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PLZT 2/95/5

Grade

Pick for field-induced antiferroelectric–ferroelectric switching: low permittivity, high withstand voltage and large volume strain for energy storage, explosive-electric transduction and high-strain actuation to 180 °C.

High cost $$$$

Values for the 2/95/5 condition

Other PLZT tempers and conditions

PLZT is listed in 4 conditions; see the grade overview at PLZT.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
9/65/35Default
PLZT 9/65/35
Choose the hot-pressed relaxor composition for optical shutters, modulators and goggles: relaxor at room temperature, no residual birefringence and a large Kerr effect, but limited to 80 °C.—400.05380 HV1 W/m·K
PLZT 8/65/35
Choose when a latchable remanent polarization is needed at room temperature — optical and image storage, bistable light shutters — with the ferroelectric phase retained only to 110 °C.—400.05385 HV1 W/m·K
PLZT 9/65/35 HIP
Specify the hot isostatically pressed version when maximum transmission, minimum scattering and larger optical window sizes are needed, at 7.92 g/cm³ density and the highest cost.—450.05390 HV1 W/m·K
2/95/5This page
PLZT 2/95/5
Pick for field-induced antiferroelectric–ferroelectric switching: low permittivity, high withstand voltage and large volume strain for energy storage, explosive-electric transduction and high-strain actuation to 180 °C.—450.05400 HV2 W/m·K

What is PLZT 2/95/5?

PLZT 2/95/5 is PLZT in the 2/95/5 grade — pick for field-induced antiferroelectric–ferroelectric switching: low permittivity, high withstand voltage and large volume strain for energy storage, explosive-electric transduction and high-strain actuation to 180 °C. PLZT 2/95/5 has a tensile strength of 45 MPa (6.53 ksi), weaker than 69% of ceramic grades. Elongation at break is 0.05% and the elastic modulus is 75 GPa (10.9 Msi). PLZT 2/95/5 has a density of 8 g/cm³ (0.289 lb/in³), heavier than 77% of ceramic grades. It melts at 1,300°C (2,372 °F). 9/65/35 is the default condition FabDigit quotes; 2/95/5 is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 90/100, better than 78% of ceramic grades

Limitations

  • Poor heat conductor — 1.5 W/m·K (0.867 BTU/hr·ft·°F), worse than 92% of ceramic grades
  • Limited service temperature — 180°C (356 °F), worse than 86% of ceramic grades
  • Heavy — 8 g/cm³ (0.289 lb/in³), worse than 77% of ceramic grades
  • Low stiffness — 75 GPa (10.9 Msi), worse than 76% of ceramic grades

PLZT 2/95/5 properties

Typical room-temperature values for PLZT 2/95/5; 18 are specific to this condition. Other listed values are PLZT reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical5

PLZT 2/95/5 has a density of 8 g/cm³ (0.289 lb/in³), heavier than 77% of ceramic grades. It melts at 1,300°C (2,372 °F).

Density8 g/cm³0.29 lb/in³
Melting Point (Solidus)1,300°C2,372 °F
Refractive Index2.5
Light Transmission30%
Porosity0.05%

Mechanical13

PLZT 2/95/5 has a tensile strength of 45 MPa (6.53 ksi), weaker than 69% of ceramic grades. Elongation at break is 0.05% and the elastic modulus is 75 GPa (10.9 Msi).

Elastic (Young's) Modulus75 GPa10.9 Msi
Shear Modulus27 GPa3.9 Msi
Bulk Modulus47 GPa6.8 Msi
Poisson's Ratio0.26
Tensile Strength (Ultimate)45 MPa6.5 ksi
Elongation at Break0.05%
Compressive Strength650 MPa94.3 ksi
Flexural Strength85 MPa12.3 ksi
Shear Strength60 MPa8.7 ksi
Fracture Toughness (K_IC)1.1 MPa·√m1 ksi·√in
Hardness, Vickers400 HV
Hardness, Knoop360 HK
Hardness, Mohs5.5

Thermal5

PLZT 2/95/5 is rated for continuous service to 180°C (356 °F). It conducts heat at 1.5 W/m·K (0.867 BTU/hr·ft·°F), worse than 92% of ceramic grades. Thermal expansion is 5 µm/m·K (2.78 µin/in·°F).

