FabDigitFabDigit

ECO PEROX

Additive grade

also Hydrin

PEROX = peroxide-cured GECO compound

Pick for static seals needing low compression set and no lead/thiourea cure residues.

High cost $$$$

Values for the PEROX condition

Other ECO grades and fills

ECO is listed in 9 conditions; see the grade overview at ECO.

Compare all 9 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Shore A 50
Soft diaphragms, bellows and low-clamp-force gaskets.—940012 Shore D
Conductive / antistatic grade
Choose for fuel hose liners that must dissipate static charge per SAE J30/J2260 requirements.—1022023 Shore D
GECO / ETER
Use where sulfur or peroxide cure, lower compression set and the best low-temperature flexibility are required.—1128018 Shore D
Shore A 60
Hose inner liners and flexible fuel-system components.—1132016 Shore D
PEROXThis page
Peroxide-cured GECO compound
Pick for static seals needing low compression set and no lead/thiourea cure residues.—1123022 Shore D
ECO-CODefault
ECO
Standard choice for fuel and vacuum hose, diaphragms and seals needing oil resistance plus −40 °C flexibility.—1225022 Shore D
Shore A 70
Default seal/O-ring and hose hardness; best balance of strength and set.—1225022 Shore D
Epichlorohydrin homopolymer
Pick when the lowest gas/fuel permeability and best hydrocarbon resistance matter more than cold flexibility.—1322022 Shore D
Shore A 80
Higher-pressure seals, backup rings and stiff mount elements.—1318030 Shore D

What is ECO PEROX?

ECO PEROX is ECO in the PEROX grade — pick for static seals needing low compression set and no lead/thiourea cure residues. ECO PEROX has a tensile strength of 11 MPa (1.6 ksi), weaker than 78% of polymer grades. Elongation at break is 230% and the elastic modulus is 0.01 GPa (0.001 Msi). ECO PEROX has a density of 1.36 g/cm³ (0.0491 lb/in³), heavier than 75% of polymer grades. Its glass-transition temperature is -40°C (-40 °F). ECO-CO is the default condition FabDigit quotes; PEROX is available on request or by drawing note.

Advantages

  • Good UV / weathering resistance — 88/100, better than 90% of polymer grades
  • Forms and bends easily — 88/100, better than 85% of polymer grades
  • Ductile — tolerates forming and impact — 230%, better than 77% of polymer grades
  • High service temperature — 135°C (275 °F), better than 75% of polymer grades

Limitations

  • Difficult to machine — 25/100, worse than 93% of polymer grades
  • Absorbs moisture — dry before molding — 1.5%, worse than 91% of polymer grades
  • Difficult to weld — 5/100, worse than 89% of polymer grades
  • High mold shrinkage — 2.2%, worse than 87% of polymer grades
  • Low stiffness — 0.01 GPa (0.001 Msi), worse than 84% of polymer grades

ECO PEROX properties

Typical room-temperature values for ECO PEROX; 17 are specific to this condition. Other listed values are ECO reference data and may not represent this condition. Bars are the position among polymer grades.

Physical4

ECO PEROX has a density of 1.36 g/cm³ (0.0491 lb/in³), heavier than 75% of polymer grades. Its glass-transition temperature is -40°C (-40 °F).

Density1.36 g/cm³0.05 lb/in³
Glass Transition (Tg)-40°C-40 °F
Water Absorption (24 h)1.5%
Water Absorption (Saturation)5%

Mechanical8

ECO PEROX has a tensile strength of 11 MPa (1.6 ksi), weaker than 78% of polymer grades. Elongation at break is 230% and the elastic modulus is 0.01 GPa (0.001 Msi).

Elastic (Young's) Modulus0.01 GPa0 Msi
Poisson's Ratio0.5
Tensile Strength (Ultimate)11 MPa1.6 ksi
Elongation at Break230%
Hardness, Shore A70 Shore A
Hardness, Shore D22 Shore D
Tear Strength22 kN/m126 lbf/in
Compression Set (22 h, 70 °C)18%

Thermal8

ECO PEROX is rated for continuous service to 135°C (275 °F). It conducts heat at 0.22 W/m·K (0.127 BTU/hr·ft·°F), better than 60% of polymer grades. Thermal expansion is 180 µm/m·K (100 µin/in·°F).

Thermal Conductivity0.22 W/m·K0.13 BTU/hr·ft·°F
Specific Heat Capacity1,600 J/kg·K0.38 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)180 µm/m·K100 µin/in·°F
Max Service Temperature (continuous)135°C275 °F
Min Service Temperature-40°C-40 °F
Flammability (UL 94)Typically HB; chlorine content gives partial self-extinguishing behaviour, but HCl/smoke evolved on burning
Limiting Oxygen Index25%
Max Service Temperature (short-term)150°C302 °F

Electrical4

ECO PEROX is an electrical insulator with a dielectric strength of 16 kV/mm (406.4 V/mil) and a resistivity of 1×10⁸ Ω·m.

