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GaAs SI-LEC

Grade · default condition

SI-LEC = semi-insulating single crystal, liquid encapsulated Czochralski

Standard undoped semi-insulating crystal for CO2-laser windows, IR optics and microwave/MMIC substrates.

High cost $$$$

Values for the SI-LEC condition

Other GaAs tempers and conditions

GaAs is listed in 4 conditions; see the grade overview at GaAs.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Poly-GaAs
Cheapest form — synthesised charge for crystal growth and low-cost thick IR blanks; grain boundaries scatter light and reduce strength, so not for high-power laser optics.—550590 HV48 W/m·K
SI-LECDefaultThis page
Semi-insulating single crystal, liquid encapsulated Czochralski
Standard undoped semi-insulating crystal for CO2-laser windows, IR optics and microwave/MMIC substrates.—700600 HV55 W/m·K
Si-doped conductive single crystal
Conductive substrate grade for LEDs, laser diodes and solar cells; not used for IR windows because free-carrier absorption kills 10.6 µm transmission.—720620 HV45 W/m·K
Semi-insulating single crystal, vertical gradient freeze
Pick when low dislocation density (EPD <5×10³ cm⁻²) and low residual stress matter — epi-ready device substrates and large low-wavefront-distortion optics.—800600 HV55 W/m·K

What is GaAs SI-LEC?

GaAs SI-LEC is GaAs in the SI-LEC grade — standard undoped semi-insulating crystal for CO2-laser windows, IR optics and microwave/MMIC substrates. GaAs SI-LEC has a tensile strength of 70 MPa (10.2 ksi), stronger than 76% of glass grades. Elongation at break is 0% and the elastic modulus is 85.5 GPa (12.4 Msi). GaAs SI-LEC has a density of 5.32 g/cm³ (0.192 lb/in³), heavier than 92% of glass grades. It melts at 1,238°C (2,260 °F).

Advantages

  • Conducts heat well — 55 W/m·K (31.8 BTU/hr·ft·°F), better than 93% of glass grades
  • Easy to machine — 35/100, better than 77% of glass grades

Limitations

  • High embodied carbon — 130 kg CO₂/kg, worse than 97% of glass grades
  • Heavy — 5.32 g/cm³ (0.192 lb/in³), worse than 92% of glass grades
  • Low fracture toughness — 0.44 MPa·√m (0.4 ksi·√in), worse than 78% of glass grades

GaAs SI-LEC properties

Typical room-temperature values for GaAs SI-LEC; 16 are specific to this condition. Other listed values are GaAs reference data and may not represent this condition. Bars are the position among glass grades.

Physical5

GaAs SI-LEC has a density of 5.32 g/cm³ (0.192 lb/in³), heavier than 92% of glass grades. It melts at 1,238°C (2,260 °F).

Density5.32 g/cm³0.19 lb/in³
Melting Point (Solidus)1,238°C2,260 °F
Refractive Index3.28
Light Transmission54%
Porosity0%

Mechanical13

GaAs SI-LEC has a tensile strength of 70 MPa (10.2 ksi), stronger than 76% of glass grades. Elongation at break is 0% and the elastic modulus is 85.5 GPa (12.4 Msi).

Elastic (Young's) Modulus85.5 GPa12.4 Msi
Shear Modulus32.9 GPa4.8 Msi
Bulk Modulus76 GPa11 Msi
Poisson's Ratio0.31
Tensile Strength (Ultimate)70 MPa10.2 ksi
Elongation at Break0%
Compressive Strength700 MPa102 ksi
Flexural Strength90 MPa13.1 ksi
Shear Strength55 MPa8 ksi
Fracture Toughness (K_IC)0.44 MPa·√m0.4 ksi·√in
Hardness, Vickers600 HV
Hardness, Knoop731 HK
Hardness, Mohs4.5

Thermal5

GaAs SI-LEC is rated for continuous service to 460°C (860 °F). It conducts heat at 55 W/m·K (31.8 BTU/hr·ft·°F), better than 93% of glass grades. Thermal expansion is 5.7 µm/m·K (3.17 µin/in·°F).

Thermal Conductivity55 W/m·K31.8 BTU/hr·ft·°F
Specific Heat Capacity327 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.7 µm/m·K3.2 µin/in·°F
Max Service Temperature (continuous)460°C860 °F
Min Service Temperature-269°C-452 °F

Electrical5

GaAs SI-LEC is an electrical insulator with a dielectric strength of 40 kV/mm (1,016 V/mil) and a resistivity of 1,000,000 Ω·m.

