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Phenolic XX FR

Flame-retardant grade

ASTM D709 · also Garolite XX, Bakelite

FR = flame-retardant paper phenolic

Pick where a UL 94 V-0 rating is mandated for the insulating part (appliance and switchgear insulation).

CNC machiningSheet metalPremium cost $$$

Values for the FR condition

Other Phenolic XX grades and fills

Phenolic XX is listed in 6 conditions; see the grade overview at Phenolic XX.

Compare all 6 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
NEMA XXXPC
Pick for high-volume cold blanking of thin insulation parts without pre-heating the sheet.—761.687 Shore D
NEMA XXXP
Pick for thin sheet that must be blanked/punched (terminal strips, washers) while keeping good electrical loss figures.—801.588 Shore D
NEMA XXX
Pick for radio-frequency or humid-environment insulation where low loss and low moisture pickup matter more than strength.—831.489 Shore D
FRThis page
Flame-retardant paper phenolic
Pick where a UL 94 V-0 rating is mandated for the insulating part (appliance and switchgear insulation).—851.490 Shore D
NEMA XX cellulose-paper / phenolic laminate (default)
General-purpose paper-phenolic sheet/rod/tube for combined mechanical and low-frequency electrical duty at low cost.—901.590 Shore D
NEMA X
Pick when only mechanical strength matters (spacers, jigs, wear pads) and electrical performance is irrelevant.—1001.691 Shore D

What is Phenolic XX FR?

Phenolic XX FR is Phenolic XX in the FR grade — pick where a UL 94 V-0 rating is mandated for the insulating part (appliance and switchgear insulation). Phenolic XX FR has a tensile strength of 85 MPa (12.3 ksi), weaker than 75% of composite grades. Elongation at break is 1.4% and the elastic modulus is 7 GPa (1.02 Msi). Phenolic XX FR has a density of 1.34 g/cm³ (0.0484 lb/in³), lighter than 78% of composite grades. Its glass-transition temperature is 170°C (338 °F). Phenolic Matrix is the default condition FabDigit quotes; FR is available on request or by drawing note.

Advantages

  • Easy to machine — 78/100, better than 80% of composite grades
  • Low embodied carbon — 4.5 kg CO₂/kg, better than 79% of composite grades
  • Lightweight — 1.34 g/cm³ (0.0484 lb/in³), better than 78% of composite grades

Limitations

  • Degrades in UV without stabilisers — 25/100, worse than 86% of composite grades
  • Limited service temperature — 120°C (248 °F), worse than 78% of composite grades
  • Low stiffness — 7 GPa (1.02 Msi), worse than 77% of composite grades
  • Absorbs moisture — dry before molding — 1.3%, worse than 75% of composite grades

Phenolic XX FR properties

Typical room-temperature values for Phenolic XX FR; 23 are specific to this condition. Other listed values are Phenolic XX reference data and may not represent this condition. Bars are the position among composite grades.

Physical4

Phenolic XX FR has a density of 1.34 g/cm³ (0.0484 lb/in³), lighter than 78% of composite grades. Its glass-transition temperature is 170°C (338 °F).

Density1.34 g/cm³0.05 lb/in³
Glass Transition (Tg)170°C338 °F
Water Absorption (24 h)1.3%
Water Absorption (Saturation)4%

Mechanical14

Phenolic XX FR has a tensile strength of 85 MPa (12.3 ksi), weaker than 75% of composite grades. Elongation at break is 1.4% and the elastic modulus is 7 GPa (1.02 Msi).

Elastic (Young's) Modulus7 GPa1 Msi
Shear Modulus2.7 GPa0.39 Msi
Poisson's Ratio0.28
Tensile Strength (Ultimate)85 MPa12.3 ksi
Elongation at Break1.4%
Compressive Strength230 MPa33.4 ksi
Compressive Modulus7 GPa1 Msi
Flexural Strength115 MPa16.7 ksi
Flexural Modulus7.8 GPa1.1 Msi
Shear Strength80 MPa11.6 ksi
Izod Impact, Notched26 J/m0.49 ft·lbf/in
Hardness, Shore D90 Shore D
Hardness, Rockwell M105 HRM
Hardness, Rockwell R124 HRR

Thermal10

Phenolic XX FR is rated for continuous service to 120°C (248 °F). It conducts heat at 0.26 W/m·K (0.15 BTU/hr·ft·°F), worse than 71% of composite grades. Thermal expansion is 25 µm/m·K (13.9 µin/in·°F).

Thermal Conductivity0.26 W/m·K0.15 BTU/hr·ft·°F
Specific Heat Capacity1,300 J/kg·K0.31 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)25 µm/m·K13.9 µin/in·°F
Max Service Temperature (continuous)120°C248 °F
Min Service Temperature-50°C-58 °F
Heat Deflection Temp. @ 0.45 MPa170°C338 °F
Heat Deflection Temp. @ 1.8 MPa148°C298 °F
Flammability (UL 94)V-0
Limiting Oxygen Index40%
Max Service Temperature (short-term)150°C302 °F

Electrical7

Phenolic XX FR is an electrical insulator with a dielectric strength of 15 kV/mm (381 V/mil) and a resistivity of 1×10⁹ Ω·m.

