: TPU.

NBR, EPDM or FKM for an O-ring?

Match the fluid: NBR for mineral oils, greases and fuels to about 100 °C; EPDM for water, steam, glycol coolants, brake fluid and outdoor weather (never mineral oil — it swells); FKM for fuels, hot oils, acids and most solvents to 200 °C. If the seal sees both oil and ozone, HNBR or FKM; if it sees ketones, EPDM or FFKM.