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Refractory Metal Zr 704 CW-SR

Supply condition

UNS R60704 · ASTM B550/B551 Grade 704

CW-SR = cold Worked and Stress Relieved

Choose for tubing, rod and fasteners needing higher strength and better dimensional stability than fully annealed material.

High cost $$$$

Values for the CW-SR condition

Other Zr 704 tempers and conditions

Zr 704 is listed in 4 conditions; see the grade overview at Zr 704.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
AnnealedDefault
recrystallization annealed (mill standard for B550/B551/B523)
Default stocked condition for plate, sheet, bar and tube; best ductility and formability with guaranteed ASTM minimums.3004702288 HRB—
As-welded deposit
Reference condition for design of welded Zr 704 vessels; strength close to base metal but ductility is reduced if shielding is imperfect.30046014192 HB3.4 % IACS
Hot Worked / As-Forged
Pick for heavy forged valve bodies and flanges where section size makes full annealing impractical.32048018185 HB3.4 % IACS
CW-SRThis page
Cold Worked and Stress Relieved
Choose for tubing, rod and fasteners needing higher strength and better dimensional stability than fully annealed material.4806001420 HRC3.3 % IACS

What is Zr 704 CW-SR?

Zr 704 CW-SR is Zr 704 supplied in the CW-SR condition — choose for tubing, rod and fasteners needing higher strength and better dimensional stability than fully annealed material. Zr 704 CW-SR has a yield strength of 480 MPa (69.6 ksi) and a tensile strength of 600 MPa (87 ksi) — stronger than 72% of refractory metal grades. Elongation at break is 14% and the elastic modulus is 99 GPa (14.4 Msi). Zr 704 CW-SR has a density of 6.57 g/cm³ (0.237 lb/in³), lighter than 67% of refractory metal grades. It melts at 1,840°C (3,344 °F). Annealed is the default condition FabDigit quotes; CW-SR is available on request or by drawing note.

Limitations

  • Limited service temperature — 350°C (662 °F), worse than 89% of refractory metal grades
  • Poor heat conductor — 14.6 W/m·K (8.44 BTU/hr·ft·°F), worse than 84% of refractory metal grades
  • Low stiffness — 99 GPa (14.4 Msi), worse than 79% of refractory metal grades
  • High embodied carbon — 95 kg CO₂/kg, worse than 75% of refractory metal grades

Zr 704 CW-SR properties

Typical room-temperature values for Zr 704 CW-SR; 23 are specific to this condition. Other listed values are Zr 704 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Zr 704 CW-SR has a density of 6.57 g/cm³ (0.237 lb/in³), lighter than 67% of refractory metal grades. It melts at 1,840°C (3,344 °F).

Density6.57 g/cm³0.24 lb/in³
Melting Point (Solidus)1,840°C3,344 °F
Liquidus Temperature1,855°C3,371 °F

Mechanical16

Zr 704 CW-SR has a yield strength of 480 MPa (69.6 ksi) and a tensile strength of 600 MPa (87 ksi) — stronger than 72% of refractory metal grades. Elongation at break is 14% and the elastic modulus is 99 GPa (14.4 Msi).

Elastic (Young's) Modulus99 GPa14.4 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus100 GPa14.5 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)600 MPa87 ksi
Yield Strength (0.2% offset)480 MPa69.6 ksi
Elongation at Break14%
Reduction in Area32%
Compressive Strength500 MPa72.5 ksi
Shear Strength365 MPa52.9 ksi
Fatigue Strength (Endurance Limit)280 MPa40.6 ksi
Fracture Toughness (K_IC)45 MPa·√m41 ksi·√in
Charpy V-Notch Impact (RT)25 J18.4 ft·lbf
Hardness, Brinell222 HB
Hardness, Rockwell B98 HRB
Hardness, Vickers235 HV

Thermal6

Zr 704 CW-SR is rated for continuous service to 350°C (662 °F). It conducts heat at 14.6 W/m·K (8.44 BTU/hr·ft·°F), worse than 84% of refractory metal grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity14.6 W/m·K8.4 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion210 J/g90.3 BTU/lb
Max Service Temperature (continuous)350°C662 °F
Min Service Temperature-196°C-321 °F

Electrical3

Zr 704 CW-SR conducts electricity at 3.3 % IACS, worse than 72% of refractory metal grades.

Electrical Conductivity3.3 % IACS
Electrical Resistivity5.2×10⁻⁷ Ω·m20.5 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (90/100), better than 75% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.1 V
Corrosion ResistanceExcellent90/100
Chemical Resistance SummaryExcellent in HCl of all concentrations up to boiling, H2SO4 to ~70%, nitric acid, organic acids, alkalis and molten salts; attacked by HF, ferric/cupric chlorides, wet chlorine and aqua regia.

