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mLLDPE NAT-C6

Grade · default condition

ASTM D1248 · ISO 1872-1

NAT-C6 = natural film grade, 1-hexene copolymer

Standard high-clarity blown-film mLLDPE for stretch/collation and packaging film; best balance of price and toughness.

Standard cost $$

Values for the NAT-C6 condition

Other mLLDPE grades and fills

mLLDPE is listed in 7 conditions; see the grade overview at mLLDPE.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Metallocene plastomer / VLDPE (density 0.885–0.912)
Very-low-density mPE for ultra-low seal initiation temperature, soft flexible film, impact modification and blend toughening.62290033 Shore D
Natural film grade, 1-octene copolymer
Choose when maximum dart impact, puncture resistance and low seal-initiation temperature are needed (heavy-duty sacks, sealant layers).103385047 Shore D
NAT-C6DefaultThis page
Natural film grade, 1-hexene copolymer
Standard high-clarity blown-film mLLDPE for stretch/collation and packaging film; best balance of price and toughness.103075048 Shore D
Slip / antiblock additivated film grade
Erucamide slip plus silica/talc antiblock for low COF film that runs on FFS and bagging lines.103272047 Shore D
Injection-moulding grade
High melt-flow mLLDPE for thin-wall lids, closures and housewares needing ESCR and low-temperature impact.112260052 Shore D
Carbon-black UV grade
Black, carbon-black-loaded version for maximum outdoor life in pipe liners, geomembrane and silage film; opaque only.112870050 Shore D
Rotomoulding grade
Heat-stabilised, ground-powder mLLDPE for tanks and containers where impact at low temperature and ESCR matter.172655060 Shore D

What is mLLDPE NAT-C6?

mLLDPE NAT-C6 is mLLDPE in the NAT-C6 grade — standard high-clarity blown-film mLLDPE for stretch/collation and packaging film; best balance of price and toughness. mLLDPE NAT-C6 has a yield strength of 10 MPa (1.45 ksi) and a tensile strength of 30 MPa (4.35 ksi) — weaker than 91% of polymer grades. Elongation at break is 750% and the elastic modulus is 0.25 GPa (0.0363 Msi). mLLDPE NAT-C6 has a density of 0.92 g/cm³ (0.0332 lb/in³), lighter than 80% of polymer grades. Its glass-transition temperature is -120°C (-184 °F).

Advantages

  • Ductile — tolerates forming and impact — 750%, better than 99% of polymer grades
  • Forms and bends easily — 92/100, better than 97% of polymer grades
  • Low moisture uptake — 0.01%, better than 97% of polymer grades
  • Low embodied carbon — 2 kg CO₂/kg, better than 96% of polymer grades
  • Readily welded — 90/100, better than 94% of polymer grades

Limitations

  • Low strength — 10 MPa (1.45 ksi), worse than 91% of polymer grades
  • Hard to polish — 30/100, worse than 82% of polymer grades
  • High mold shrinkage — 2%, worse than 81% of polymer grades
  • Degrades in UV without stabilisers — 25/100, worse than 76% of polymer grades

mLLDPE NAT-C6 properties

Typical room-temperature values for mLLDPE NAT-C6; 10 are specific to this condition. Other listed values are mLLDPE reference data and may not represent this condition. Bars are the position among polymer grades.

Physical7

mLLDPE NAT-C6 has a density of 0.92 g/cm³ (0.0332 lb/in³), lighter than 80% of polymer grades. Its glass-transition temperature is -120°C (-184 °F).

Density0.92 g/cm³0.03 lb/in³
Melting Temperature (Tm)120°C248 °F
Glass Transition (Tg)-120°C-184 °F
Water Absorption (24 h)0.01%
Water Absorption (Saturation)0.02%
Refractive Index1.51
Light Transmission90%

Mechanical12

mLLDPE NAT-C6 has a yield strength of 10 MPa (1.45 ksi) and a tensile strength of 30 MPa (4.35 ksi) — weaker than 91% of polymer grades. Elongation at break is 750% and the elastic modulus is 0.25 GPa (0.0363 Msi).

