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LiNbO3 BLN-SAW

Grade

BLN-SAW = black LN / acoustic (SAW) grade

Reduced (oxygen-deficient) opaque wafer whose lowered resistivity bleeds off pyroelectric charge — standard for 128°Y-X and 64°Y-X SAW filter/resonator production and for handling-safe wafer processing.

High cost $$$$

Values for the BLN-SAW condition

Other LiNbO3 tempers and conditions

LiNbO3 is listed in 5 conditions; see the grade overview at LiNbO3.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
iron-doped LiNbO3 (0.01–0.1 wt% Fe2O3)
Deliberately photorefractive grade for holographic data storage, phase conjugation and slow-light/adaptive interferometry; visibly yellow-brown with extra absorption.—950600 HV5 W/m·K
BLN-SAWThis page
Black LN / acoustic (SAW) grade
Reduced (oxygen-deficient) opaque wafer whose lowered resistivity bleeds off pyroelectric charge — standard for 128°Y-X and 64°Y-X SAW filter/resonator production and for handling-safe wafer processing.—950600 HV5 W/m·K
CLN-OPTDefault
CLN optical grade
Default workhorse: cheapest large-boule grade for electro-optic modulators, Q-switches, waveguides and general optics below ~10 MW/cm² at 1064 nm.—1000600 HV5 W/m·K
MgO:LN
Pick when green/visible power or photorefractive (optical) damage is the limit — MgO above the ~4.6 mol% threshold raises the damage threshold by 1–2 orders and lowers the coercive field for PPLN poling.—1000620 HV5 W/m·K
Near-stoichiometric LiNbO3
Choose for very low coercive field (~4 kV/mm vs ~21 kV/mm), thick-aperture periodic poling and reduced photorefractive/UV absorption; costlier and available in smaller sizes.—1000580 HV5 W/m·K

What is LiNbO3 BLN-SAW?

LiNbO3 BLN-SAW is LiNbO3 in the BLN-SAW grade — reduced (oxygen-deficient) opaque wafer whose lowered resistivity bleeds off pyroelectric charge — standard for 128°Y-X and 64°Y-X SAW filter/resonator production and for handling-safe wafer processing. LiNbO3 BLN-SAW has a tensile strength of 95 MPa (13.8 ksi), stronger than 79% of glass grades. Elongation at break is 0% and the elastic modulus is 175 GPa (25.4 Msi). LiNbO3 BLN-SAW has a density of 4.65 g/cm³ (0.168 lb/in³), heavier than 83% of glass grades. It melts at 1,257°C (2,295 °F). CLN-OPT is the default condition FabDigit quotes; BLN-SAW is available on request or by drawing note.

Advantages

  • Stiff — 175 GPa (25.4 Msi), better than 92% of glass grades
  • Tough — resists crack growth — 1.1 MPa·√m (1 ksi·√in), better than 90% of glass grades

Limitations

  • High embodied carbon — 60 kg CO₂/kg, worse than 87% of glass grades
  • Heavy — 4.65 g/cm³ (0.168 lb/in³), worse than 83% of glass grades

LiNbO3 BLN-SAW properties

Typical room-temperature values for LiNbO3 BLN-SAW; 15 are specific to this condition. Other listed values are LiNbO3 reference data and may not represent this condition. Bars are the position among glass grades.

Physical5

LiNbO3 BLN-SAW has a density of 4.65 g/cm³ (0.168 lb/in³), heavier than 83% of glass grades. It melts at 1,257°C (2,295 °F).

Density4.65 g/cm³0.17 lb/in³
Melting Point (Solidus)1,257°C2,295 °F
Refractive Index2.286
Light Transmission0%
Porosity0%

Mechanical12

LiNbO3 BLN-SAW has a tensile strength of 95 MPa (13.8 ksi), stronger than 79% of glass grades. Elongation at break is 0% and the elastic modulus is 175 GPa (25.4 Msi).

Elastic (Young's) Modulus175 GPa25.4 Msi
Shear Modulus70 GPa10.2 Msi
Bulk Modulus118 GPa17.1 Msi
Poisson's Ratio0.25
Tensile Strength (Ultimate)95 MPa13.8 ksi
Elongation at Break0%
Compressive Strength950 MPa138 ksi
Flexural Strength115 MPa16.7 ksi
Fracture Toughness (K_IC)1.1 MPa·√m1 ksi·√in
Hardness, Vickers600 HV
Hardness, Knoop600 HK
Hardness, Mohs5

Thermal5

LiNbO3 BLN-SAW is rated for continuous service to 400°C (752 °F). It conducts heat at 4.6 W/m·K (2.66 BTU/hr·ft·°F), better than 68% of glass grades. Thermal expansion is 15.4 µm/m·K (8.56 µin/in·°F).

Thermal Conductivity4.6 W/m·K2.7 BTU/hr·ft·°F
Specific Heat Capacity628 J/kg·K0.15 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)15.4 µm/m·K8.6 µin/in·°F
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-269°C-452 °F

Electrical4

LiNbO3 BLN-SAW has an electrical resistivity of 1×10⁸ Ω·m.