Sustainability4

Producing a kilogram of Zr 704 CW-SR takes about 1,400 MJ of energy and emits 95 kg of CO₂ — more than 67% of refractory metal grades. Typical recycled content is 20%.

Embodied Energy (primary production)1,400 MJ/kg601,892 BTU/lb
Embodied Carbon (primary production)95 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content20%

Manufacturability8

Zr 704 CW-SR's machinability is fair (35/100, better than 81% of refractory metal grades); weldability very good (70/100); formability fair (35/100).

MachinabilityFair35/100
Machinability Rating (AISI 1212 = 100 %)28%
WeldabilityVery good70/100
Formability (cold)Fair35/100
CastabilityPoor25/100
Brazeability / SolderabilityPoor20/100
PolishabilityGood60/100
Anodizing Responsegood — anodizes to stable coloured oxide films (decorative/wear films), but not a structural coating like Al anodizing

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Zr 704 CW-SR

Is Zr 704 easy to machine?

Use slow speeds, heavy positive-rake sharp carbide tooling and flood coolant; chips are pyrophoric — keep them wet and collect separately.

Can Zr 704 be welded?

GTAW/EBW with high-purity argon, trailing shield and back purge (<20 ppm O2/N2); a bright silver weld is acceptable, white or grey indicates contamination.

Can Zr 704 be formed, bent or molded?

Cold-form on generous radii (≥3–5t) with slow rams; warm forming at 200–400 °C improves bendability, and tools should be lubricated to avoid galling.

What surface finishes work on Zr 704?

Pickle in HNO3–HF to remove oxide and hydride skin after hot work; can be electropolished or anodized for colour, but avoid iron contamination from grinding media.

Zr 704 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Sn1 – 21.5
Fe+Crcombined iron plus chromium0.2 – 0.40.3
Hfhafnium is a natural companion of zirconium≤ 4.52
O≤ 0.180.12
C≤ 0.050.02
N≤ 0.030.01
H≤ 0.010
Zr+Hfbalance zirconium plus hafnium≥ 97.5 (balance)—

Zr 704 CW-SR — frequently asked

What is Zr 704 CW-SR used for?

Zr 704 CW-SR is typically used for process piping, heat exchanger tubing and chemical vessel components. In short: sn-strengthened zirconium; stronger than Zr 702; 400 °C acid-service grade.

What is the yield strength of Zr 704 CW-SR?

Zr 704 CW-SR has a typical yield strength of 480 MPa (69.6 ksi) and a tensile strength of 600 MPa (87 ksi) — stronger than 72% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is Zr 704 CW-SR easy to machine?

Not especially — machinability is rated fair (35/100, better than 81% of refractory metal grades). Use slow speeds, heavy positive-rake sharp carbide tooling and flood coolant; chips are pyrophoric — keep them wet and collect separately.

Can Zr 704 CW-SR be welded?

Yes — weldability is rated very good (70/100). GTAW/EBW with high-purity argon, trailing shield and back purge (<20 ppm O2/N2); a bright silver weld is acceptable, white or grey indicates contamination.

What surface finishes work on Zr 704 CW-SR?

Pickle in HNO3–HF to remove oxide and hydride skin after hot work; can be electropolished or anodized for colour, but avoid iron contamination from grinding media.

Can Zr 704 CW-SR be formed, bent or molded?

Cold-form on generous radii (≥3–5t) with slow rams; warm forming at 200–400 °C improves bendability, and tools should be lubricated to avoid galling.

What is the maximum service temperature of Zr 704 CW-SR?

Zr 704 CW-SR is rated for continuous use to about 350°C (662 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Zr 704 Annealed and Zr 704 CW-SR?

Annealed is the default condition — default stocked condition for plate, sheet, bar and tube; best ductility and formability with guaranteed ASTM minimums. CW-SR: choose for tubing, rod and fasteners needing higher strength and better dimensional stability than fully annealed material. Yield strength is 300 MPa in Annealed versus 480 MPa in CW-SR.

Sources

  1. ASTM B551/B551M — Zirconium and Zirconium Alloy Strip, Sheet and Plate — ASTM International (2019)
  2. ASTM B550/B550M — Zirconium and Zirconium Alloy Bar and Wire — ASTM International (2020)
  3. ASTM B523 / B658 — Zirconium Alloy Seamless and Welded Tube and Pipe — ASTM International (2022)
  4. Zirconium Alloys 702/704/705 technical data — ATI (Wah Chang) (2020)
  5. ASM Handbook Vol.2 — Properties and Selection: Nonferrous Alloys — ASM International (1990)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.