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Ce-TZP

Ce-TZP is a tetragonal zirconia stabilized with 10–12 mol% ceria, which raises fracture toughness well above yttria-stabilized zirconia at the cost of hardness, making it the choice for maximum damage tolerance.

High cost $$$$

Reference datasheet — Ce-TZP is not in the instant-quote catalog. Upload your part and an engineer will quote it in this grade or suggest the closest stocked equivalent.

Values for the 12CE condition

Ce-TZP tempers and conditions

Ce-TZP is supplied in 4 conditions, soft to hard. 12CE is the default FabDigit quotes; the values on this page are for it.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
10Ce-TZP
Pick when peak fracture toughness / damage tolerance matters more than strength or hardness; more transformable, so watch stability near room temperature.2800.2950 HV2 W/m·K
Hot isostatic pressed
Choose for the highest strength and finest surface finish in Ce-TZP (wire-drawing dies, precision wear parts) where porosity-initiated failure must be eliminated.4300.21,130 HV3 W/m·K
12CEDefault
12Ce-TZP
Standard commercial Ce-TZP: best balance of ~550 MPa strength and 10–14 MPa·√m toughness with good phase stability.1,030 HV3 W/m·K
Ce-TZP/Al2O3 nanocomposite
Alumina-dispersed Ce-TZP: restores hardness and doubles strength while keeping very high toughness — the grade used for hip joint heads and heavily loaded tooling.1,200 HV6 W/m·K

What is Ce-TZP?

Ce-TZP is a tetragonal zirconia stabilized with 10–12 mol% ceria, which raises fracture toughness well above yttria-stabilized zirconia at the cost of hardness, making it the choice for maximum damage tolerance. It is supplied as sintered and HIP blanks and as layered ZTA/Ce-TZP composites for biomedical and impact-loaded parts. Density is 6.2 g/cm³, modulus 205 GPa, thermal conductivity 2.5 W/m·K and maximum service temperature 1000 °C; it must not be sintered in vacuum or reducing atmospheres, which reduce the ceria. Use 3Y-TZP where hardness and wear resistance matter more. Ce-TZP has a density of 6.2 g/cm³ (0.224 lb/in³), heavier than 68% of ceramic grades. It melts at 2,650°C (4,802 °F). Ce-TZP has a tensile strength of 330 MPa (47.9 ksi), stronger than 68% of ceramic grades. The elastic modulus is 205 GPa (29.7 Msi).

What is Ce-TZP used for?

  • biomedical implants
  • impact-resistant components
  • layered ZTA/Ce-TZP composites

Advantages

  • Tough — resists crack growth — 12 MPa·√m (10.9 ksi·√in), better than 93% of ceramic grades
  • Good corrosion resistance — 92/100, better than 88% of ceramic grades

Limitations

  • Poor heat conductor — 2.5 W/m·K (1.44 BTU/hr·ft·°F), worse than 83% of ceramic grades

Ce-TZP properties

Typical room-temperature values for Ce-TZP-12CE; bars are the position among ceramic grades.

Physical4

Ce-TZP has a density of 6.2 g/cm³ (0.224 lb/in³), heavier than 68% of ceramic grades. It melts at 2,650°C (4,802 °F).

Density6.2 g/cm³0.22 lb/in³
Melting Point (Solidus)2,650°C4,802 °F
Refractive Index2.18
Porosity0.2%

Mechanical11

Ce-TZP has a tensile strength of 330 MPa (47.9 ksi), stronger than 68% of ceramic grades. The elastic modulus is 205 GPa (29.7 Msi).

Elastic (Young's) Modulus205 GPa29.7 Msi
Shear Modulus78 GPa11.3 Msi
Bulk Modulus175 GPa25.4 Msi
Poisson's Ratio0.31
Tensile Strength (Ultimate)330 MPa47.9 ksi
Compressive Strength2,000 MPa290 ksi
Flexural Strength550 MPa79.8 ksi
Fracture Toughness (K_IC)12 MPa·√m10.9 ksi·√in
Hardness, Vickers1,030 HV
Hardness, Knoop1,000 HK
Hardness, Mohs8

Thermal5

Ce-TZP is rated for continuous service to 1,000°C (1,832 °F). It conducts heat at 2.5 W/m·K (1.44 BTU/hr·ft·°F), worse than 83% of ceramic grades. Thermal expansion is 10.5 µm/m·K (5.83 µin/in·°F).

Thermal Conductivity2.5 W/m·K1.4 BTU/hr·ft·°F
Specific Heat Capacity450 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)10.5 µm/m·K5.8 µin/in·°F
Max Service Temperature (continuous)1,000°C1,832 °F
Min Service Temperature-200°C-328 °F

Electrical5

Ce-TZP is an electrical insulator with a dielectric strength of 12 kV/mm (304.8 V/mil) and a resistivity of 1×10⁸ Ω·m.

Electrical Resistivity1×10⁸ Ω·m3.94×10¹⁵ µΩ·in
Dielectric Strength12 kV/mm305 V/mil
Dielectric Constant (1 MHz)28
Dissipation Factor (1 MHz)0.002
Volume Resistivity1×10¹⁰ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (92/100), better than 88% of ceramic grades.

Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryExcellent against water, steam, alkalis, molten non-ferrous metals and most acids; attacked by HF and hot concentrated H2SO4/H3PO4. Unlike Y-TZP it is essentially immune to low-temperature hydrothermal degradation, but strongly reducing atmospheres or vacuum above ~800 °C reduce Ce4+ to Ce3+, causing darkening and loss of tetragonal stability.

