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Refractory Metal TZM As Sintered

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UNS R03640, R03630 · ASTM B387 Grade 363 · also Mo-Ti-Zr

Pressed-and-sintered blank before forging/rolling; residual porosity means low strength and ductility — normally an intermediate product, occasionally sold for crucibles and furnace parts.

Specialty cost $$$$$

Values for the As Sintered condition

Other TZM tempers and conditions

TZM is listed in 5 conditions; see the grade overview at TZM.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
As SinteredThis page
powder-metallurgy blank, unworked
Pressed-and-sintered blank before forging/rolling; residual porosity means low strength and ductility — normally an intermediate product, occasionally sold for crucibles and furnace parts.3504504170 HB27 % IACS
fully recrystallized in vacuum
Choose when maximum dimensional stability and creep resistance above 1400 °C matter more than room-temperature strength; more brittle at RT because DBTT rises.4205602512 HRC126 W/m·K
vacuum arc cast and wrought-worked billet
Vacuum-arc-cast route giving very low interstitial content and coarse grain — preferred for large forged dies and high-temperature creep parts.5607001820 HRC32 % IACS
wrought, stress relieved below recrystallization
Standard stocked condition for rod, plate and forgings — best combination of room-temperature strength, ductility and dimensional stability up to ~1300 °C.7609001526 HRC118 W/m·K
as-swaged / as-rolled, unrecrystallized
Highest room-temperature strength and hardness (thin sheet, wire, small rod); limited ductility and residual stress, not for service above ~1000 °C.9401,050831 HRC29 % IACS

What is TZM As Sintered?

TZM As Sintered is TZM in the As Sintered condition — pressed-and-sintered blank before forging/rolling; residual porosity means low strength and ductility — normally an intermediate product, occasionally sold for crucibles and furnace parts. TZM As Sintered has a yield strength of 350 MPa (50.8 ksi) and a tensile strength of 450 MPa (65.3 ksi) — stronger than 57% of refractory metal grades. Elongation at break is 4% and the elastic modulus is 285 GPa (41.3 Msi). TZM As Sintered has a density of 9.9 g/cm³ (0.358 lb/in³), heavier than 60% of refractory metal grades. It melts at 2,617°C (4,743 °F). Stress Relieved is the default condition FabDigit quotes; As Sintered is available on request or by drawing note.

Advantages

  • Easy to machine — 55/100, better than 101% of refractory metal grades
  • High electrical conductivity — 27 % IACS, better than 80% of refractory metal grades
  • Conducts heat well — 105 W/m·K (60.7 BTU/hr·ft·°F), better than 77% of refractory metal grades
  • Low embodied carbon — 26 kg CO₂/kg, better than 77% of refractory metal grades

Limitations

  • Needs corrosion protection — 42/100, worse than 95% of refractory metal grades
  • Limited formability — 10/100, worse than 86% of refractory metal grades
  • Limited ductility — 4%, worse than 84% of refractory metal grades
  • Low fracture toughness — 13 MPa·√m (11.8 ksi·√in), worse than 82% of refractory metal grades

TZM As Sintered properties

Typical room-temperature values for TZM As Sintered; 23 are specific to this condition. Other listed values are TZM reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

TZM As Sintered has a density of 9.9 g/cm³ (0.358 lb/in³), heavier than 60% of refractory metal grades. It melts at 2,617°C (4,743 °F).

Density9.9 g/cm³0.36 lb/in³
Melting Point (Solidus)2,617°C4,743 °F
Liquidus Temperature2,623°C4,753 °F

Mechanical16

TZM As Sintered has a yield strength of 350 MPa (50.8 ksi) and a tensile strength of 450 MPa (65.3 ksi) — stronger than 57% of refractory metal grades. Elongation at break is 4% and the elastic modulus is 285 GPa (41.3 Msi).

Elastic (Young's) Modulus285 GPa41.3 Msi
Shear Modulus122 GPa17.7 Msi
Bulk Modulus260 GPa37.7 Msi
Poisson's Ratio0.32
Tensile Strength (Ultimate)450 MPa65.3 ksi
Yield Strength (0.2% offset)350 MPa50.8 ksi
Elongation at Break4%
Reduction in Area6%
Compressive Strength550 MPa79.8 ksi
Shear Strength300 MPa43.5 ksi
Fatigue Strength (Endurance Limit)180 MPa26.1 ksi
Fracture Toughness (K_IC)13 MPa·√m11.8 ksi·√in
Charpy V-Notch Impact (RT)3 J2.2 ft·lbf
Hardness, Brinell170 HB
Hardness, Rockwell C26 HRC
Hardness, Vickers180 HV

Thermal6

TZM As Sintered is rated for continuous service to 1,100°C (2,012 °F). It conducts heat at 105 W/m·K (60.7 BTU/hr·ft·°F), better than 77% of refractory metal grades. Thermal expansion is 5.3 µm/m·K (2.94 µin/in·°F).

Thermal Conductivity105 W/m·K60.7 BTU/hr·ft·°F
Specific Heat Capacity272 J/kg·K0.06 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.3 µm/m·K2.9 µin/in·°F
Latent Heat of Fusion390 J/g168 BTU/lb
Max Service Temperature (continuous)1,100°C2,012 °F
Min Service Temperature20°C68 °F

Electrical3

TZM As Sintered conducts electricity at 27 % IACS, better than 80% of refractory metal grades.