Thermal Conductivity1.5 W/m·K0.87 BTU/hr·ft·°F
Specific Heat Capacity350 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5 µm/m·K2.8 µin/in·°F
Max Service Temperature (continuous)180°C356 °F
Min Service Temperature-50°C-58 °F

Electrical5

PLZT 2/95/5 is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1×10¹¹ Ω·m.

Electrical Resistivity1×10¹¹ Ω·m3.94×10¹⁸ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)400
Dissipation Factor (1 MHz)0.01
Volume Resistivity1×10¹² Ω·cm

Chemical & Environmental2

Corrosion resistance is good (62/100), worse than 70% of ceramic grades.

Corrosion ResistanceGood62/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of PLZT 2/95/5 takes about 100 MJ of energy and emits 9 kg of CO₂ — less than 55% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)100 MJ/kg42,992 BTU/lb
Embodied Carbon (primary production)9 kg CO₂/kg
Embodied Water150 L/kg18 gal/lb
Typical Recycled Content0%

Manufacturability3

PLZT 2/95/5's machinability is not recommended (7/100, better than 63% of ceramic grades).

MachinabilityNot recommended7/100
PolishabilityExcellent90/100
Sintering / Firing Temperature1,250°C2,282 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PLZT 2/95/5

Is PLZT easy to machine?

Machine only with diamond wheels or wire saws followed by lapping and polishing; sintered PLZT cannot be turned or milled. Thin plates chip readily, so use low feed rates and water cooling.

Can PLZT be welded?

Not weldable. Assemble to metals or optics with epoxy adhesive, glass solder, or by brazing to a metallised layer (Cr/Ni/Au or electroless Ni).

Can PLZT be formed, bent or molded?

Formed from co-precipitated or mixed-oxide powder by cold isostatic pressing, then densified by hot pressing or hot isostatic pressing in a PbO atmosphere; lead volatilisation and stoichiometry must be closely controlled.

What surface finishes work on PLZT?

Lap and polish both faces to λ/4 flatness and apply AR coatings; electrodes are usually sputtered transparent ITO or evaporated Cr/Au, and poled parts are aged below the Curie temperature to stabilise properties.

PLZT chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
PbA-site host; (Pb0.91La0.09) for 9/65/3555 – 6158.3
Ladopant level = first digit of grade (at% A-site substitution)1 – 53.9
ZrB-site; Zr/Ti = 65/3514 – 2517.9
TiB-site1 – 65.1
Ooxygen site of the perovskite ABO3 latticebalance—

PLZT 2/95/5 — frequently asked

What is PLZT 2/95/5 used for?

PLZT 2/95/5 is typically used for optical shutters, electro-optic modulators, flash-blindness goggles and actuators. In short: transparent electro-optic PZT; optical-grade piezo ceramic; low 80 °C service limit.

What is the tensile strength of PLZT 2/95/5?

PLZT 2/95/5 has a typical tensile strength of 45 MPa (6.53 ksi) — weaker than 69% of ceramic grades. Strength varies by condition: see the 4 listed tempers.

Is PLZT 2/95/5 easy to machine?

Not especially — machinability is rated not recommended (7/100, better than 63% of ceramic grades). Machine only with diamond wheels or wire saws followed by lapping and polishing; sintered PLZT cannot be turned or milled. Thin plates chip readily, so use low feed rates and water cooling.

Can PLZT 2/95/5 be welded?

Not weldable. Assemble to metals or optics with epoxy adhesive, glass solder, or by brazing to a metallised layer (Cr/Ni/Au or electroless Ni).

What surface finishes work on PLZT 2/95/5?

Lap and polish both faces to λ/4 flatness and apply AR coatings; electrodes are usually sputtered transparent ITO or evaporated Cr/Au, and poled parts are aged below the Curie temperature to stabilise properties.

Can PLZT 2/95/5 be formed, bent or molded?

Formed from co-precipitated or mixed-oxide powder by cold isostatic pressing, then densified by hot pressing or hot isostatic pressing in a PbO atmosphere; lead volatilisation and stoichiometry must be closely controlled.

What is the maximum service temperature of PLZT 2/95/5?

PLZT 2/95/5 is rated for continuous use to about 180°C (356 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Engineered Materials Handbook Vol. 4: Ceramics and Glasses — Electro-optic ceramics — ASM International (1991)
  2. Haertling, 'Ferroelectric Ceramics: History and Technology', J. Am. Ceram. Soc. 82[4] — American Ceramic Society (1999)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.