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Spinel REFR

Grade

REFR = refractory-grade spinel

Low-cost porous form for cement-kiln transition zones, steel-ladle linings and slag-resistant castables.

High cost $$$$

Values for the REFR condition

Other Spinel tempers and conditions

Spinel is listed in 4 conditions; see the grade overview at Spinel.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
SINT-DENSEDefault
pressureless-sintered dense polycrystalline spinel (opaque, >99 % TD)
Default technical-ceramic form: dense opaque spinel parts for semiconductor chamber components, kiln furniture and corrosion-exposed structural ceramics.———1,350 HV15 W/m·K
transparent spinel, hot-pressed + HIP optical grade
Pick for visible-to-MWIR windows, missile domes and transparent armour where sapphire is too costly or too anisotropic.———1,400 HV15 W/m·K
Single-crystal spinel
Choose for epitaxial substrates (GaN, SOS-type), UV–IR laser windows and where zero grain-boundary scattering is required.———1,450 HV24 W/m·K
REFRThis page
Refractory-grade spinel
Low-cost porous form for cement-kiln transition zones, steel-ladle linings and slag-resistant castables.————6 W/m·K

What is Spinel REFR?

Spinel REFR is Spinel in the REFR grade — low-cost porous form for cement-kiln transition zones, steel-ladle linings and slag-resistant castables. Spinel REFR has a tensile strength of 120 MPa (17.4 ksi), stronger than 51% of ceramic grades. The elastic modulus is 100 GPa (14.5 Msi). Spinel REFR has a density of 3 g/cm³ (0.108 lb/in³), lighter than 75% of ceramic grades. It melts at 2,135°C (3,875 °F). SINT-DENSE is the default condition FabDigit quotes; REFR is available on request or by drawing note.

Advantages

  • High service temperature — 1,800°C (3,272 °F), better than 92% of ceramic grades
  • Easy to machine — 15/100, better than 81% of ceramic grades
  • Lightweight — 3 g/cm³ (0.108 lb/in³), better than 75% of ceramic grades

Limitations

  • Hard to polish — 20/100, worse than 99% of ceramic grades

Spinel REFR properties

Typical room-temperature values for Spinel REFR; 12 are specific to this condition. Other listed values are Spinel reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical5

Spinel REFR has a density of 3 g/cm³ (0.108 lb/in³), lighter than 75% of ceramic grades. It melts at 2,135°C (3,875 °F).

Density3 g/cm³0.11 lb/in³
Melting Point (Solidus)2,135°C3,875 °F
Refractive Index1.715
Light Transmission0%
Porosity16%

Mechanical11

Spinel REFR has a tensile strength of 120 MPa (17.4 ksi), stronger than 51% of ceramic grades. The elastic modulus is 100 GPa (14.5 Msi).

Elastic (Young's) Modulus100 GPa14.5 Msi
Shear Modulus108 GPa15.7 Msi
Bulk Modulus193 GPa28 Msi
Poisson's Ratio0.26
Tensile Strength (Ultimate)120 MPa17.4 ksi
Compressive Strength110 MPa16 ksi
Flexural Strength25 MPa3.6 ksi
Fracture Toughness (K_IC)1.8 MPa·√m1.6 ksi·√in
Hardness, Vickers1,350 HV
Hardness, Knoop1,300 HK
Hardness, Mohs8

Thermal5

Spinel REFR is rated for continuous service to 1,800°C (3,272 °F). It conducts heat at 6 W/m·K (3.47 BTU/hr·ft·°F), worse than 61% of ceramic grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity6 W/m·K3.5 BTU/hr·ft·°F
Specific Heat Capacity820 J/kg·K0.2 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Max Service Temperature (continuous)1,800°C3,272 °F
Min Service Temperature-269°C-452 °F

Electrical5

Spinel REFR is an electrical insulator with a dielectric strength of 16 kV/mm (406.4 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength16 kV/mm406 V/mil
Dielectric Constant (1 MHz)8.3
Dissipation Factor (1 MHz)3×10⁻⁴
Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (85/100), better than 69% of ceramic grades.