Elastic (Young's) Modulus0.25 GPa0.04 Msi
Shear Modulus0.09 GPa0.01 Msi
Bulk Modulus2 GPa0.26 Msi
Poisson's Ratio0.45
Tensile Strength (Ultimate)30 MPa4.4 ksi
Yield Strength (0.2% offset)10 MPa1.5 ksi
Elongation at Break750%
Flexural Modulus0.28 GPa0.04 Msi
Fracture Toughness (K_IC)2 MPa·√m1.8 ksi·√in
Izod Impact, Notched850 J/m15.9 ft·lbf/in
Hardness, Shore A92 Shore A
Hardness, Shore D48 Shore D

Thermal11

mLLDPE NAT-C6 is rated for continuous service to 75°C (167 °F). It conducts heat at 0.33 W/m·K (0.191 BTU/hr·ft·°F), better than 89% of polymer grades. Thermal expansion is 180 µm/m·K (100 µin/in·°F).

Thermal Conductivity0.33 W/m·K0.19 BTU/hr·ft·°F
Specific Heat Capacity2,100 J/kg·K0.5 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)180 µm/m·K100 µin/in·°F
Max Service Temperature (continuous)75°C167 °F
Min Service Temperature-70°C-94 °F
Heat Deflection Temp. @ 0.45 MPa55°C131 °F
Heat Deflection Temp. @ 1.8 MPa35°C95 °F
Vicat Softening Point (B50)98°C208 °F
Flammability (UL 94)HB (burns; no self-extinguishing rating without FR additives)
Limiting Oxygen Index18%
Max Service Temperature (short-term)95°C203 °F

Electrical7

mLLDPE NAT-C6 is an electrical insulator with a dielectric strength of 28 kV/mm (711.2 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength28 kV/mm711 V/mil
Dielectric Constant (1 MHz)2.3
Dissipation Factor (1 MHz)2×10⁻⁴
Volume Resistivity1×10¹⁶ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 91% of polymer grades. UV resistance is poor.

Corrosion ResistanceExcellent92/100
UV / Weathering ResistancePoor25/100
Chemical Resistance SummaryExcellent against water, acids, alkalis, salts, alcohols and most polar solvents; swells in hot aliphatic/aromatic hydrocarbons and chlorinated solvents above ~60 °C; attacked by strong oxidisers; surfactants and detergents can trigger ESCR failure (mPE grades have markedly better ESCR than ZN-LLDPE).

Sustainability4

Producing a kilogram of mLLDPE NAT-C6 takes about 80 MJ of energy and emits 2 kg of CO₂ — less than 85% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)80 MJ/kg34,394 BTU/lb
Embodied Carbon (primary production)2 kg CO₂/kg
Embodied Water100 L/kg12 gal/lb
Typical Recycled Content0%

Manufacturability8

mLLDPE NAT-C6's machinability is fair (50/100, worse than 73% of polymer grades); weldability excellent (90/100); formability excellent (92/100).

MachinabilityFair50/100
WeldabilityExcellent90/100
Formability (cold)Excellent92/100
PolishabilityPoor30/100
Mold Shrinkage2%
Melt Flow Rate1 g/10 min
Processing Melt Temperature (typ.)205°C401 °F
Mold Temperature (typ.)25°C77 °F

Common Calculations5

Specific Strength (UTS / density)calculated33 kN·m/kg
Specific Stiffness (E / density)calculated0.3 MN·m/kg
Modulus of Resiliencecalculated200 kJ/m³
Thermal Diffusivitycalculated0.2 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with mLLDPE NAT-C6

Is mLLDPE easy to machine?

Rarely machined; if needed use sharp positive-rake tools, high speed and low feed with air cooling — the material is soft, gummy and springs back, so hold generous tolerances.

Can mLLDPE be welded?

Excellent heat sealing, hot-plate, impulse and extrusion welding to other PE; low seal-initiation temperature is a key selling point; no solvent bonding and adhesives need corona/flame surface treatment.

