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FFKM Plasma

Additive grade

also Chemraz, Perfluoroelastomer

Plasma = plasma / Radical Resistant

Choose for direct exposure to NF₃/O₂/fluorine radical plasma chamber cleans where erosion rate and particle shedding dominate seal life.

Injection moldingStandard cost $$

Values for the Plasma condition

Other FFKM grades and fills

FFKM is listed in 7 conditions; see the grade overview at FFKM.

Compare all 7 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Low Temperature
Use where the seal must stay resilient below −20 °C while still needing full FFKM chemical resistance.—1417075 Shore A
carbon-black filled, 70–75 Shore A
Lowest-cost workhorse FFKM for chemical process plant O-rings up to about 260–290 °C.—1516072 Shore A
PlasmaThis page
Plasma / Radical Resistant
Choose for direct exposure to NF₃/O₂/fluorine radical plasma chamber cleans where erosion rate and particle shedding dominate seal life.—1512030 Shore D
High Temperature
Pick when the seal sees sustained >290 °C, e.g. ALD/CVD chamber, hot process gas or steam-hydrocarbon service.—1612030 Shore D
Steam / Amine / Hot Water Resistant grade
Optimised cure system and filler for long-term hot water, saturated steam and amine service where standard peroxide-cured elastomers harden or blister.—1615075 Shore A
low-particulate, plasma/wet-etch resistant perfluoroelastomer
Default choice for wafer-fab chamber, gate valve, slit-valve and wet-bench seals where particle generation, plasma erosion and metal-ion contamination matter.—1714075 Shore A
RGD / Explosive-Decompression Resistant
Higher-hardness, high-modulus compound qualified against rapid gas decompression, H₂S/amine and sour well fluids in downhole and valve seals.—2111040 Shore D

What is FFKM Plasma?

FFKM Plasma is FFKM in the Plasma grade — choose for direct exposure to NF₃/O₂/fluorine radical plasma chamber cleans where erosion rate and particle shedding dominate seal life. FFKM Plasma has a tensile strength of 15 MPa (2.18 ksi), weaker than 74% of polymer grades. Elongation at break is 120% and the elastic modulus is 0.01 GPa (0.002 Msi). FFKM Plasma has a density of 2.1 g/cm³ (0.0759 lb/in³), heavier than 98% of polymer grades. Its glass-transition temperature is -3°C (27 °F). Semiconductor Grade is the default condition FabDigit quotes; Plasma is available on request or by drawing note.

Advantages

  • Good corrosion resistance — 99/100, better than 100% of polymer grades
  • High service temperature — 300°C (572 °F), better than 99% of polymer grades
  • Good UV / weathering resistance — 95/100, better than 95% of polymer grades
  • Conducts heat well — 0.3 W/m·K (0.173 BTU/hr·ft·°F), better than 83% of polymer grades

Limitations

  • High embodied carbon — 28 kg CO₂/kg, worse than 100% of polymer grades
  • Heavy — 2.1 g/cm³ (0.0759 lb/in³), worse than 98% of polymer grades
  • Difficult to machine — 18/100, worse than 98% of polymer grades
  • High mold shrinkage — 3.2%, worse than 98% of polymer grades
  • Low stiffness — 0.01 GPa (0.002 Msi), worse than 77% of polymer grades

FFKM Plasma properties

Typical room-temperature values for FFKM Plasma; 15 are specific to this condition. Other listed values are FFKM reference data and may not represent this condition. Bars are the position among polymer grades.

Physical3

FFKM Plasma has a density of 2.1 g/cm³ (0.0759 lb/in³), heavier than 98% of polymer grades. Its glass-transition temperature is -3°C (27 °F).

Density2.1 g/cm³0.08 lb/in³
Glass Transition (Tg)-3°C27 °F
Water Absorption (24 h)0.15%

Mechanical8

FFKM Plasma has a tensile strength of 15 MPa (2.18 ksi), weaker than 74% of polymer grades. Elongation at break is 120% and the elastic modulus is 0.01 GPa (0.002 Msi).

Elastic (Young's) Modulus0.01 GPa0 Msi
Poisson's Ratio0.49
Tensile Strength (Ultimate)15 MPa2.2 ksi
Elongation at Break120%
Shear Strength12 MPa1.7 ksi
Hardness, Shore A80 Shore A
Tear Strength16 kN/m91.4 lbf/in
Compression Set (22 h, 70 °C)14%

Thermal8

FFKM Plasma is rated for continuous service to 300°C (572 °F). It conducts heat at 0.3 W/m·K (0.173 BTU/hr·ft·°F), better than 83% of polymer grades. Thermal expansion is 230 µm/m·K (127.8 µin/in·°F).

