FabDigit

ZnSe

also Irtran-4

ZnSe (Irtran-4) is a chemically vapour-deposited II-VI compound crystal transmitting 0.5–22 µm with very low absorption at 10.6 µm, which makes it the standard lens and window material for CO2 lasers.

High cost $$$$

Reference datasheet — ZnSe is not in the instant-quote catalog. Upload your part and an engineer will quote it in this grade or suggest the closest stocked equivalent.

ZnSe tempers and conditions

ZnSe is supplied in 2 conditions, soft to hard.

Compare all 2 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Single-crystal ZnSe
Used as substrate and host for Cr²⁺:ZnSe / Fe²⁺:ZnSe mid-IR lasers and for lowest-scatter research optics; anisotropic, cleaves on {110}, expensive in large sizes.42095 HV19 W/m·K
Multispectral / HIP-treated water-clear ZnSe
Pick when visible/NIR clarity and low scatter matter (0.4–14 µm multispectral windows, thermal imagers with visible channel); HIP coarsens grains so it is slightly weaker.480100 HV18 W/m·K

Supply forms, finishes and certifications

Ways ZnSe is supplied — form, process route, surface or paperwork — without a datasheet of their own. The property values above apply.

OptionWhat it isType
CVDDefault
Chemical-vapour-deposited polycrystalline ZnSeCoating

What is ZnSe?

ZnSe (Irtran-4) is a chemically vapour-deposited II-VI compound crystal transmitting 0.5–22 µm with very low absorption at 10.6 µm, which makes it the standard lens and window material for CO2 lasers. It is stocked as CVD, multispectral CVD-MS and single-crystal blanks for flats, meniscus lenses, prisms and camera optics. The limits are mechanical and thermal: it is soft and brittle with a tendency to edge chipping, conducts 18 W/m·K and is rated to about 300 °C, and its dust is toxic because of the selenium. ZnS is the harder, lower-cost alternative where 10.6 µm absorption is not the governing requirement. ZnSe has a density of 5.27 g/cm³ (0.19 lb/in³), heavier than 90% of glass grades. It melts at 1,525°C (2,777 °F). ZnSe has a tensile strength of 50 MPa (7.25 ksi), stronger than 59% of glass grades. The elastic modulus is 67.2 GPa (9.75 Msi).

What is ZnSe used for?

  • CO2 laser lenses/windows
  • IR camera lenses
  • multispectral optics

Advantages

  • Conducts heat well — 18 W/m·K (10.4 BTU/hr·ft·°F), better than 85% of glass grades
  • Easy to machine — 45/100, better than 85% of glass grades

Limitations

  • Heavy — 5.27 g/cm³ (0.19 lb/in³), worse than 90% of glass grades
  • Limited service temperature — 300°C (572 °F), worse than 80% of glass grades
  • Low fracture toughness — 0.5 MPa·√m (0.455 ksi·√in), worse than 76% of glass grades

ZnSe properties

Typical room-temperature values; bars are the position among glass grades.

Physical5

ZnSe has a density of 5.27 g/cm³ (0.19 lb/in³), heavier than 90% of glass grades. It melts at 1,525°C (2,777 °F).

Density5.27 g/cm³0.19 lb/in³
Melting Point (Solidus)1,525°C2,777 °F
Refractive Index2.403
Light Transmission71%
Porosity0%

Mechanical10

ZnSe has a tensile strength of 50 MPa (7.25 ksi), stronger than 59% of glass grades. The elastic modulus is 67.2 GPa (9.75 Msi).

Elastic (Young's) Modulus67.2 GPa9.7 Msi
Shear Modulus26.6 GPa3.9 Msi
Bulk Modulus40 GPa5.8 Msi
Poisson's Ratio0.28
Tensile Strength (Ultimate)50 MPa7.3 ksi
Flexural Strength55 MPa8 ksi
Fracture Toughness (K_IC)0.5 MPa·√m0.46 ksi·√in
Hardness, Vickers105 HV
Hardness, Knoop110 HK
Hardness, Mohs2.5

Thermal5

ZnSe is rated for continuous service to 300°C (572 °F). It conducts heat at 18 W/m·K (10.4 BTU/hr·ft·°F), better than 85% of glass grades. Thermal expansion is 7.1 µm/m·K (3.94 µin/in·°F).

Thermal Conductivity18 W/m·K10.4 BTU/hr·ft·°F
Specific Heat Capacity339 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)7.1 µm/m·K3.9 µin/in·°F
Max Service Temperature (continuous)300°C572 °F
Min Service Temperature-200°C-328 °F

Electrical3

ZnSe has an electrical resistivity of 1×10¹⁰ Ω·m.

Electrical Resistivity1×10¹⁰ Ω·m3.94×10¹⁷ µΩ·in
Dielectric Constant (1 MHz)9.1
Volume Resistivity1×10¹² Ω·cm

Chemical & Environmental2

Corrosion resistance is good (55/100), worse than 74% of glass grades.

