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PBO (Zylon) UD-EP

Matrix

also Zylon

UD-EP = unidirectional PBO/epoxy laminate

PBO-reinforced epoxy prepreg/laminate for lightweight pressure-vessel overwrap, stiffeners and impact structures; excellent tensile properties but very low compressive and off-axis strength.

High cost $$$$

Values for the UD-EP condition

Other PBO (Zylon) grades and fills

PBO (Zylon) is listed in 3 conditions; see the grade overview at PBO (Zylon).

Compare all 3 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
UD-EPThis page
Unidirectional PBO/epoxy laminate
PBO-reinforced epoxy prepreg/laminate for lightweight pressure-vessel overwrap, stiffeners and impact structures; excellent tensile properties but very low compressive and off-axis strength.—2,6001.8—
Woven PBO fabric / ballistic and cut-resistant cloth
Plain or basket-weave fabric from AS yarn for soft armour, blast blankets, welding curtains and heat-resistant conveyor covers; fabric strengths are per-yarn values derated by crimp.—3,5004—
High-modulus heat-treated PBO filament yarn
Heat-treated yarn with ~50 % higher modulus and lower moisture regain; pick it for stiffness-critical composites, tethers, tension members and dimensionally stable structures.—5,8002.5—

What is PBO (Zylon) UD-EP?

PBO (Zylon) UD-EP is PBO (Zylon) in the UD-EP condition — pBO-reinforced epoxy prepreg/laminate for lightweight pressure-vessel overwrap, stiffeners and impact structures; excellent tensile properties but very low compressive and off-axis strength. PBO (Zylon) UD-EP has a tensile strength of 2,600 MPa (377 ksi), stronger than 78% of composite grades. Elongation at break is 1.8% and the elastic modulus is 160 GPa (23.2 Msi). PBO (Zylon) UD-EP has a density of 1.42 g/cm³ (0.0513 lb/in³), lighter than 63% of composite grades. Its glass-transition temperature is 500°C (932 °F).

Limitations

  • Degrades in UV without stabilisers — 12/100, worse than 100% of composite grades
  • Absorbs moisture — dry before molding — 2%, worse than 88% of composite grades
  • Difficult to machine — 18/100, worse than 80% of composite grades
  • High embodied carbon — 30 kg CO₂/kg, worse than 80% of composite grades

PBO (Zylon) UD-EP properties

Typical room-temperature values for PBO (Zylon) UD-EP; 11 are specific to this condition. Other listed values are PBO (Zylon) reference data and may not represent this condition. Bars are the position among composite grades.

Physical4

PBO (Zylon) UD-EP has a density of 1.42 g/cm³ (0.0513 lb/in³), lighter than 63% of composite grades. Its glass-transition temperature is 500°C (932 °F).

Density1.42 g/cm³0.05 lb/in³
Glass Transition (Tg)500°C932 °F
Water Absorption (24 h)2%
Water Absorption (Saturation)2.5%

Mechanical4

PBO (Zylon) UD-EP has a tensile strength of 2,600 MPa (377 ksi), stronger than 78% of composite grades. Elongation at break is 1.8% and the elastic modulus is 160 GPa (23.2 Msi).

Elastic (Young's) Modulus160 GPa23.2 Msi
Tensile Strength (Ultimate)2,600 MPa377 ksi
Elongation at Break1.8%
Compressive Strength220 MPa31.9 ksi

Thermal7

PBO (Zylon) UD-EP is rated for continuous service to 130°C (266 °F). Thermal expansion is -4 µm/m·K (-2.22 µin/in·°F).

Specific Heat Capacity1,200 J/kg·K0.29 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)-4 µm/m·K-2.2 µin/in·°F
Max Service Temperature (continuous)130°C266 °F
Min Service Temperature-196°C-321 °F
Flammability (UL 94)V-0 equivalent behaviour; fabric does not sustain burning in air (LOI ≈68 %)
Limiting Oxygen Index68%
Max Service Temperature (short-term)550°C1,022 °F

Electrical1

Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental3

Corrosion resistance is very good (70/100), worse than 64% of composite grades. UV resistance is not recommended.