Sustainability4

Producing a kilogram of Ce-TZP takes about 110 MJ of energy and emits 7.5 kg of CO₂ — less than 52% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)110 MJ/kg47,292 BTU/lb
Embodied Carbon (primary production)7.5 kg CO₂/kg
Embodied Water280 L/kg33.6 gal/lb
Typical Recycled Content0%

Manufacturability3

Ce-TZP's machinability is not recommended (4/100, worse than 85% of ceramic grades).

MachinabilityNot recommended4/100
PolishabilityExcellent88/100
Sintering / Firing Temperature1,500°C2,732 °F

Common Calculations4

Specific Strength (UTS / density)calculated53 kN·m/kg
Specific Stiffness (E / density)calculated33.1 MN·m/kg
Thermal Diffusivitycalculated0.9 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Strength versus weight in the ceramic family

Yield strength against density for every ceramic grade FabDigit runs. Ce-TZP is highlighted; hover a dot for its name, or open the interactive family chart.

501002005001,000234567Density (g/cm³)Yield strength (MPa) — log scale

Working with Ce-TZP

Is Ce-TZP easy to machine?

Green/bisque machine wherever possible; after sintering only diamond grinding, lapping or laser/ultrasonic machining — but Ce-TZP tolerates grinding far better than Y-TZP thanks to its high toughness.

Can Ce-TZP be welded?

Not weldable; join by active-metal brazing (Ti-containing AgCu), glass sealing or mechanical/shrink fits, allowing for the ~10.5 µm/m·K CTE mismatch with steels.

Can Ce-TZP be formed, bent or molded?

Formed by uniaxial/CIP pressing, slip or injection molding of granulate, then sintering at 1450–1550 °C in air; avoid reducing atmospheres and vacuum sintering, which reduce ceria and darken/destabilize the body.

Ce-TZP chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
CeO2≈10–12 mol% CeO2 expressed in wt%13 – 1716
Al2O3sintering aid in monolithic grades; 20–30 vol% in Ce-TZP/A composite0 – 0.50.25
HfO2naturally present with zirconia1 – 2.51.8
SiO2impurity0 – 0.10.02
Fe2O3impurity0 – 0.050.01
Na2Oimpurity0 – 0.050.01
ZrO2balance, tetragonal phasebalance

What surface finishes work on Ce-TZP?

Diamond lapping and polishing to Ra <0.05 µm; grinding-induced compressive surface stress from t→m transformation actually raises strength, and no LTD annealing is needed as with Y-TZP.

How much does Ce-TZP cost?

Ce-TZP is a high-cost ceramic ($$$$), pricier than about 78% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Ce-TZP — frequently asked

What is Ce-TZP used for?

Ce-TZP is typically used for biomedical implants, impact-resistant components and layered ZTA/Ce-TZP composites. In short: highest-toughness zirconia; no hydrothermal ageing; damage-tolerant Y-TZP substitute.

What is the tensile strength of Ce-TZP?

Ce-TZP has a typical tensile strength of 330 MPa (47.9 ksi) — stronger than 68% of ceramic grades. Strength varies by condition: see the 4 listed tempers.

Is Ce-TZP easy to machine?

Not especially — machinability is rated not recommended (4/100, worse than 85% of ceramic grades). Green/bisque machine wherever possible; after sintering only diamond grinding, lapping or laser/ultrasonic machining — but Ce-TZP tolerates grinding far better than Y-TZP thanks to its high toughness.

Can Ce-TZP be welded?

Not weldable; join by active-metal brazing (Ti-containing AgCu), glass sealing or mechanical/shrink fits, allowing for the ~10.5 µm/m·K CTE mismatch with steels.

What surface finishes work on Ce-TZP?

Diamond lapping and polishing to Ra <0.05 µm; grinding-induced compressive surface stress from t→m transformation actually raises strength, and no LTD annealing is needed as with Y-TZP.

Can Ce-TZP be formed, bent or molded?

Formed by uniaxial/CIP pressing, slip or injection molding of granulate, then sintering at 1450–1550 °C in air; avoid reducing atmospheres and vacuum sintering, which reduce ceria and darken/destabilize the body.

What is the maximum service temperature of Ce-TZP?

Ce-TZP is rated for continuous use to about 1,000°C (1,832 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

How much does Ce-TZP cost?

Ce-TZP is a high-cost ceramic ($$$$), pricier than about 78% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Sources

  1. CEZ series ceria-stabilized zirconia powder data — Tosoh (2022)
  2. ASM Engineered Materials Handbook Vol.4: Ceramics and Glasses — ASM International (1991)
  3. Transformation toughening in Ce-TZP and Ce-TZP/Al2O3 composites (review chapters) — Journal of the American Ceramic Society / Elsevier (2010)
  4. Zirconia ceramic material properties (TZP grades) — CoorsTek / Kyocera (2023)
  5. ISO 13356 — Implants for surgery: ceramic materials based on yttria-stabilized tetragonal zirconia (reference for TZP test methods) — ISO (2015)

Property data is compiled from published supplier and standards handbooks and normalised for comparison; hardness values on non-Brinell scales are converted approximately for charting only. Manufacturability limits are FabDigit quote-engine defaults and may be relaxed by engineering review. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.