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ZERODUR M

Heat-treated state

also Schott ZERODUR, Astronomical Mirror Glass

M = thermomechanically controlled processed

Shorter ceramization route giving lower cost and shorter lead time at somewhat wider CTE tolerance — for large mirror substrates and mounts.

Standard cost $$

Values for the M condition

Other ZERODUR tempers and conditions

ZERODUR is listed in 6 conditions; see the grade overview at ZERODUR.

Compare all 6 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
standard ceramized & fine-annealed ZERODUR, Expansion Class 2
Default commercial delivery state: ceramized, fine-annealed blank with CTE 0 ± 0.10 ×10⁻⁶/K — use for general precision optics and mechanical metrology parts.—30—620 HV1 W/m·K
Expansion Class 1
Tighter-CTE selection for telescope mirror blanks and stable structures where thermal drift budget is a few nanometres.—30—620 HV1 W/m·K
Expansion Class 0
Premium selected class for EUV lithography optics, ring-laser gyros and length standards; long ceramization/selection cycle raises price and lead time.—30—620 HV1 W/m·K
Expansion Class 0 EXTREME
Highest-specification tolerance class, reserved for EUV mask blanks and ultra-stable metrology where CTE must be near-perfectly zero.—30—620 HV1 W/m·K
MThis page
Thermomechanically controlled processed
Shorter ceramization route giving lower cost and shorter lead time at somewhat wider CTE tolerance — for large mirror substrates and mounts.—300620 HV1 W/m·K
ZERODUR K20
Companion glass-ceramic with a deliberate small positive CTE, chosen to CTE-match metals/coatings or as a lower-cost mechanically similar substrate.—30—620 HV2 W/m·K

What is ZERODUR M?

ZERODUR M is ZERODUR heat treated to M — shorter ceramization route giving lower cost and shorter lead time at somewhat wider CTE tolerance — for large mirror substrates and mounts. ZERODUR M has a tensile strength of 30 MPa (4.35 ksi), weaker than 80% of glass grades. The elastic modulus is 90 GPa (13.1 Msi). ZERODUR M has a density of 2.53 g/cm³ (0.0914 lb/in³), lighter than 66% of glass grades. Annealed Glass is the default condition FabDigit quotes; M is available on request or by drawing note.

Advantages

  • Tough — resists crack growth — 0.9 MPa·√m (0.819 ksi·√in), better than 79% of glass grades
  • Stiff — 90 GPa (13.1 Msi), better than 75% of glass grades

ZERODUR M properties

Typical room-temperature values for ZERODUR M; 15 are specific to this condition. Other listed values are ZERODUR reference data and may not represent this condition. Bars are the position among glass grades.

Physical4

ZERODUR M has a density of 2.53 g/cm³ (0.0914 lb/in³), lighter than 66% of glass grades.

Density2.53 g/cm³0.09 lb/in³
Refractive Index1.542
Light Transmission88%
Porosity0%

Mechanical11

ZERODUR M has a tensile strength of 30 MPa (4.35 ksi), weaker than 80% of glass grades. The elastic modulus is 90 GPa (13.1 Msi).

Elastic (Young's) Modulus90 GPa13.1 Msi
Shear Modulus36.3 GPa5.3 Msi
Bulk Modulus59 GPa8.5 Msi
Poisson's Ratio0.24
Tensile Strength (Ultimate)30 MPa4.4 ksi
Compressive Strength500 MPa72.5 ksi
Flexural Strength50 MPa7.3 ksi
Fracture Toughness (K_IC)0.9 MPa·√m0.82 ksi·√in
Hardness, Vickers620 HV
Hardness, Knoop620 HK
Hardness, Mohs6.2

Thermal5

ZERODUR M is rated for continuous service to 500°C (932 °F). It conducts heat at 1.5 W/m·K (0.844 BTU/hr·ft·°F), better than 59% of glass grades. Thermal expansion is 0 µm/m·K (0 µin/in·°F).

Thermal Conductivity1.5 W/m·K0.84 BTU/hr·ft·°F
Specific Heat Capacity800 J/kg·K0.19 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)0 µm/m·K0 µin/in·°F
Max Service Temperature (continuous)500°C932 °F
Min Service Temperature-270°C-454 °F

Electrical5

ZERODUR M is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)7.4
Dissipation Factor (1 MHz)0.0035
Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (85/100), better than 65% of glass grades.

