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ZRB2-SIC-CF

Reinforced grade

ZRB2-SIC-CF = carbon-fibre / chopped-fibre toughened UHTC

Pick when damage tolerance and thermal-shock survival matter more than absolute hardness — fibres raise toughness at the cost of oxidation life and strength scatter.

High cost $$$$

Values for the ZRB2-SIC-CF condition

Other ZrB2 tempers and conditions

ZrB2 is listed in 4 conditions; see the grade overview at ZrB2.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ZRB2-SIC-CFThis page
Carbon-fibre / chopped-fibre toughened UHTC
Pick when damage tolerance and thermal-shock survival matter more than absolute hardness — fibres raise toughness at the cost of oxidation life and strength scatter.———1,200 HV45 W/m·K
Pressureless sintered ZrB2
Choose when complex near-net shapes or larger parts are needed and 5–10 % lower strength / slight residual porosity is acceptable.———1,700 HV60 W/m·K
HPDefault
Hot-pressed monolithic ZrB2
Baseline dense monolithic UHTC: pick for electrodes, molten-metal hardware and short-duration high-heat-flux parts where SiC contamination is unwanted.———2,200 HV75 W/m·K
ZrB2–20 vol % SiC
The workhorse UHTC: SiC particles double the flexural strength and form a protective silica scale, so pick it for oxidizing service to ~1600–1800 °C (leading edges, nozzle throats).———2,300 HV78 W/m·K

What is ZRB2-SIC-CF?

ZRB2-SIC-CF is ZrB2 in the ZRB2-SIC-CF grade — pick when damage tolerance and thermal-shock survival matter more than absolute hardness — fibres raise toughness at the cost of oxidation life and strength scatter. ZRB2-SIC-CF has a tensile strength of 280 MPa (40.6 ksi), stronger than 67% of ceramic grades. The elastic modulus is 300 GPa (43.5 Msi). ZRB2-SIC-CF has a density of 4.6 g/cm³ (0.166 lb/in³), lighter than 54% of ceramic grades. It melts at 3,245°C (5,873 °F). HP is the default condition FabDigit quotes; ZRB2-SIC-CF is available on request or by drawing note.

Advantages

  • High service temperature — 1,600°C (2,912 °F), better than 86% of ceramic grades
  • Tough — resists crack growth — 7.5 MPa·√m (6.83 ksi·√in), better than 76% of ceramic grades

Limitations

  • High embodied carbon — 28 kg CO₂/kg, worse than 84% of ceramic grades

ZRB2-SIC-CF properties

Typical room-temperature values for ZRB2-SIC-CF; 10 are specific to this condition. Other listed values are ZrB2 reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical3

ZRB2-SIC-CF has a density of 4.6 g/cm³ (0.166 lb/in³), lighter than 54% of ceramic grades. It melts at 3,245°C (5,873 °F).

Density4.6 g/cm³0.17 lb/in³
Melting Point (Solidus)3,245°C5,873 °F
Porosity5%

Mechanical11

ZRB2-SIC-CF has a tensile strength of 280 MPa (40.6 ksi), stronger than 67% of ceramic grades. The elastic modulus is 300 GPa (43.5 Msi).

Elastic (Young's) Modulus300 GPa43.5 Msi
Shear Modulus213 GPa30.9 Msi
Bulk Modulus230 GPa33.4 Msi
Poisson's Ratio0.14
Tensile Strength (Ultimate)280 MPa40.6 ksi
Compressive Strength1,800 MPa261 ksi
Flexural Strength350 MPa50.8 ksi
Fracture Toughness (K_IC)7.5 MPa·√m6.8 ksi·√in
Hardness, Vickers1,200 HV
Hardness, Knoop1,800 HK
Hardness, Mohs9

Thermal5

ZRB2-SIC-CF is rated for continuous service to 1,600°C (2,912 °F). It conducts heat at 45 W/m·K (26 BTU/hr·ft·°F), better than 69% of ceramic grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity45 W/m·K26 BTU/hr·ft·°F
Specific Heat Capacity430 J/kg·K0.1 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Max Service Temperature (continuous)1,600°C2,912 °F
Min Service Temperature-200°C-328 °F

Electrical2

ZRB2-SIC-CF has an electrical resistivity of 9.2×10⁻⁸ Ω·m.

Electrical Resistivity9.2×10⁻⁸ Ω·m3.62 µΩ·in
Volume Resistivity9.2×10⁻⁶ Ω·cm

Chemical & Environmental2

Corrosion resistance is very good (70/100), worse than 59% of ceramic grades.

