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Refractory Metal Chromium Alloy 33-AW (As-welded deposit)

Heat-treated state

UNS R20033 · ASTM B615/B616/B617

Property basis for weld joints and weld overlay when no post-weld solution anneal is applied.

High cost $$$$

Values for the AW condition

Other Chromium Alloy 33 tempers and conditions

Chromium Alloy 33 is listed in 5 conditions; see the grade overview at Chromium Alloy 33.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Forged then solution annealed
Heavy sections and pressure fittings supplied to ASTM B564/B462-type requirements.41578045195 HB1.7 % IACS
SADefault
Solution annealed
Standard stocked condition for plate, sheet, bar, pipe and tube; maximum corrosion resistance and ductility.43081050200 HB—
Cold rolled and solution annealed sheet/strip
Thin sheet and strip for vessel linings, plate heat exchangers and bellows where surface finish matters.45083045210 HB1.7 % IACS
AWThis page
As-welded deposit
Property basis for weld joints and weld overlay when no post-weld solution anneal is applied.4607603518 HRC1.6 % IACS
Cold worked
Choose when higher proof strength and close dimensional tolerance are needed, e.g. fasteners and pump shafts.7209802528 HRC—

What is Chromium Alloy 33-AW?

Chromium Alloy 33-AW is Chromium Alloy 33 heat treated to AW — property basis for weld joints and weld overlay when no post-weld solution anneal is applied. Chromium Alloy 33-AW has a yield strength of 460 MPa (66.7 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 70% of refractory metal grades. Elongation at break is 35% and the elastic modulus is 200 GPa (29 Msi). Chromium Alloy 33-AW has a density of 7.9 g/cm³ (0.285 lb/in³), lighter than 51% of refractory metal grades. It melts at 1,350°C (2,462 °F). SA is the default condition FabDigit quotes; AW is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 80/100, better than 97% of refractory metal grades
  • Low embodied carbon — 5.8 kg CO₂/kg, better than 97% of refractory metal grades
  • Ductile — tolerates forming and impact — 35%, better than 93% of refractory metal grades

Limitations

  • Poor heat conductor — 11.5 W/m·K (6.64 BTU/hr·ft·°F), worse than 99% of refractory metal grades
  • Low electrical conductivity — 1.6 % IACS, worse than 96% of refractory metal grades
  • Difficult to machine — 18/100, worse than 80% of refractory metal grades

Chromium Alloy 33-AW properties

Typical room-temperature values for Chromium Alloy 33-AW; 23 are specific to this condition. Other listed values are Chromium Alloy 33 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Chromium Alloy 33-AW has a density of 7.9 g/cm³ (0.285 lb/in³), lighter than 51% of refractory metal grades. It melts at 1,350°C (2,462 °F).

Density7.9 g/cm³0.29 lb/in³
Melting Point (Solidus)1,350°C2,462 °F
Liquidus Temperature1,400°C2,552 °F

Mechanical13

Chromium Alloy 33-AW has a yield strength of 460 MPa (66.7 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 70% of refractory metal grades. Elongation at break is 35% and the elastic modulus is 200 GPa (29 Msi).

Elastic (Young's) Modulus200 GPa29 Msi
Shear Modulus77 GPa11.2 Msi
Bulk Modulus167 GPa24.2 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)760 MPa110 ksi
Yield Strength (0.2% offset)460 MPa66.7 ksi
Elongation at Break35%
Reduction in Area40%
Shear Strength460 MPa66.7 ksi
Fatigue Strength (Endurance Limit)270 MPa39.2 ksi
Charpy V-Notch Impact (RT)80 J59 ft·lbf
Hardness, Brinell215 HB
Hardness, Rockwell B96 HRB

Thermal6

Chromium Alloy 33-AW is rated for continuous service to 400°C (752 °F). It conducts heat at 11.5 W/m·K (6.64 BTU/hr·ft·°F), worse than 99% of refractory metal grades. Thermal expansion is 14.5 µm/m·K (8.06 µin/in·°F).

Thermal Conductivity11.5 W/m·K6.6 BTU/hr·ft·°F
Specific Heat Capacity450 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)14.5 µm/m·K8.1 µin/in·°F
Latent Heat of Fusion270 J/g116 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-100°C-148 °F

Electrical3

Chromium Alloy 33-AW conducts electricity at 1.6 % IACS, worse than 96% of refractory metal grades.

Electrical Conductivity1.6 % IACS
Electrical Resistivity1.08×10⁻⁶ Ω·m42.5 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is very good (82/100), worse than 54% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.05 V
Corrosion ResistanceVery good82/100
Chemical Resistance SummaryOutstanding in hot concentrated nitric and mixed nitric/HF acids, in 60–99 % sulphuric acid up to elevated temperature, and in chloride-bearing media (pitting/crevice resistant, CPT typically >85 °C). Good in caustics and organic acids; limited in hot reducing hydrochloric acid and strongly reducing HF.

Sustainability4

Producing a kilogram of Chromium Alloy 33-AW takes about 78 MJ of energy and emits 5.8 kg of CO₂ — less than 96% of refractory metal grades. Typical recycled content is 35%.