Electrical Conductivity27 % IACS
Electrical Resistivity6.4×10⁻⁸ Ω·m2.52 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is fair (42/100), worse than 95% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.2 V
Corrosion ResistanceFair42/100
Chemical Resistance SummaryExcellent in vacuum, hydrogen, inert gas, molten glass and many liquid metals (Li, Na, Bi, Zn); resists HCl, HF and non-oxidizing acids and molten alkali-free glass. Attacked by nitric acid, aqua regia, hot concentrated sulfuric acid, molten alkalis/nitrates and by oxygen — forms volatile MoO₃ above about 500 °C in air.

Sustainability4

Producing a kilogram of TZM As Sintered takes about 380 MJ of energy and emits 26 kg of CO₂ — less than 78% of refractory metal grades. Typical recycled content is 25%.

Embodied Energy (primary production)380 MJ/kg163,371 BTU/lb
Embodied Carbon (primary production)26 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content25%

Manufacturability7

TZM As Sintered's machinability is good (55/100, better than 101% of refractory metal grades); weldability poor (25/100); formability not recommended (10/100).

MachinabilityGood55/100
Machinability Rating (AISI 1212 = 100 %)50%
WeldabilityPoor25/100
Formability (cold)Not recommended10/100
Brazeability / SolderabilityGood65/100
PolishabilityVery good70/100
Anodizing Responsen/a — not anodized; oxidation protection is achieved with Si-Cr-Fe (silicide) or CVD/PVD coatings for air service above 500 °C

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with TZM As Sintered

Is TZM easy to machine?

Machines like a hard, abrasive cast iron — sharp positive-rake carbide or PCD tools, rigid setup, generous coolant, avoid dull edges that cause chipping and subsurface cracks; grinding and EDM work well.

Can TZM be welded?

Fusion welding (EB, laser, GTAW in chamber) recrystallizes and embrittles the joint — prefer vacuum brazing, mechanical fastening or friction/diffusion bonding for structural parts.

Can TZM be formed, bent or molded?

Form warm (200–500 °C, higher for recrystallized stock) to stay above the DBTT; generous bend radii, no sharp cold bends, and stress relieve at 900–1100 °C after heavy work.

What surface finishes work on TZM?

Cannot be anodized; use electropolishing or mechanical polish for clean vacuum surfaces and Si-Cr-Fe silicide, aluminide or CVD coatings when the part must see air above ~500 °C.

TZM chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Ticarbide former, main strengthener0.4 – 0.550.5
Zr0.06 – 0.120.08
Cforms TiC/ZrC dispersoids0.01 – 0.040.03
O≤ 0.03—
N≤ 0—
Fe≤ 0.01—
Ni≤ 0.01—
Si≤ 0.01—
Mobalance, ≥99.2 % with additionsbalance—

TZM As Sintered — frequently asked

What is TZM As Sintered used for?

TZM As Sintered is typically used for rocket nozzles and thrust chamber inserts, hot-work extrusion and forging dies, furnace hot-zone structures and fixtures, die-casting core pins and shot sleeves, isothermal forging tooling and X-ray rotating anode substrates. In short: higher-strength molybdenum alloy.

What is the yield strength of TZM As Sintered?

TZM As Sintered has a typical yield strength of 350 MPa (50.8 ksi) and a tensile strength of 450 MPa (65.3 ksi) — stronger than 57% of refractory metal grades. Strength varies by condition: see the 5 listed tempers.

Is TZM As Sintered easy to machine?

Reasonably — machinability is rated good (55/100, better than 101% of refractory metal grades). Machines like a hard, abrasive cast iron — sharp positive-rake carbide or PCD tools, rigid setup, generous coolant, avoid dull edges that cause chipping and subsurface cracks; grinding and EDM work well.

Can TZM As Sintered be welded?

Not readily — weldability is rated poor (25/100). Fusion welding (EB, laser, GTAW in chamber) recrystallizes and embrittles the joint — prefer vacuum brazing, mechanical fastening or friction/diffusion bonding for structural parts.

What surface finishes work on TZM As Sintered?

Cannot be anodized; use electropolishing or mechanical polish for clean vacuum surfaces and Si-Cr-Fe silicide, aluminide or CVD coatings when the part must see air above ~500 °C.

Can TZM As Sintered be formed, bent or molded?

Form warm (200–500 °C, higher for recrystallized stock) to stay above the DBTT; generous bend radii, no sharp cold bends, and stress relieve at 900–1100 °C after heavy work.

What is the maximum service temperature of TZM As Sintered?

TZM As Sintered is rated for continuous use to about 1,100°C (2,012 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASTM B387 — Molybdenum and Molybdenum Alloy Bar, Rod, and Wire (Type 364 TZM) — ASTM International (2018)
  2. ASTM B386 — Molybdenum and Molybdenum Alloy Plate, Sheet, Strip, Foil — ASTM International (2018)
  3. TZM molybdenum alloy material properties — Plansee SE (2023)
  4. ASM Handbook Vol. 2 — Properties of Refractory Metals and Alloys — ASM International (1990)
  5. Molybdenum and TZM technical data — H.C. Starck Solutions / Ed Fagan Inc. (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.