Electrical Resistivity1,000,000 Ω·m3.94×10¹³ µΩ·in
Dielectric Strength40 kV/mm1,016 V/mil
Dielectric Constant (1 MHz)12.9
Dissipation Factor (1 MHz)6×10⁻⁴
Volume Resistivity1×10⁸ Ω·cm

Chemical & Environmental2

Corrosion resistance is good (55/100), worse than 74% of glass grades.

Corrosion ResistanceGood55/100
Chemical Resistance SummaryInsoluble in water and stable in dry air; slowly oxidises in humid air above ~300 °C. Etched by HCl, HNO₃, H₂SO₄/H₂O₂ and hot alkalis; reacts with halogens. Contact with acids can liberate toxic arsine — handle dust and etch residues under controlled ventilation.

Sustainability4

Producing a kilogram of GaAs SI-LEC takes about 2,000 MJ of energy and emits 130 kg of CO₂ — more than 97% of glass grades. Typical recycled content is 5%.

Embodied Energy (primary production)2,000 MJ/kg859,846 BTU/lb
Embodied Carbon (primary production)130 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content5%

Manufacturability2

GaAs SI-LEC's machinability is fair (35/100, better than 77% of glass grades).

MachinabilityFair35/100
PolishabilityExcellent92/100

Common Calculations4

Specific Strength (UTS / density)calculated13 kN·m/kg
Specific Stiffness (E / density)calculated16.1 MN·m/kg
Thermal Diffusivitycalculated31.6 mm²/s
Thermal Shock Resistance Indexcalculated8

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with GaAs SI-LEC

Is GaAs easy to machine?

Diamond wire saw / ID saw and diamond lapping only; single-point diamond turning works in ductile regime, but {110} cleavage means edge chipping — always chamfer and use full arsenic-dust extraction.

Can GaAs be welded?

Not weldable; joined by optical contacting, epoxy/indium bonding or metallised (AuGe/Ni/Au) soldering into mounts.

Can GaAs be formed, bent or molded?

No plastic forming — shape is set by melt growth (LEC/VGF) followed by slicing, grinding and polishing; complex profiles are ground, not pressed.

What surface finishes work on GaAs?

CMP to epi-ready/laser-grade finish, then multilayer AR coating (ThF₄/ZnSe or DLC) is essential since each uncoated surface reflects ~28%.

GaAs chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Gastoichiometric 1:1 atomic with As48 – 48.448.2
Cresidual carbon ~1×10¹⁵–1×10¹⁶ cm⁻³, compensates EL2 in SI material≈ 2×10⁻⁸2×10⁻⁸
Siintentional dopant only in n-type grade (1×10¹⁷–5×10¹⁸ cm⁻³)≈ 1×10⁻⁷1×10⁻⁷
Asmelt grown near-stoichiometric; slight As-rich melt typical≥ 51.6 (balance)—

GaAs SI-LEC — frequently asked

What is GaAs SI-LEC used for?

GaAs SI-LEC is typically used for CO2 laser optics, IR windows/lenses, optoelectronic device substrates and laser diode substrates. In short: rugged 10.6 µm window; stronger than ZnSe; semi-insulating IR substrate.

What is the tensile strength of GaAs SI-LEC?

GaAs SI-LEC has a typical tensile strength of 70 MPa (10.2 ksi) — stronger than 76% of glass grades. Strength varies by condition: see the 4 listed tempers.

Is GaAs SI-LEC easy to machine?

Not especially — machinability is rated fair (35/100, better than 77% of glass grades). Diamond wire saw / ID saw and diamond lapping only; single-point diamond turning works in ductile regime, but {110} cleavage means edge chipping — always chamfer and use full arsenic-dust extraction.

Can GaAs SI-LEC be welded?

Not weldable; joined by optical contacting, epoxy/indium bonding or metallised (AuGe/Ni/Au) soldering into mounts.

What surface finishes work on GaAs SI-LEC?

CMP to epi-ready/laser-grade finish, then multilayer AR coating (ThF₄/ZnSe or DLC) is essential since each uncoated surface reflects ~28%.

Can GaAs SI-LEC be formed, bent or molded?

No plastic forming — shape is set by melt growth (LEC/VGF) followed by slicing, grinding and polishing; complex profiles are ground, not pressed.

What is the maximum service temperature of GaAs SI-LEC?

GaAs SI-LEC is rated for continuous use to about 460°C (860 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. NSM Archive — Physical Properties of Gallium Arsenide — Ioffe Institute (2001)
  2. Gallium Arsenide (GaAs) Optical Material Data — Crystran Ltd (2023)
  3. Handbook of Optical Constants of Solids — Academic Press (Palik, ed.) (1998)
  4. Semi-Insulating GaAs Substrate Specification (LEC / VGF) — Freiberger Compound Materials / AXT Inc. (2023)
  5. ASM Engineered Materials Handbook Vol. 4: Ceramics and Glasses — ASM International (1991)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.