Embodied Energy (primary production)78 MJ/kg33,534 BTU/lb
Embodied Carbon (primary production)5.8 kg CO₂/kg
Embodied Water200 L/kg24 gal/lb
Typical Recycled Content35%

Manufacturability8

Chromium Alloy 33-AW's machinability is poor (18/100, worse than 80% of refractory metal grades); weldability very good (70/100); formability poor (30/100).

MachinabilityPoor18/100
Machinability Rating (AISI 1212 = 100 %)12%
WeldabilityVery good70/100
Formability (cold)Poor30/100
CastabilityFair35/100
Brazeability / SolderabilityGood55/100
PolishabilityVery good80/100
Anodizing Responsen/a — stainless-type alloy; use pickling and passivation (nitric or citric) instead of anodizing

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Chromium Alloy 33-AW

Is Chromium Alloy 33 easy to machine?

Machine like a super-austenitic: rigid setups, sharp positive-rake carbide, ~25–50 % of 316L cutting speed, heavy feed to cut under the work-hardened layer, and flood coolant.

Can Chromium Alloy 33 be welded?

Weld with matching Alloy 33 filler (or over-alloyed Ni-base such as ERNiCrMo-3/-4), low heat input, interpass below ~150 °C, no preheat and no PWHT; backing gas with Ar+N₂ preserves nitrogen in root passes.

Can Chromium Alloy 33 be formed, bent or molded?

Cold forms well but work-hardens quickly and needs roughly twice the press force of 304; hot work 1100–1200 °C followed by solution anneal and water quench.

What surface finishes work on Chromium Alloy 33?

Pickle in HNO₃/HF then passivate to restore the Cr-rich film; mechanically polishes to a bright finish — never anodize, and avoid carbon-steel contamination during grinding.

Chromium Alloy 33 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Crdrives PREN and nitric-acid resistance31 – 3533
Ni30 – 3331
Mo0.5 – 21.6
Cuimproves sulphuric acid behaviour0.3 – 1.20.6
Naustenite stabiliser, doubles proof strength0.35 – 0.60.45
Mn≤ 20.5
Si≤ 0.50.3
C≤ 0.020.01
P≤ 0.02—
S≤ 0.01—
Fe≥ 30 (balance)—

Chromium Alloy 33-AW — frequently asked

What is Chromium Alloy 33-AW used for?

Chromium Alloy 33-AW is typically used for high-temperature furnace parts, glass and metal contact components, electrical contact and resistor materials and specialty alloying additive stock. In short: ductile wrought chromium grade; corrosion-resistance score 88; weldable in the Cr-alloy family.

What is the yield strength of Chromium Alloy 33-AW?

Chromium Alloy 33-AW has a typical yield strength of 460 MPa (66.7 ksi) and a tensile strength of 760 MPa (110 ksi) — stronger than 70% of refractory metal grades. Strength varies by condition: see the 5 listed tempers.

Is Chromium Alloy 33-AW easy to machine?

Not especially — machinability is rated poor (18/100, worse than 80% of refractory metal grades). Machine like a super-austenitic: rigid setups, sharp positive-rake carbide, ~25–50 % of 316L cutting speed, heavy feed to cut under the work-hardened layer, and flood coolant.

Can Chromium Alloy 33-AW be welded?

Yes — weldability is rated very good (70/100). Weld with matching Alloy 33 filler (or over-alloyed Ni-base such as ERNiCrMo-3/-4), low heat input, interpass below ~150 °C, no preheat and no PWHT; backing gas with Ar+N₂ preserves nitrogen in root passes.

What surface finishes work on Chromium Alloy 33-AW?

Pickle in HNO₃/HF then passivate to restore the Cr-rich film; mechanically polishes to a bright finish — never anodize, and avoid carbon-steel contamination during grinding.

Can Chromium Alloy 33-AW be formed, bent or molded?

Cold forms well but work-hardens quickly and needs roughly twice the press force of 304; hot work 1100–1200 °C followed by solution anneal and water quench.

What is the maximum service temperature of Chromium Alloy 33-AW?

Chromium Alloy 33-AW is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Chromium Alloy 33-SA and Chromium Alloy 33-CW?

SA is the default condition — standard stocked condition for plate, sheet, bar, pipe and tube; maximum corrosion resistance and ductility. CW: choose when higher proof strength and close dimensional tolerance are needed, e.g. fasteners and pump shafts. Yield strength is 430 MPa in SA versus 720 MPa in CW.

Sources

  1. VDM Alloy 33 / Nicrofer 3033 material data sheet — VDM Metals (2020)
  2. ASTM B625 — Cr-Ni-Fe-Mo-Cu-N alloy plate, sheet and strip (incl. UNS R20033) — ASTM International (2021)
  3. ASTM B649 — Ni-Fe-Cr-Mo-Cu alloy bar, wire and forgings — ASTM International (2021)
  4. ASTM B622 / B619 / B626 — seamless pipe & tube, welded pipe, welded tube — ASTM International (2021)
  5. EN 10088-2 — X1CrNiMoCuN33-32-1 (1.4591) — CEN (2014)
  6. ASM Handbook Vol. 13B — Corrosion: Materials — ASM International (2005)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.