Electrical Resistivity1×10⁸ Ω·m3.94×10¹⁵ µΩ·in
Dielectric Strength16 kV/mm406 V/mil
Dielectric Constant (1 MHz)8
Volume Resistivity1×10¹⁰ Ω·cm

Chemical & Environmental3

Corrosion resistance is very good (84/100), better than 58% of polymer grades. UV resistance is excellent.

Corrosion ResistanceVery good84/100
UV / Weathering ResistanceExcellent88/100
Chemical Resistance SummaryExcellent in gasoline, gasohol, diesel, mineral and ATF oils, ozone and weathering; very low fuel/gas permeability. Fair in hot air to ~125 °C. Poor in ketones, esters, chlorinated solvents, brake fluid, strong bases (dehydrochlorination) and superheated steam.

Sustainability3

Producing a kilogram of ECO PEROX takes about 115 MJ of energy and emits 4.8 kg of CO₂ — more than 70% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)115 MJ/kg49,441 BTU/lb
Embodied Carbon (primary production)4.8 kg CO₂/kg
Typical Recycled Content0%

Manufacturability5

ECO PEROX's machinability is poor (25/100, worse than 93% of polymer grades); weldability not recommended (5/100); formability excellent (88/100).

MachinabilityPoor25/100
WeldabilityNot recommended5/100
Formability (cold)Excellent88/100
Mold Shrinkage2.2%
Mold Temperature (typ.)170°C338 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ECO PEROX

Is ECO easy to machine?

Cured ECO is best die-cut, water-jet or cryo-deflashed; grinding/turning needs sharp tools and freezing to avoid tearing and smearing.

Can ECO be welded?

Not weldable as a thermoset; joints are made by adhesive bonding (cyanoacrylate/epoxy on chlorinated-primer or plasma-treated surfaces) or by co-vulcanization during molding.

Can ECO be formed, bent or molded?

Mills and extrudes easily but is tacky and scorch-sensitive; compression/injection cure at 160–190 °C with an MgO-type acid acceptor, and post-cure 2–4 h at 150 °C for lowest compression set.

What surface finishes work on ECO?

Usually used as-molded in black; surfaces can be talc- or PTFE-dusted, plasma- or chlorine-treated for low friction, and adhesion to brass/steel inserts is achieved with standard rubber-to-metal bonding agents.

ECO chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
epichlorohydrin (ECH) unitschlorine-bearing repeat unit; ~30–38 wt% Cl in CO homopolymer55 – 7568
ethylene oxide (EO) unitsraises low-temperature flexibility, absent in CO homopolymer25 – 4532
allyl glycidyl ether (AGE)cure-site monomer, present only in GECO/ETER terpolymer0 – 80
carbon black (N550/N774)phr in a typical 70 Shore A compound30 – 7050
plasticizer / process oil (ether-ester tphr0 – 208
acid acceptor (MgO / hydrotalcite) + curphr; acid acceptor essential to trap evolved HCl3 – 106

ECO PEROX — frequently asked

What is ECO PEROX used for?

ECO PEROX is typically used for fuel hoses, vacuum hoses, automotive seals and low-temp gaskets. In short: fuel resistance to -40 °C; inherently antistatic elastomer; low permeability to fuels.

What is the tensile strength of ECO PEROX?

ECO PEROX has a typical tensile strength of 11 MPa (1.6 ksi) — weaker than 78% of polymer grades. Strength varies by condition: see the 9 listed tempers.

Is ECO PEROX easy to machine?

Not especially — machinability is rated poor (25/100, worse than 93% of polymer grades). Cured ECO is best die-cut, water-jet or cryo-deflashed; grinding/turning needs sharp tools and freezing to avoid tearing and smearing.

Can ECO PEROX be welded?

Not readily — weldability is rated not recommended (5/100). Not weldable as a thermoset; joints are made by adhesive bonding (cyanoacrylate/epoxy on chlorinated-primer or plasma-treated surfaces) or by co-vulcanization during molding.

What surface finishes work on ECO PEROX?

Usually used as-molded in black; surfaces can be talc- or PTFE-dusted, plasma- or chlorine-treated for low friction, and adhesion to brass/steel inserts is achieved with standard rubber-to-metal bonding agents.

Can ECO PEROX be formed, bent or molded?

Mills and extrudes easily but is tacky and scorch-sensitive; compression/injection cure at 160–190 °C with an MgO-type acid acceptor, and post-cure 2–4 h at 150 °C for lowest compression set.

What is the maximum service temperature of ECO PEROX?

ECO PEROX is rated for continuous use to about 135°C (275 °F), and briefly to 150°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Hydrin CO/ECO/ETER epichlorohydrin elastomer technical bulletins — Zeon Chemicals (2021)
  2. Engineered Materials Handbook Vol.2: Engineering Plastics / Rubber Products Manufacturing Technology — ASM International (1988)
  3. ASTM D2000 — Classification System for Rubber Products in Automotive Applications (type/class CH, CE) — ASTM (2020)
  4. ISO 1629 — Rubber and latices: nomenclature (CO, ECO, GECO) — ISO (2013)
  5. SAE J30 / SAE J2260 — Fuel and vapour hose requirements — SAE International (2018)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.