Corrosion ResistanceVery good70/100
UV / Weathering ResistanceNot recommended12/100
Chemical Resistance SummaryExcellent against organic solvents, fuels and most alkalis; resistant to abrasion and cut. Degraded by concentrated sulfuric/nitric/methanesulfonic acids, by prolonged UV/visible light, and by hydrolysis in hot humid environments (strength loss over months of service).

Sustainability3

Producing a kilogram of PBO (Zylon) UD-EP takes about 500 MJ of energy and emits 30 kg of CO₂ — more than 84% of composite grades. Typical recycled content is 0%.

Embodied Energy (primary production)500 MJ/kg214,962 BTU/lb
Embodied Carbon (primary production)30 kg CO₂/kg
Typical Recycled Content0%

Manufacturability1

PBO (Zylon) UD-EP's machinability is poor (18/100, worse than 80% of composite grades).

MachinabilityPoor18/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PBO (Zylon) UD-EP

Is PBO (Zylon) easy to machine?

Fabric and laminates cannot be sheared cleanly — use hot knife, ultrasonic cutter, waterjet or new carbide/PCD tooling; fibers fuzz and blunt tools quickly.

Can PBO (Zylon) be welded?

Not weldable; join by stitching with PBO/aramid thread, mechanical clamping or adhesive bonding of the composite laminate.

Can PBO (Zylon) be formed, bent or molded?

Processed as continuous yarn — weaving, braiding, filament winding or prepreg lay-up with epoxy/phenolic; cure below ~180 °C and avoid moisture pick-up before cure.

What surface finishes work on PBO (Zylon)?

Surface treatment (plasma, epoxy sizing) needed for resin adhesion; protect all exposed parts with UV-opaque covers, coatings or outer fabric layers to limit light and humidity aging.

PBO (Zylon) chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
residual phosphorus (from PPA solvent)Residual acid content is a key driver of hydrolytic aging0.05 – 0.60.3
finish / sizingSpin finish on yarn surface0.2 – 10.5
poly(p-phenylene-2,6-benzobisoxazole) reRigid-rod heterocyclic polymer; monomers 4,6-diaminoresorcinol dihydrochloride + terephthalic acid, dry-jet wet spun from polyphosphoric acidbalance—

PBO (Zylon) UD-EP — frequently asked

What is PBO (Zylon) UD-EP used for?

PBO (Zylon) UD-EP is typically used for high-performance ballistic armor, aerospace tethers/cables, sporting goods and reinforcement for extreme-performance composites. In short: strongest organic fiber; higher modulus than aramid; light and humidity sensitive.

What is the tensile strength of PBO (Zylon) UD-EP?

PBO (Zylon) UD-EP has a typical tensile strength of 2,600 MPa (377 ksi) — stronger than 78% of composite grades. Strength varies by condition: see the 3 listed tempers.

Is PBO (Zylon) UD-EP easy to machine?

Not especially — machinability is rated poor (18/100, worse than 80% of composite grades). Fabric and laminates cannot be sheared cleanly — use hot knife, ultrasonic cutter, waterjet or new carbide/PCD tooling; fibers fuzz and blunt tools quickly.

Can PBO (Zylon) UD-EP be welded?

Not weldable; join by stitching with PBO/aramid thread, mechanical clamping or adhesive bonding of the composite laminate.

What surface finishes work on PBO (Zylon) UD-EP?

Surface treatment (plasma, epoxy sizing) needed for resin adhesion; protect all exposed parts with UV-opaque covers, coatings or outer fabric layers to limit light and humidity aging.

Can PBO (Zylon) UD-EP be formed, bent or molded?

Processed as continuous yarn — weaving, braiding, filament winding or prepreg lay-up with epoxy/phenolic; cure below ~180 °C and avoid moisture pick-up before cure.

What is the maximum service temperature of PBO (Zylon) UD-EP?

PBO (Zylon) UD-EP is rated for continuous use to about 130°C (266 °F), and briefly to 550°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Zylon (PBO fiber) Technical Information — Toyobo Co., Ltd. (2020)
  2. ASM Handbook Vol. 21: Composites — High-performance organic fibers — ASM International (2001)
  3. NIJ/NIST studies on aging of PBO body-armor fiber — NIST (2005)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.