Electrical Resistivity1×10⁹ Ω·m3.94×10¹⁶ µΩ·in
Dielectric Strength15 kV/mm381 V/mil
Dielectric Constant (1 MHz)5
Dissipation Factor (1 MHz)0.04
Volume Resistivity1×10¹¹ Ω·cm
Surface Resistivity1×10¹¹ Ω
Comparative Tracking Index (CTI)125 V

Chemical & Environmental3

Corrosion resistance is good (65/100), worse than 72% of composite grades. UV resistance is poor.

Corrosion ResistanceGood65/100
UV / Weathering ResistancePoor25/100
Chemical Resistance SummaryGood against oils, greases, aliphatic solvents and weak acids; attacked by strong alkalis, hot concentrated acids and oxidizers; long water/steam exposure swells the paper and drops insulation resistance.

Sustainability3

Producing a kilogram of Phenolic XX FR takes about 80 MJ of energy and emits 4.5 kg of CO₂ — less than 84% of composite grades. Typical recycled content is 5%.

Embodied Energy (primary production)80 MJ/kg34,394 BTU/lb
Embodied Carbon (primary production)4.5 kg CO₂/kg
Typical Recycled Content5%

Manufacturability4

Phenolic XX FR's machinability is very good (78/100, better than 80% of composite grades); weldability not recommended (0/100); formability poor (15/100).

MachinabilityVery good78/100
WeldabilityNot recommended0/100
Formability (cold)Poor15/100
PolishabilityFair35/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Phenolic XX FR

Is Phenolic XX easy to machine?

Cuts, drills and turns easily with sharp carbide tooling at high speed and no coolant; dust is abrasive and irritating, so use vacuum extraction and back up holes to avoid edge chipping and delamination.

Can Phenolic XX be welded?

Thermoset — cannot be welded or thermally reformed; join by bolting, riveting or epoxy/phenolic adhesive bonding after abrading the surface.

Can Phenolic XX be formed, bent or molded?

Supplied as fully cured sheet, rod and tube; thin sheet (P/PC grades) can be hot- or cold-punched, but thick stock must be machined to shape.

What surface finishes work on Phenolic XX?

Sand or scrape edges to remove fuzz and seal machined surfaces with varnish/epoxy to limit moisture pickup; the natural finish is brown-to-black and not platable, though it accepts primer-based paint.

Phenolic XX chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
phenol-formaldehyde resinresole/novolac, fully cured thermoset binder40 – 5548
volatiles/residual moisture0 – 21
cellulose kraft paperreinforcement web, multiple plies≥ 45 (balance)—

Phenolic XX FR — frequently asked

What is Phenolic XX FR used for?

Phenolic XX FR is typically used for electrical insulators and barriers, terminal boards and tag strips, punched washers, gaskets and shims, coil and transformer spacers, switch and relay bases and low-load bushings and cams. In short: classic phenolic laminate.

What is the tensile strength of Phenolic XX FR?

Phenolic XX FR has a typical tensile strength of 85 MPa (12.3 ksi) — weaker than 75% of composite grades. Strength varies by condition: see the 6 listed tempers.

Is Phenolic XX FR easy to machine?

Yes — machinability is rated very good (78/100, better than 80% of composite grades). Cuts, drills and turns easily with sharp carbide tooling at high speed and no coolant; dust is abrasive and irritating, so use vacuum extraction and back up holes to avoid edge chipping and delamination.

Can Phenolic XX FR be welded?

Not readily — weldability is rated not recommended (0/100). Thermoset — cannot be welded or thermally reformed; join by bolting, riveting or epoxy/phenolic adhesive bonding after abrading the surface.

What surface finishes work on Phenolic XX FR?

Sand or scrape edges to remove fuzz and seal machined surfaces with varnish/epoxy to limit moisture pickup; the natural finish is brown-to-black and not platable, though it accepts primer-based paint.

Can Phenolic XX FR be formed, bent or molded?

Supplied as fully cured sheet, rod and tube; thin sheet (P/PC grades) can be hot- or cold-punched, but thick stock must be machined to shape.

What is the maximum service temperature of Phenolic XX FR?

Phenolic XX FR is rated for continuous use to about 120°C (248 °F), and briefly to 150°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in Phenolic XX FR?

Yes — Phenolic XX FR is available for CNC machining and sheet metal with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. NEMA LI 1 — Industrial Laminating Thermosetting Products — NEMA (1998)
  2. ASTM D709 — Standard Specification for Laminated Thermosetting Materials — ASTM (2017)
  3. Paper-phenolic industrial laminate grades X / XX / XXX / XXXP — Norplex-Micarta (2022)
  4. Engineered Materials Handbook Vol. 2 — Engineering Plastics (phenolic laminates) — ASM International (1988)
  5. MatWeb paper-reinforced phenolic laminate property listings — MatWeb (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.