Corrosion ResistanceExcellent85/100
Chemical Resistance SummaryInert to water, most acids and alkalis at room temperature; markedly better resistance to molten basic slags, alkali vapour and steel-plant fluxes than alumina; attacked by HF, hot concentrated H2SO4/H3PO4 and molten alkali fluorides.

Sustainability4

Producing a kilogram of Spinel REFR takes about 75 MJ of energy and emits 6.5 kg of CO₂ — less than 69% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)75 MJ/kg32,244 BTU/lb
Embodied Carbon (primary production)6.5 kg CO₂/kg
Embodied Water200 L/kg24 gal/lb
Typical Recycled Content0%

Manufacturability3

Spinel REFR's machinability is poor (15/100, better than 81% of ceramic grades).

MachinabilityPoor15/100
PolishabilityPoor20/100
Sintering / Firing Temperature1,750°C3,182 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Spinel REFR

Is Spinel easy to machine?

Green machining before firing is the economical route; fired parts require diamond grinding, lapping and ultrasonic/laser drilling with light passes to avoid subsurface damage.

Can Spinel be welded?

Not weldable — join by active-metal brazing (Ti/Ag-Cu), glass frit sealing or metallised Mo-Mn plus Ni plating for vacuum-tight assemblies.

Can Spinel be formed, bent or molded?

Uniaxial/isostatic pressing, slip or tape casting and injection moulding of fine MgAl2O4 powder; transparent grades need vacuum sintering or hot pressing followed by HIP at 1750–1900 °C / 150–200 MPa; allow ~15–18 % firing shrinkage.

What surface finishes work on Spinel?

Diamond lapping then colloidal-silica or CeO2 polishing gives optical λ/10 flatness and <1 nm Ra; AR coatings are applied for IR window use, and no anodising/plating is applicable.

Spinel chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
MgOstoichiometric MgO·Al2O3; Al-rich (MgO·1.5–2Al2O3) grades are used for transparent and refractory products27 – 29.528.3
LiFsintering aid used in hot-pressed transparent grades; removed/volatilised during HIP0 – 10.5
SiO2+CaO+Fe2O3 (impurities)≤200 ppm total for optical grades0 – 0.50.1
Al2O3≥ 70.5 (balance)—

Spinel REFR — frequently asked

What is Spinel REFR used for?

Spinel REFR is typically used for transparent armor/windows, refractory linings, IR domes and molten metal handling refractories. In short: transparent structural ceramic; optically isotropic cubic oxide; good thermal shock resistance.

What is the tensile strength of Spinel REFR?

Spinel REFR has a typical tensile strength of 120 MPa (17.4 ksi) — stronger than 51% of ceramic grades. Strength varies by condition: see the 4 listed tempers.

Is Spinel REFR easy to machine?

Not especially — machinability is rated poor (15/100, better than 81% of ceramic grades). Green machining before firing is the economical route; fired parts require diamond grinding, lapping and ultrasonic/laser drilling with light passes to avoid subsurface damage.

Can Spinel REFR be welded?

Not weldable — join by active-metal brazing (Ti/Ag-Cu), glass frit sealing or metallised Mo-Mn plus Ni plating for vacuum-tight assemblies.

What surface finishes work on Spinel REFR?

Diamond lapping then colloidal-silica or CeO2 polishing gives optical λ/10 flatness and <1 nm Ra; AR coatings are applied for IR window use, and no anodising/plating is applicable.

Can Spinel REFR be formed, bent or molded?

Uniaxial/isostatic pressing, slip or tape casting and injection moulding of fine MgAl2O4 powder; transparent grades need vacuum sintering or hot pressing followed by HIP at 1750–1900 °C / 150–200 MPa; allow ~15–18 % firing shrinkage.

What is the maximum service temperature of Spinel REFR?

Spinel REFR is rated for continuous use to about 1,800°C (3,272 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASM Engineered Materials Handbook Vol.4: Ceramics and Glasses — ASM International (1991)
  2. Transparent Spinel Ceramic Window Material Data — Surmet / II-VI optical ceramics datasheets (2022)
  3. Technical Ceramics Material Properties — Spinel and Oxide Ceramics — CoorsTek / Kyocera (2023)
  4. ACerS-NIST Phase Equilibria Diagrams — MgO–Al2O3 system — American Ceramic Society / NIST (2018)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.