Electrical Resistivity1×10⁸ Ω·m3.94×10¹⁵ µΩ·in
Dielectric Constant (1 MHz)30
Dissipation Factor (1 MHz)0.001
Volume Resistivity1×10¹⁰ Ω·cm

Chemical & Environmental2

Corrosion resistance is very good (75/100), better than 51% of glass grades.

Corrosion ResistanceVery good75/100
Chemical Resistance SummaryInsoluble in water and organic solvents; stable to most acids and bases at RT. Etched by HF and HF/HNO3 mixtures (used for domain revealing, faster on -Z face); attacked by hot concentrated alkali and molten salts. Reduces (darkens) in vacuum/H2 above ~500 °C, and loses Li at high temperature in air.

Sustainability3

Producing a kilogram of LiNbO3 BLN-SAW takes about 900 MJ of energy and emits 60 kg of CO₂ — more than 89% of glass grades. Typical recycled content is 0%.

Embodied Energy (primary production)900 MJ/kg386,931 BTU/lb
Embodied Carbon (primary production)60 kg CO₂/kg
Typical Recycled Content0%

Manufacturability2

LiNbO3 BLN-SAW's machinability is not recommended (12/100, worse than 68% of glass grades).

MachinabilityNot recommended12/100
PolishabilityExcellent88/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with LiNbO3 BLN-SAW

Is LiNbO3 easy to machine?

Diamond-only: ID/wire sawing, lapping and CMP; the crystal cleaves and chips easily and is strongly anisotropic — no conventional cutting, and avoid thermal shock (>10 °C/min) which cracks large blanks.

Can LiNbO3 be welded?

Not weldable; join by optical contacting, adhesive/epoxy bonding, direct (fusion) wafer bonding to SiO2/Si for LNOI, or metallized solder attach.

Can LiNbO3 be formed, bent or molded?

Grown as boules by Czochralski from a congruent melt, then single-domain poled just below Tc; device gratings are made by room-temperature electric-field poling (~21 kV/mm CLN, ~5 kV/mm MgO/SLN).

What surface finishes work on LiNbO3?

CMP to sub-nm roughness, then AR/dielectric coatings; Ti in-diffusion or proton exchange forms waveguides; Cr/Au or Al metallization for electrodes and SAW IDTs.

LiNbO3 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nbcongruent melt Li/Nb ≈ 0.946 (48.45 mol% Li2O – 51.55 mol% Nb2O5)62.5 – 63.462.9
Linear-stoichiometric SLN grade runs Li/Nb 0.99–1.004.45 – 4.754.6
MgOmol% dopant in MgO:LN damage-resistant grade (typ. 5 mol%)0 – 50
Fe2O3wt% dopant in photorefractive Fe:LN grade0 – 0.10
Onominal 32.5 wt%; reduced 'black' wafers are slightly oxygen-deficientbalance—

LiNbO3 BLN-SAW — frequently asked

What is LiNbO3 BLN-SAW used for?

LiNbO3 BLN-SAW is typically used for electro-optic modulators, SAW devices, frequency doubling (SHG) and waveguide substrates. In short: standard electro-optic crystal; anisotropic, chips easily; 500 °C service ceiling.

What is the tensile strength of LiNbO3 BLN-SAW?

LiNbO3 BLN-SAW has a typical tensile strength of 95 MPa (13.8 ksi) — stronger than 79% of glass grades. Strength varies by condition: see the 5 listed tempers.

Is LiNbO3 BLN-SAW easy to machine?

Not especially — machinability is rated not recommended (12/100, worse than 68% of glass grades). Diamond-only: ID/wire sawing, lapping and CMP; the crystal cleaves and chips easily and is strongly anisotropic — no conventional cutting, and avoid thermal shock (>10 °C/min) which cracks large blanks.

Can LiNbO3 BLN-SAW be welded?

Not weldable; join by optical contacting, adhesive/epoxy bonding, direct (fusion) wafer bonding to SiO2/Si for LNOI, or metallized solder attach.

What surface finishes work on LiNbO3 BLN-SAW?

CMP to sub-nm roughness, then AR/dielectric coatings; Ti in-diffusion or proton exchange forms waveguides; Cr/Au or Al metallization for electrodes and SAW IDTs.

Can LiNbO3 BLN-SAW be formed, bent or molded?

Grown as boules by Czochralski from a congruent melt, then single-domain poled just below Tc; device gratings are made by room-temperature electric-field poling (~21 kV/mm CLN, ~5 kV/mm MgO/SLN).

What is the maximum service temperature of LiNbO3 BLN-SAW?

LiNbO3 BLN-SAW is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Lithium niobate: summary of physical properties and crystal structure (Weis & Gaylord), Applied Physics A 37 — Springer (1985)
  2. Properties of Lithium Niobate, EMIS Datareviews Series No. 28 — INSPEC/IEE (2002)
  3. Landolt-Börnstein III/29: Elastic, piezoelectric and dielectric constants of crystals — Springer (1993)
  4. LiNbO3 crystal and wafer specifications (optical, MgO-doped, black SAW grades) — CASTECH / Yamaju Ceramics / Gooch & Housego (2023)
  5. GB/T (LiNbO3 single crystal and wafer specification) — SAC/GB (2018)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.