Thermal Conductivity0.3 W/m·K0.17 BTU/hr·ft·°F
Specific Heat Capacity1,000 J/kg·K0.24 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)230 µm/m·K128 µin/in·°F
Max Service Temperature (continuous)300°C572 °F
Min Service Temperature-20°C-4 °F
Flammability (UL 94)Self-extinguishing; fully fluorinated backbone, typically rated V-0 in tested thicknesses
Limiting Oxygen Index95%
Max Service Temperature (short-term)340°C644 °F

Electrical4

FFKM Plasma is an electrical insulator with a dielectric strength of 18 kV/mm (457.2 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength18 kV/mm457 V/mil
Dielectric Constant (1 MHz)4
Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental3

Corrosion resistance is excellent (99/100), better than 100% of polymer grades. UV resistance is excellent.

Corrosion ResistanceExcellent99/100
UV / Weathering ResistanceExcellent95/100
Chemical Resistance SummaryNear-universal resistance: strong acids and bases, amines, ketones, esters, ethers, hot steam, oxidizing plasmas, fuels and hot hydrocarbons; attacked only by molten alkali metals, elemental fluorine at high temperature and some fluorinated solvents that cause swelling. Rapid gas decompression and cryogenic sealing are the practical limits, not chemistry.

Sustainability3

Producing a kilogram of FFKM Plasma takes about 400 MJ of energy and emits 28 kg of CO₂ — more than 100% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)400 MJ/kg171,969 BTU/lb
Embodied Carbon (primary production)28 kg CO₂/kg
Typical Recycled Content0%

Manufacturability3

FFKM Plasma's machinability is poor (18/100, worse than 98% of polymer grades).

MachinabilityPoor18/100
Mold Shrinkage3.2%
Mold Temperature (typ.)190°C374 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with FFKM Plasma

Is FFKM easy to machine?

Not a machining material — parts are net-shape moulded; trimming is done cryogenically or by waterjet, and any secondary cutting must avoid heat and tearing.

Can FFKM be welded?

Cannot be welded; joints are made by co-moulding or bonded splices, and spliced rings lose a large part of the burst/extrusion strength.

Can FFKM be formed, bent or molded?

Compression or injection moulded at roughly 170–205 °C with a long oven post-cure (up to ~305 °C, hours to days) to develop full compression-set and heat resistance; mould shrinkage is high (~3–4 %) so tooling must be scaled per compound.

What surface finishes work on FFKM?

Supplied as-moulded with minimal flash; semiconductor grades are washed/extracted and cleanroom packaged, and no coating or painting is practical on the low-energy fluorinated surface.

FFKM chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
tetrafluoroethylene (TFE)backbone comonomer, wt% of polymer50 – 7062
perfluoromethylvinyl ether (PMVE)flexibilising comonomer28 – 4536
cure-site monomer (e.g. perfluoro nitriltriazine or peroxide cross-link site0.3 – 31.5
filler (carbon black, silica, TiO2, BaSOphr in the compound; grade dependent5 – 3015
curative / co-agent package0.5 – 42

FFKM Plasma — frequently asked

What is FFKM Plasma used for?

FFKM Plasma is typically used for semiconductor plasma chamber seals, wafer wet-process O-rings, chemical reactor and valve seals, hot oilfield downhole seals, steam and amine service gaskets and aerospace fuel and hydraulic seals. In short: semiconductor-grade perfluoroelastomer.

What is the tensile strength of FFKM Plasma?

FFKM Plasma has a typical tensile strength of 15 MPa (2.18 ksi) — weaker than 74% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is FFKM Plasma easy to machine?

Not especially — machinability is rated poor (18/100, worse than 98% of polymer grades). Not a machining material — parts are net-shape moulded; trimming is done cryogenically or by waterjet, and any secondary cutting must avoid heat and tearing.

Can FFKM Plasma be welded?

Cannot be welded; joints are made by co-moulding or bonded splices, and spliced rings lose a large part of the burst/extrusion strength.

What surface finishes work on FFKM Plasma?

Supplied as-moulded with minimal flash; semiconductor grades are washed/extracted and cleanroom packaged, and no coating or painting is practical on the low-energy fluorinated surface.

Can FFKM Plasma be formed, bent or molded?

Compression or injection moulded at roughly 170–205 °C with a long oven post-cure (up to ~305 °C, hours to days) to develop full compression-set and heat resistance; mould shrinkage is high (~3–4 %) so tooling must be scaled per compound.

What is the maximum service temperature of FFKM Plasma?

FFKM Plasma is rated for continuous use to about 300°C (572 °F), and briefly to 340°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in FFKM Plasma?

Yes — FFKM Plasma is available for injection molding; every part is priced by an engineer rather than instantly. Upload a STEP file to get a price and a DFM check.

Sources

  1. Kalrez Perfluoroelastomer Parts — product and compound selection data — DuPont (2023)
  2. Chemraz perfluoroelastomer compound datasheets — Greene Tweed (2022)
  3. ASTM D1418 / ASTM D2000 — rubber classification (FFKM) — ASTM (2022)
  4. ASTM D412 / D395 / D2240 — tensile, compression set, durometer hardness of elastomers — ASTM (2021)
  5. ASM Engineered Materials Handbook Vol. 2 — Engineering Plastics/Elastomers — ASM International (1988)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.