Can mLLDPE be formed, bent or molded?

Mainly blown/cast film — narrow MWD gives high extruder pressure and melt-fracture risk, so use a PPA, wider die gaps and grooved-feed or high-torque screws; also rotomoulded (powder) and injection moulded at 190–235 °C with cold tooling.

What surface finishes work on mLLDPE?

Non-polar surface: corona or flame treat to 38–42 dyn/cm before printing, laminating or coating; no plating; pigmenting via masterbatch.

mLLDPE chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
1-hexene or 1-octene comonomershort-chain branching from single-site metallocene catalyst; sets density/Tm3 – 128
antioxidant / process stabiliserhindered phenol + phosphite0.05 – 0.30.15
slip & antiblock additiveserucamide + silica/talc, film grades only0 – 0.50.2
polymer processing aid (fluoroelastomer)reduces melt fracture typical of narrow-MWD mPE0 – 0.10.05
ethylene (repeat unit)backbone monomer≥ 88 (balance)—

mLLDPE NAT-C6 — frequently asked

What is mLLDPE NAT-C6 used for?

mLLDPE NAT-C6 is typically used for high-performance stretch film, heavy-duty shipping sacks, multilayer food packaging film and agricultural film. In short: toughest LLDPE film resin; low seal-initiation temperature; narrow-MWD metallocene grade.

What is the yield strength of mLLDPE NAT-C6?

mLLDPE NAT-C6 has a typical yield strength of 10 MPa (1.45 ksi) and a tensile strength of 30 MPa (4.35 ksi) — weaker than 91% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is mLLDPE NAT-C6 easy to machine?

Reasonably — machinability is rated fair (50/100, worse than 73% of polymer grades). Rarely machined; if needed use sharp positive-rake tools, high speed and low feed with air cooling — the material is soft, gummy and springs back, so hold generous tolerances.

Can mLLDPE NAT-C6 be welded?

Yes — weldability is rated excellent (90/100). Excellent heat sealing, hot-plate, impulse and extrusion welding to other PE; low seal-initiation temperature is a key selling point; no solvent bonding and adhesives need corona/flame surface treatment.

What surface finishes work on mLLDPE NAT-C6?

Non-polar surface: corona or flame treat to 38–42 dyn/cm before printing, laminating or coating; no plating; pigmenting via masterbatch.

Can mLLDPE NAT-C6 be formed, bent or molded?

Mainly blown/cast film — narrow MWD gives high extruder pressure and melt-fracture risk, so use a PPA, wider die gaps and grooved-feed or high-torque screws; also rotomoulded (powder) and injection moulded at 190–235 °C with cold tooling.

What is the maximum service temperature of mLLDPE NAT-C6?

mLLDPE NAT-C6 is rated for continuous use to about 75°C (167 °F), and briefly to 95°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between mLLDPE NAT-C6 and mLLDPE ROTO?

NAT-C6 is the default condition — standard high-clarity blown-film mLLDPE for stretch/collation and packaging film; best balance of price and toughness. ROTO: heat-stabilised, ground-powder mLLDPE for tanks and containers where impact at low temperature and ESCR matter. Yield strength is 10 MPa in NAT-C6 versus 17 MPa in ROTO.

Sources

  1. ASTM D1248 — Standard Specification for Polyethylene Plastics Extrusion Materials — ASTM International (2016)
  2. ISO 1872-1 — Plastics: Polyethylene (PE) moulding and extrusion materials, designation system — ISO (2023)
  3. ASTM D1238 — Melt Flow Rates of Thermoplastics by Extrusion Plastometer — ASTM International (2023)
  4. Exceed / Enable metallocene PE film resin datasheets — ExxonMobil Chemical (2023)
  5. ELITE enhanced polyethylene and AFFINITY polyolefin plastomer datasheets — Dow (2023)
  6. CAMPUS / plastics property database — LLDPE film and injection grades — CWFG / CAMPUS consortium (2024)
  7. ASM Engineered Materials Handbook, Vol. 2: Engineering Plastics — ASM International (1988)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.