Corrosion ResistanceGood55/100
Chemical Resistance SummaryInsoluble in water (~0.001 g/100 g) and stable in most organic solvents and alcohols; attacked by mineral acids (HNO₃, HCl, H₂SO₄) and by strong alkalis, and surface oxidizes/hazes in humid air above ~300 °C. Avoid ultrasonic cleaning of coated parts; clean with isopropanol/acetone and lens tissue.

Manufacturability2

ZnSe's machinability is fair (45/100, better than 85% of glass grades).

MachinabilityFair45/100
PolishabilityExcellent85/100

Common Calculations4

Specific Strength (UTS / density)calculated9 kN·m/kg
Specific Stiffness (E / density)calculated12.8 MN·m/kg
Thermal Diffusivitycalculated10.1 mm²/s
Thermal Shock Resistance Indexcalculated2

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Strength versus weight in the glass family

Yield strength against density for every glass grade FabDigit runs. ZnSe is highlighted; hover a dot for its name, or open the interactive family chart.

501002005002.533.5Density (g/cm³)Yield strength (MPa) — log scale

Working with ZnSe

Is ZnSe easy to machine?

Grind/core with diamond tooling under flood coolant or single-point diamond turn with light depth of cut; brittle and prone to edge chipping, and all dust/swarf is toxic (Se) so wet cutting with sealed extraction is mandatory.

Can ZnSe be welded?

Not weldable — a brittle ceramic; join only by optical contacting, epoxy bonding or mechanical mounting in compliant (RTV/retaining-ring) cells to avoid mount stress.

Can ZnSe be formed, bent or molded?

Formed to net shape by CVD deposition on mandrels, then HIP for multispectral grade; no plastic forming is possible, curved optics are generated and polished from blanks.

ZnSe chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Znstoichiometric ZnSe, 1:1 molar45 – 45.645.3
impurities (C, Si, Fe, Cu, O)total metallic + carbon impurities in optical grade; low absorption depends on ppm-level control≤ 0.010
Se≥ 54.4 (balance)

What surface finishes work on ZnSe?

Pitch or polyurethane polish to <10 Å rms, then AR coat (ThF₄/YbF₃ or ZnS/YF₃ stacks) or DLC-protect the exposed face; keep bare surfaces dry and handle with gloves — hygroscopic-free but easily scratched.

Equivalent designations

Standards and trade names that resolve to ZnSe in FabDigit's catalog. Equivalence is nominal — check the exact specification when certification matters.

Trade names
Irtran-4

How much does ZnSe cost?

ZnSe is a high-cost glass ($$$$), pricier than about 78% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

ZnSe — frequently asked

What is ZnSe used for?

ZnSe is typically used for CO2 laser lenses/windows, IR camera lenses and multispectral optics. In short: standard CO2 laser optic; low 10.6 µm absorption; brittle, selenium-bearing dust.

What is the tensile strength of ZnSe?

ZnSe has a typical tensile strength of 50 MPa (7.25 ksi) — stronger than 59% of glass grades. Strength varies by condition: see the 2 listed tempers.

Is ZnSe easy to machine?

Reasonably — machinability is rated fair (45/100, better than 85% of glass grades). Grind/core with diamond tooling under flood coolant or single-point diamond turn with light depth of cut; brittle and prone to edge chipping, and all dust/swarf is toxic (Se) so wet cutting with sealed extraction is mandatory.

Can ZnSe be welded?

Not weldable — a brittle ceramic; join only by optical contacting, epoxy bonding or mechanical mounting in compliant (RTV/retaining-ring) cells to avoid mount stress.

What surface finishes work on ZnSe?

Pitch or polyurethane polish to <10 Å rms, then AR coat (ThF₄/YbF₃ or ZnS/YF₃ stacks) or DLC-protect the exposed face; keep bare surfaces dry and handle with gloves — hygroscopic-free but easily scratched.

Can ZnSe be formed, bent or molded?

Formed to net shape by CVD deposition on mandrels, then HIP for multispectral grade; no plastic forming is possible, curved optics are generated and polished from blanks.

What is the maximum service temperature of ZnSe?

ZnSe is rated for continuous use to about 300°C (572 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

How much does ZnSe cost?

ZnSe is a high-cost glass ($$$$), pricier than about 78% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Sources

  1. CVD ZnSe optical material datasheet — II-VI / Coherent (2022)
  2. Cleartran multispectral ZnSe properties — Dow / II-VI (2019)
  3. Handbook of Optical Constants of Solids — Academic Press (Palik, ed.) (1998)
  4. Handbook of Optical Materials — CRC Press (Weber) (2003)
  5. IR window and lens material property tables — Thorlabs / Edmund Optics technical notes (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison; hardness values on non-Brinell scales are converted approximately for charting only. Manufacturability limits are FabDigit quote-engine defaults and may be relaxed by engineering review. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.