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Steel P21 Nitrided

Finish state

AISI/SAE P21 · UNS T51621

Choose for abrasive glass- or mineral-filled resins where cavity wear, not core strength, governs life.

Premium cost $$$

Values for the Nitrided condition

Other P21 tempers and conditions

P21 is listed in 5 conditions; see the grade overview at P21.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
soft annealed for machining/forming stock
Softest supply state for heavy stock removal or re-forging before solution + aging.48072022220 HB—
Solution annealed
Pick when the cavity is to be fully machined soft and then age-hardened with near-zero distortion.7409501830 HRC—
Pre-hardened (solution treated + aged), as-supplied mold plate
Standard stock condition: machine directly to finished cavity, no further heat treatment or distortion.1,1501,3001440 HRC—
NitridedThis page
aged core with gas/plasma nitrided case
Choose for abrasive glass- or mineral-filled resins where cavity wear, not core strength, governs life.1,1501,3001140 HRC4.9 % IACS
High-hardness aged mirror-polish grade
Slightly harder aged variant for optical/mirror cavities and long-run high-gloss parts.1,2301,3801242 HRC—

What is P21 Nitrided?

P21 Nitrided is P21 supplied in the Nitrided condition — choose for abrasive glass- or mineral-filled resins where cavity wear, not core strength, governs life. P21 Nitrided has a yield strength of 1,150 MPa (167 ksi) and a tensile strength of 1,300 MPa (189 ksi) — stronger than 94% of steel grades. Elongation at break is 11% and the elastic modulus is 205 GPa (29.7 Msi). P21 Nitrided has a density of 7.83 g/cm³ (0.283 lb/in³), lighter than 80% of steel grades. It melts at 1,420°C (2,588 °F). PH 38-42 HRC is the default condition FabDigit quotes; Nitrided is available on request or by drawing note.

Advantages

  • High strength — 1,150 MPa (167 ksi), better than 94% of steel grades
  • Good corrosion resistance — 25/100, better than 92% of steel grades
  • Polishes to a fine finish — 70/100, better than 87% of steel grades
  • High service temperature — 450°C (842 °F), better than 86% of steel grades

Limitations

  • Difficult to machine — 10/100, worse than 99% of steel grades
  • Limited formability — 5/100, worse than 99% of steel grades
  • Difficult to weld — 12/100, worse than 96% of steel grades
  • Limited ductility — 11%, worse than 89% of steel grades
  • Low electrical conductivity — 4.9 % IACS, worse than 82% of steel grades

P21 Nitrided properties

Typical room-temperature values for P21 Nitrided; 23 are specific to this condition. Other listed values are P21 reference data and may not represent this condition. Bars are the position among steel grades.

Physical3

P21 Nitrided has a density of 7.83 g/cm³ (0.283 lb/in³), lighter than 80% of steel grades. It melts at 1,420°C (2,588 °F).

Density7.83 g/cm³0.28 lb/in³
Melting Point (Solidus)1,420°C2,588 °F
Liquidus Temperature1,490°C2,714 °F

Mechanical16

P21 Nitrided has a yield strength of 1,150 MPa (167 ksi) and a tensile strength of 1,300 MPa (189 ksi) — stronger than 94% of steel grades. Elongation at break is 11% and the elastic modulus is 205 GPa (29.7 Msi).

Elastic (Young's) Modulus205 GPa29.7 Msi
Shear Modulus80 GPa11.6 Msi
Bulk Modulus163 GPa23.6 Msi
Poisson's Ratio0.29
Tensile Strength (Ultimate)1,300 MPa189 ksi
Yield Strength (0.2% offset)1,150 MPa167 ksi
Elongation at Break11%
Reduction in Area42%
Compressive Strength1,300 MPa189 ksi
Shear Strength780 MPa113 ksi
Fatigue Strength (Endurance Limit)660 MPa95.7 ksi
Fracture Toughness (K_IC)65 MPa·√m59.2 ksi·√in
Charpy V-Notch Impact (RT)15 J11.1 ft·lbf
Hardness, Brinell375 HB
Hardness, Rockwell C40 HRC
Hardness, Vickers750 HV

Thermal6

P21 Nitrided is rated for continuous service to 450°C (842 °F). It conducts heat at 33 W/m·K (19.1 BTU/hr·ft·°F), worse than 80% of steel grades. Thermal expansion is 12.4 µm/m·K (6.89 µin/in·°F).

Thermal Conductivity33 W/m·K19.1 BTU/hr·ft·°F
Specific Heat Capacity460 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)12.4 µm/m·K6.9 µin/in·°F
Latent Heat of Fusion270 J/g116 BTU/lb
Max Service Temperature (continuous)450°C842 °F
Min Service Temperature-30°C-22 °F

Electrical3

P21 Nitrided conducts electricity at 4.9 % IACS, worse than 82% of steel grades.

Electrical Conductivity4.9 % IACS
Electrical Resistivity3.5×10⁻⁷ Ω·m13.8 µΩ·in
Magnetic Responseferromagnetic

Chemical & Environmental3

Corrosion resistance is poor (25/100), better than 92% of steel grades.