Corrosion ResistanceExcellent85/100
Chemical Resistance SummaryVery good resistance to water, humidity and neutral/organic media (hydrolytic class 1-type behaviour); attacked by hydrofluoric acid, hot concentrated alkalis and phosphoric acid; mild etching/staining possible in strong mineral acids during long polishing cycles.

Sustainability4

Producing a kilogram of ZERODUR M takes about 90 MJ of energy and emits 6.5 kg of CO₂ — more than 66% of glass grades. Typical recycled content is 0%.

Embodied Energy (primary production)90 MJ/kg38,693 BTU/lb
Embodied Carbon (primary production)6.5 kg CO₂/kg
Embodied Water150 L/kg18 gal/lb
Typical Recycled Content0%

Manufacturability3

ZERODUR M's machinability is poor (20/100, better than 56% of glass grades).

MachinabilityPoor20/100
PolishabilityExcellent96/100
Sintering / Firing Temperature850°C1,562 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ZERODUR M

Is ZERODUR easy to machine?

Diamond grinding, core drilling, lapping and ultrasonic machining only — no conventional cutting; keep coolant flooded and avoid edge chipping, then acid-etch or fine-grind to remove subsurface damage.

Can ZERODUR be welded?

Not weldable; parts are joined by optical contacting, low-stress epoxy/silicate bonding, frit bonding or Invar/steel flexure mounts.

Can ZERODUR be formed, bent or molded?

Supplied as cast, ceramized blanks; near-net shapes (lightweighted honeycomb mirrors) are produced by machining the blank, not by hot forming, since re-heating above ~600 °C alters the crystal phase and CTE.

What surface finishes work on ZERODUR?

Polishes to sub-nanometre rms and accepts ion-beam figuring plus Al/Ag/dielectric and multilayer coatings; a light etch after grinding recovers much of the bending strength.

ZERODUR chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
SiO2network former54 – 5855.5
Al2O324 – 2625.3
P2O56.5 – 8.57.5
Li2Oforms high-quartz solid solution crystals3 – 4.53.7
TiO2nucleating agent2 – 2.62.3
ZrO2nucleating agent1.5 – 2.21.9
ZnO1 – 1.81.4
MgO0.5 – 1.51
Na2O0.2 – 0.80.5
K2O0 – 0.80.5
As2O3fining agent in classic composition; arsenic-free melts also offered0 – 0.60.4

ZERODUR M — frequently asked

What is ZERODUR M used for?

ZERODUR M is typically used for telescope mirror blanks, astronomical optics, lightweighted honeycomb mirror substrates, metrology reference plates and straightedges, ring laser gyroscope bodies and lithography stages and mask blanks. In short: zero-expansion glass-ceramic.

What is the tensile strength of ZERODUR M?

ZERODUR M has a typical tensile strength of 30 MPa (4.35 ksi) — weaker than 80% of glass grades. Strength varies by condition: see the 6 listed tempers.

Is ZERODUR M easy to machine?

Not especially — machinability is rated poor (20/100, better than 56% of glass grades). Diamond grinding, core drilling, lapping and ultrasonic machining only — no conventional cutting; keep coolant flooded and avoid edge chipping, then acid-etch or fine-grind to remove subsurface damage.

Can ZERODUR M be welded?

Not weldable; parts are joined by optical contacting, low-stress epoxy/silicate bonding, frit bonding or Invar/steel flexure mounts.

What surface finishes work on ZERODUR M?

Polishes to sub-nanometre rms and accepts ion-beam figuring plus Al/Ag/dielectric and multilayer coatings; a light etch after grinding recovers much of the bending strength.

Can ZERODUR M be formed, bent or molded?

Supplied as cast, ceramized blanks; near-net shapes (lightweighted honeycomb mirrors) are produced by machining the blank, not by hot forming, since re-heating above ~600 °C alters the crystal phase and CTE.

What is the maximum service temperature of ZERODUR M?

ZERODUR M is rated for continuous use to about 500°C (932 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ZERODUR — Zero Expansion Glass Ceramic, technical data — SCHOTT AG (2023)
  2. Strength of ZERODUR (TIE-33 / strength brochure) — SCHOTT AG (2021)
  3. ASM Engineered Materials Handbook Vol. 4: Ceramics and Glasses — ASM International (1991)
  4. Glass-ceramic property compilations (LAS system) — MatWeb / Ceramic Industry data (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.