Corrosion ResistanceVery good70/100
Chemical Resistance SummaryInert to most mineral acids, alkalis and molten non-ferrous metals (Al, Cu, Zn, cryolite); attacked by HF, hot HNO3 and oxidizing molten salts; oxidizes in air above ~1100 °C forming volatile B2O3 plus porous ZrO2 unless SiC is added.

Sustainability4

Producing a kilogram of ZRB2-SIC-CF takes about 320 MJ of energy and emits 28 kg of CO₂ — more than 78% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)320 MJ/kg137,575 BTU/lb
Embodied Carbon (primary production)28 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content0%

Manufacturability3

ZRB2-SIC-CF's machinability is not recommended (12/100, better than 78% of ceramic grades).

MachinabilityNot recommended12/100
PolishabilityVery good75/100
Sintering / Firing Temperature1,800°C3,272 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ZRB2-SIC-CF

Is ZrB2 easy to machine?

Green machining before sintering is preferred; fired parts need diamond grinding, and because ZrB2 is metallically conductive it can be wire/sinker EDM'd — a major advantage over SiC and Si3N4.

Can ZrB2 be welded?

Not weldable; join by active brazing (Ti/Zr-bearing AgCu or Ni-based fillers), diffusion bonding to Nb/Mo, or co-sintering.

Can ZrB2 be formed, bent or molded?

Densified by hot pressing (1850–2050 °C, 20–30 MPa) or SPS; pressureless sintering above 2000 °C needs B4C/C/MoSi2 aids, so near-net shapes are made by cold isostatic pressing plus green machining.

What surface finishes work on ZrB2?

Diamond lapping/polishing to sub-µm Ra; for long oxidizing exposure apply or co-sinter SiC/HfO2-based coatings, and avoid abrasive blasting which leaves strength-limiting flaws.

ZrB2 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
B18.5 – 19.619.2
Hfnatural companion of zirconium, not removed0.5 – 2.51.5
Osurface B2O3/ZrO2 on powder; must be reduced for densification≤ 10.5
Cfrom carbothermal route / carbon sintering aid≤ 0.50.2
Femilling pickup≤ 0.20.05
SiC0 in monolithic grade; 15–30 vol % in ZrB2–SiC composite variants≈ 00
Zrstoichiometric ZrB2; commercial Zr carries 1–2.5 % Hf≥ 78.5 (balance)—

ZRB2-SIC-CF — frequently asked

What is ZRB2-SIC-CF used for?

ZRB2-SIC-CF is typically used for hypersonic leading edges, rocket nozzle inserts, molten metal crucibles and cutting tool additives. In short: EDM-machinable UHTC; metal-like thermal conductivity; highest-temperature boride family.

What is the tensile strength of ZRB2-SIC-CF?

ZRB2-SIC-CF has a typical tensile strength of 280 MPa (40.6 ksi) — stronger than 67% of ceramic grades. Strength varies by condition: see the 4 listed tempers.

Is ZRB2-SIC-CF easy to machine?

Not especially — machinability is rated not recommended (12/100, better than 78% of ceramic grades). Green machining before sintering is preferred; fired parts need diamond grinding, and because ZrB2 is metallically conductive it can be wire/sinker EDM'd — a major advantage over SiC and Si3N4.

Can ZRB2-SIC-CF be welded?

Not weldable; join by active brazing (Ti/Zr-bearing AgCu or Ni-based fillers), diffusion bonding to Nb/Mo, or co-sintering.

What surface finishes work on ZRB2-SIC-CF?

Diamond lapping/polishing to sub-µm Ra; for long oxidizing exposure apply or co-sinter SiC/HfO2-based coatings, and avoid abrasive blasting which leaves strength-limiting flaws.

Can ZRB2-SIC-CF be formed, bent or molded?

Densified by hot pressing (1850–2050 °C, 20–30 MPa) or SPS; pressureless sintering above 2000 °C needs B4C/C/MoSi2 aids, so near-net shapes are made by cold isostatic pressing plus green machining.

What is the maximum service temperature of ZRB2-SIC-CF?

ZRB2-SIC-CF is rated for continuous use to about 1,600°C (2,912 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications — Wiley/The American Ceramic Society (2014)
  2. Refractory Diborides of Zirconium and Hafnium (J. Am. Ceram. Soc. review) — American Ceramic Society (2007)
  3. ASM Engineered Materials Handbook Vol. 4 — Ceramics and Glasses — ASM International (1991)
  4. ISO 26845 — Fine ceramics, vocabulary and test-condition reporting — ISO (2008)
  5. Boride / UHTC component datasheets (CoorsTek, Kyocera, / ZrB2 powder) — various producers (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.