Galvanic Potential (seawater, vs SCE)-0.6 V
Corrosion ResistancePoor25/100
Chemical Resistance SummaryRusts readily in humid air and with condensate; attacked by acidic or chloride-bearing plastics off-gas (PVC, flame-retarded resins). Requires oiling, dehumidified storage, or hard-chrome/PVD coating for corrosive molding.

Sustainability4

Producing a kilogram of P21 Nitrided takes about 34 MJ of energy and emits 2.4 kg of CO₂ — more than 82% of steel grades. Typical recycled content is 30%.

Embodied Energy (primary production)34 MJ/kg14,617 BTU/lb
Embodied Carbon (primary production)2.4 kg CO₂/kg
Embodied Water60 L/kg7.2 gal/lb
Typical Recycled Content30%

Manufacturability8

P21 Nitrided's machinability is not recommended (10/100, worse than 99% of steel grades); weldability not recommended (12/100); formability not recommended (5/100).

MachinabilityNot recommended10/100
Machinability Rating (AISI 1212 = 100 %)8%
WeldabilityNot recommended12/100
Formability (cold)Not recommended5/100
CastabilityFair35/100
Brazeability / SolderabilityFair40/100
PolishabilityVery good70/100
Anodizing Responsen/a — ferrous alloy; use hard chrome, electroless nickel or PVD instead

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with P21 Nitrided

Is P21 easy to machine?

Machines cleanly at 38–42 HRC with coated carbide (rigid setup, moderate feed); machining in the solution-treated state and aging afterwards gives the best surface plus near-zero size change.

Can P21 be welded?

TIG repair with matching Ni-Al or maraging filler, preheat ~200–250 °C, then re-age at ~510–550 °C to restore weld-zone hardness and avoid polish streaks.

Can P21 be formed, bent or molded?

Hot work 1050–850 °C then slow cool/anneal; no cold forming — the alloy is used as machined mold plate.

What surface finishes work on P21?

Excellent diamond polish to mirror (Ra <0.02 µm) and good photo-etch texturing; add hard chrome, electroless Ni or PVD for corrosive or abrasive resins.

P21 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
C0.15 – 0.250.2
Si0.15 – 0.40.3
Mn0.2 – 0.60.35
P≤ 0.03—
Smax; free-machining versions add controlled S≤ 0.03—
Niforms NiAl precipitate with Al3.85 – 4.254
Alage-hardening element1 – 1.31.2
Cr0.1 – 0.350.25
Mooptional, producer dependent0.1 – 0.30.2
Febalance—

P21 Nitrided — frequently asked

What is P21 Nitrided used for?

P21 Nitrided is typically used for precision plastic mold cavities, optical/lens molds and components requiring low distortion after hardening. In short: age-hardening mold steel; low distortion after hardening; mirror-polish cavity grade.

What is the yield strength of P21 Nitrided?

P21 Nitrided has a typical yield strength of 1,150 MPa (167 ksi) and a tensile strength of 1,300 MPa (189 ksi) — stronger than 94% of steel grades. Strength varies by condition: see the 5 listed tempers.

Is P21 Nitrided easy to machine?

Not especially — machinability is rated not recommended (10/100, worse than 99% of steel grades). Machines cleanly at 38–42 HRC with coated carbide (rigid setup, moderate feed); machining in the solution-treated state and aging afterwards gives the best surface plus near-zero size change.

Can P21 Nitrided be welded?

Not readily — weldability is rated not recommended (12/100). TIG repair with matching Ni-Al or maraging filler, preheat ~200–250 °C, then re-age at ~510–550 °C to restore weld-zone hardness and avoid polish streaks.

What surface finishes work on P21 Nitrided?

Excellent diamond polish to mirror (Ra <0.02 µm) and good photo-etch texturing; add hard chrome, electroless Ni or PVD for corrosive or abrasive resins.

Can P21 Nitrided be formed, bent or molded?

Hot work 1050–850 °C then slow cool/anneal; no cold forming — the alloy is used as machined mold plate.

What is the maximum service temperature of P21 Nitrided?

P21 Nitrided is rated for continuous use to about 450°C (842 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between P21 PH 38-42 HRC and P21-ST?

PH 38-42 HRC is the default condition — standard stock condition: machine directly to finished cavity, no further heat treatment or distortion. ST: pick when the cavity is to be fully machined soft and then age-hardened with near-zero distortion. Yield strength is 1,150 MPa in PH 38-42 HRC versus 740 MPa in ST.

Sources

  1. ASM Handbook Vol.1 — Properties and Selection: Irons, Steels, and High-Performance Alloys (mold steels) — ASM International (1990)
  2. ASTM A681 — Alloy Tool Steels (P-type mold steels) — ASTM (2015)
  3. GB/T 1299 / GB/T 1299-2014 — SAC (2014)
  4. Ni-Al age-hardening plastic mold steel datasheets (NAK80/P21-class) — Daido Steel / Baosteel Special Steel (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.